ThyssenKrupp Uhde s commercially proven PRENFLO and HTW TM Gasification Technologies Halle (Saale), June 13,
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1 ThyssenKrupp Uhde s commercially proven PRENFLO and HTW TM Gasification Technologies Halle (Saale), June 13, 2013 Claudio Marsico Director Sales Gas Technologies Division
2 Presentation Outline ThyssenKrupp and Uhde Uhde s experience and expertise in gasification PRENFLO (PSG / PDQ) High Temperature Winkler (HTW) Updates on Projects and Alliances Summary June 13, 2013 Halle (Saale) Page 2
3 ThyssenKrupp Group Workforce: ~150,000 ThyssenKrupp AG Steel Europe TK Uhde Elevator Technology TK Polysius Industrial Solutions TK Fördertechnik Components Technology Marine Systems Material Services vereinfacht, vorläufig June 13, 2013 Halle (Saale) Page 3
4 From the idea to operation of a chemical plant Research phase Concept development and assessment Execution of R&D projects Acquisition of technologies / companies Bid phase Project development / market study Feasibility study Project financing Project implementation phase Licence award or procurement Basic / detail engineering Procurement / inspection / shipping Project execution Construction Commissioning Operation and service phase Training of operating personnel Plant maintenance and operation Materials management and spare parts Plant optimisation and upgrading June 13, 2013 Halle (Saale) Page 4
5 Site-Seeing More than plants built by Uhde on all continents Fertilisers 130 plants Nitric acid Refineries Aromatics 185 plants 380 plants 75 plants Hydrogen, ammonia, methanol Org. Chemicals/petrochemicals Plastics, synthetic fibres Polyester / polyamides 120 plants 375 plants 115 plants 400 plants Electrolysis Coke Plant Technologies Tank storage facilities Industrial plants 150 plants 500 plants 105 plants 150 plants June 13, 2013 Halle (Saale) Page 5
6 Overview of our Product divisions Ammonia & Urea Hydrogen & Nitrates Electrolysis Refining Technologies Gas Technologies Org. Chemicals/ Polymers Polyester Coke Plant Technologies June 13, 2013 Halle (Saale) Page 6
7 Presentation Outline ThyssenKrupp and Uhde Uhde s experience and expertise in gasification PRENFLO (PSG / PDQ) High Temperature Winkler (HTW) Updates on Projects and Alliances Summary June 13, 2013 Halle (Saale) Page 7
8 Market drivers for gasification of solids Feedstock Technology Product fossil fuel prices fossil fuel availability fossil fuel flexibility proven technology clean technology ideal for low rank fuel polygeneration CCS sellable by-products June 13, 2013 Halle (Saale) Page 8
9 Energy reserves (Giga tons, oil equivalent) June 13, 2013 Halle (Saale) Page 9
10 Synthesis Gas as a Central Part of Uhde s Process Chain Gasification: Feedstock - Process - Product Feedstock Gasification Syngas Further processing Product Gas, Naphtha Steam Reformer/ ATR Methanol MTO Diesel Oil/Residues Oil Gasification MTG Petrol + LPG Petroleum Coke Hard Coal PRENFLO Gasification Synthesis Gas CO +H2 Ammonia FischerTropsch Synthesis Urea Fertilizer Diesel, Naphtha Biomass Lubricants Biomass CO-Conversion Hydrogen Brown Coal HTW Gasification Methanation Synthetic NaturalGas Waste Power Plant (IGCC) Electricity June 13, 2013 Halle (Saale) Page 10
11 Various Materials require various Gasification Technologies Uhde s Gasification Portfolio PRENFLO PSG, PDQ entrained-flow gasification HTW (High Temperature Winkler) fluidized-bed gasification June 13, 2013 Halle (Saale) Page 11
12 Gasification Technologies 550 C C C June 13, 2013 Halle (Saale) Page 12
13 Uhde s Gasifiers PSG PDQ Entrained-flow gasification HTW Fluidized bed gasification June 13, 2013 Halle (Saale) Page 13
14 Presentation Outline ThyssenKrupp and Uhde Uhde s experience and expertise in gasification PRENFLO (PSG / PDQ) High Temperature Winkler (HTW) Updates on Projects and Alliances Summary June 13, 2013 Halle (Saale) Page 14
15 Developments From Koppers-Totzek to PRENFLO Start Up: 1998 PRENFLO Puertollano 2,400 t/d (180,000 m³n/h syngas) Start Up: 1985 Scale Up Factor: 50 PRENFLO Fürstenhausen 48 t/d (3,500 m³n/h syngas) Start Up: 1984 Scale Up Factor: 8 Start Up: 1978 Shell-Koppers pilot plant Hamburg 150 t/d coal PRENFLO burner test rig 6 t/d (450 m³n/h syngas) 57 years Koppers-Totzek Start of development 1941 June 13, 2013 Halle (Saale) Page 15
16 Koppers-Totzek gasification plant in Modderfontein, S. Africa (Design capacity: 1,000 t/d of ammonia) June 13, 2013 Halle (Saale) Page 16
17 Koppers-Totzek gasification plant in India (Capacity: 900 t/d of ammonia) June 13, 2013 Halle (Saale) Page 17
18 PRENFLO with Steam Generation (PSG) 1000 MWth, 40 bar Features dry coal/petcoke powder feed 4 horizontal co-annular burners membrane wall waste heat boiler (PSG) June 13, 2013 Halle (Saale) Page 18
19 PRENFLO Plant in Fürstenhausen, Germany June 13, 2013 Halle (Saale) Page 19
20 ELCOGAS IGCC plant: Gasification Island, Spain June 13, 2013 Halle (Saale) Page 20
21 Dry-fed, single train IGCC with CCS Pilot Plant at Elcogas, Spain 300 MW net based on petcoke / coal feedstock PRENFLO Gasification Coal Preparation ASU New CO 2 capture Pilot Plant implemented Gas Treatment Combined Cycle June 13, 2013 Halle (Saale) Page 21
22 PRENFLO with Direct Quench (PDQ) 1000 MWth, 40 bar Features dry coal/petcoke powder feed 4 horizontal co-annular burners membrane wall direct water quench June 13, 2013 Halle (Saale) Page 22
23 Presentation Outline ThyssenKrupp and Uhde Uhde s experience and expertise in gasification PRENFLO (PSG / PDQ) High Temperature Winkler (HTW) Updates on Projects and Alliances Summary June 13, 2013 Halle (Saale) Page 23
24 Developments The HTW Process Start Up: 1974 Scale Up Factor: 18 Start Up: 1978 HTW Laboratory Plant RWTH-Aachen 12 t/d Coal, Atm. Atmospheric Winkler generators t/d Lignite Scale Up Factor: 5 Start Up: 1988 Start Up: 1986 HTW- Pilot Plant Rheinbraun Wachtberg 40 t/d Lignite, 10 bar Start Up: 1989 June 13, 2013 Halle (Saale) Page 24 Engineering: 1994 KoBra IGCC RWE, Hürth 3700 t/d Lignite 27 bar HTW-Pilot Plant (WVW) Rheinbraun Wesseling 185 t/d Lignite, 25 bar HTW-Peat Gasification, Kemira HTW- Demonstration Plant Rheinbraun Berrenrath 720 t/d Lignite, 10 bar >20 Years
25 HTW High Temperature Winkler - Gasifier June 13, 2013 Halle (Saale) Page 25
26 HTW- Laboratory Plant (PDU) RWTH Aachen approx. 50 kg/h 1974 June 13, 2013 Halle (Saale) Page 26
27 HTW Pilot Plant RWE-Plant-Wachtberg Frechen / Germany 1,6 t/h June 13, 2013 Halle (Saale) Page 27
28 HTW Plant WVW- UK-Wesseling Wesseling / Germany 7,7 t/h Lignite bar June 13, 2013 Halle (Saale) Page 28
29 HTW Syngas Plant Kemira Oy Oulu / Finnland 30 t/h Peat 300 t/d NH June 13, 2013 Halle (Saale) Page 29
30 HTW Commercial Scale Demo Plant Berrenrath/Germany 25 t/h dried lignite 140 MWth 34,000 m³/h of syngas 300 t/d Methanol 67,000 total operating hours 84 % availability (last 10 years) June 13, 2013 Halle (Saale) Page 30
31 KoBra - Engineering June 13, 2013 Halle (Saale) Page 31
32 HTW-Precon-Gasification Niihama / Japan 48 t/d Municipal Waste Sumitomo Heavy Industries Ltd. June 13, 2013 Halle (Saale) Page 32
33 Presentation Outline ThyssenKrupp and Uhde Uhde s experience and expertise in gasification PRENFLO (PSG / PDQ) High Temperature Winkler (HTW) Updates on Projects and Alliances Summary June 13, 2013 Halle (Saale) Page 33
34 ICM s 18,000 bbl/d CTL Plant in Mongolia Coal-to-Gasoline (CTG) plant * PRENFLO PDQ gasifiers Applying TK Uhde s PRENFLO Gasification Technology #1 coal preparation #2 coal gasification *) Photo Courtesy TransgasDevelopment #3 CO-shift reactor #4 acid gas removal #5 methanol synthesis #6 methanol-to-gasoline #7 gasoline storage June 13, 2013 Halle (Saale) Page 34
35 ICM s 18,000 bbl/d CTL Plant in Mongolia Presentation of Feasibility Study Ulaanbaatar, Mongolia, June, 2008 June 13, 2013 Halle (Saale) Page 35
36 ICM s 18,000 bbl/d CTL Plant in Mongolia Mongolia and Germany sign co-operation agreement Ulaanbaatar, Mongolia, October, 2011 CTL project is of strategic importance June 13, 2013 Halle (Saale) Page 36
37 ICM s 18,000 bbl/d CTL Plant in Mongolia Signing of agreement between Gov t of Mongolia and TK Uhde in presence of Mongolian President Elbegdorj ThyssenKrupp Schloss Landsberg, Essen, Germany, March 31, 2012 June 13, 2013 Halle (Saale) Page 37
38 ICM s 18,000 bbl/d CTL Plant in Mongolia Signing of PRENFLO licence agreement between ICM and TK Uhde in presence of Mongolian President Elbegdorj ThyssenKrupp Schloss Landsberg, Essen, Germany, March 31, 2012 June 13, 2013 Halle (Saale) Page 38
39 ICM s 18,000 bbl/d CTL Plant in Mongolia Minister Battulga at ThyssenKrupp s Reference Plant Elcogas, Puertollano, Spain, April 08, 2013 June 13, 2013 Halle (Saale) Page 39
40 JAM Project in China Commissioning in 2009 Converting Coal into Gasoline Pilot Plant 100,000 tpa of gasoline Commercial Plant 1,000,000 tpa of gasoline Basic Engg. for MTG concluded June 13, 2013 Halle (Saale) Page 40
41 TransGas Coal-to-Liquids complex (18,000 bbl/d) PRENFLO with MTG based on coal Mingo County, West Virginia Applying TK Uhde s PRENFLO Gasification Technology June 13, 2013 Halle (Saale) Page 41
42 TransGas Coal-to-Liquids complex (18,000 bbl/d) Ground Breaking Ceremony, 09 May 2011, West Virginia Plant Site U.S. Senator Joe Manchin III. and WV Governor Earl Ray Tomblin June 13, 2013 Halle (Saale) Page 42
43 BioTfueL integrated process chain PRENFLO with FT based on solid and liquid feedstock Target Development and commercialisation of integrated process chain for production of 2 nd generation biofuels Uhde Total Sofiproteol Applying TK Uhde s PRENFLO Gasification Technology Axens IFP CEA June 13, 2013 Halle (Saale) Page 43
44 BioTfueL integrated process chain PRENFLO with FT based on solid and liquid feedstock Feedstock Pretreatment Gasification Gas Treatment Synthesis Wood Straw etc. Coal Torrefaction Milling CO-Shift AGR Gasel TM Fischer- Tropsch Synthesis and Product Upgrading Biodiesel; Biokerosene Petcoke Liquid Residues Life-cycle analysis for optimum equilibrium between technical-economical performance and environmental demands June 13, 2013 Halle (Saale) Page 44
45 SGCE 9,500 bpd CTL, Mozambique PRENFLO PDQ for high-ash coal Applying TK Uhde s PRENFLO Gasification Technology June 13, 2013 Halle (Saale) Page 45
46 Biomass-to-Methanol Plant, Hagfors / Värmland / Sweden Artist View Photo courtesy VärmlandsMetanol AB Applying TK Uhde s HTW Gasification Technology June 13, 2013 Halle (Saale) Page 46
47 C.GEN 450 MWe IGCC with CCS, Killingholme, UK PRENFLO PDQ selected Optional hydrogen production Carbon capture & storage Applying TK Uhde s PRENFLO Gasification Technology Synergies due to maximum integration into existing industrial network High level of standardization beneficial for future plants Feedstock: hard coal, petcoke and biomass June 13, 2013 Halle (Saale) Page 47
48 Alliances and to co-operate in the field of coal gasification JV KEPCO-Uhde Inc. founded in July 2011 in Seoul, South Korea June 13, 2013 Halle (Saale) Page 48
49 Alliances in the field of Coal-to-Liquids A) Coal-to-GASOLINE via Methanol (MTG) + B) Coal-to-DIESEL via Fischer-Tropsch + June 13, 2013 Halle (Saale) Page 49
50 Co-operations Lessons learnt from operators A) PRENFLO entrained-flow Gasification Technology + B) HTW fluidised-bed Gasification Technology + June 13, 2013 Halle (Saale) Page 50
51 Presentation Outline ThyssenKrupp and Uhde Uhde s experience and expertise in gasification PRENFLO (PSG / PDQ) High Temperature Winkler (HTW) Updates on Projects and Alliances Summary June 13, 2013 Halle (Saale) Page 51
52 Summary Gasification is a proven technology, a vast number of gasifiers are operating since decades successfully on commercial basis Gasification allows flexibility in feedstock and polygeneration of products Gasification is environmental friendly Uhde has more than 70 years of experience in gasification based on 8 different gasification technologies received more than 100 contract awards for gasifiers has proven single sourcing capability is a process oriented EPC contractor and not only licensor has built the world s largest solid fuel based, single train IGCC has built more than 2,000 plants worldwide June 13, 2013 Halle (Saale) Page 52
53 Gasification Uhde Site -Seeing Koppers-Totzek gasification Modderfontein, South Africa coal-to-ammonia/fertilisers HTW coal gasification Berrenrath, Germany coal-to-methanol GE (Texaco) coal gasification Oberhausen, Germany coal-to-hydrogen & oxochemicals PRENFLO coal gasification Fürtenhausen, Germany coal-to-methanol HTW MSW gasification Niihama, Japan waste-to-energy June 13, 2013 Halle (Saale) Page 53 PRENFLO IGCC Puertollano, Spain petcoke/coal-to-power
54 Summary Uhde is Technology Provider and EPC Contractor June 13, 2013 Halle (Saale) Page 54
55 Thank you for your attention PRENFLO IGCC, Puertollano, Spain Summer June 13, 2013 Halle (Saale) Page 55
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