Umur Kırtasiye San. ve Tic. AŞ. Neslihan Sözer Chemical Laboratory Manager

Transcription

1 TEST REPOR Page 1 of 7 REPORT NUMBER : TURA APPLICANT NAME ADDRESS Umur Kırtasiye San. ve Tic. AŞ. Esenkent Mah. Dudullu Org. San. Böl. 2. Cd No: Ümraniye İstanbul TÜRKİYE FAX NO : Attention : Özlem Kayataş ([email protected]) SAMPLE DESCRIPTION : BUYER : Paper TÜKİD DATE IN : 07 August, 2012 (13:59) RESUBMIT DATE : 10 August, 2012 DATE OUT : 23 August, 2012 PHOTO OF PRODUCT TESTED : Part No Tested Part G GLOSSY PAPER (REFERENCE : 80 G) 2 70 G 1.WOOD FREE PAPER (REFERENCE : 60 G) G A3 PAPER G BRISTOL PAPER G TRIPLEX PAPER Füsun Karaoğlu Coordinator Neslihan Sözer Chemical Laboratory Manager Merkez Mahallesi Sanayi Cad. No: 23 Altındağ Plaza Yenibosna ISTANBUL / TURKEY * * ssenturk

2 R E S U L T S Page 2 of 7 RESULTS : Analysis Parameter Reference Analysis Method PASS FAIL Norm Limit Standard for Norm Limit Tested Part Azo Dyes 64 LFBG B P - 30 ppm 2004/21/EC Part 1-5 Determination of perfluorooctane sulfonates (PFOS) & perfluorooctanoic acıd (PFOA) INTERTEK IHTM AL by LC/MS/MS P - 1 µg/m² 2006/122/EC Part 1-5 Formaldehyde JIS LAW 112 P - 20 ppm 2002/371/EC Part 1-5 Sb: 60 ppm As: 25 ppm Ba: 1000 ppm Toxic Element Cd: 75 ppm BS EN 71-3:1995 P - Analysis Cr: 60 ppm Pb: 90 ppm Hg: 60 ppm Se: 500 ppm EN 71-3 Part 1-5 P = MEETS BUYER' S REQUIREMENT / F = DOES NOT MEET BUYER' S REQUIREMENT / NR = NO REQUIREMENT / SC=STILL CONTINUES / X=NOT PERFORMED The test results relate only to the items tested. The report shall not be reproduced except in full, without the written approval of the laboratory. The reported uncertainity is based on a standard uncertainity multiplied by a coverage factor k=2, providing a level of confidence of approximately 95%. The uncertainity evaluation has been carried out in accordance with ISO/IEC and UKAS accreditation requirements. Unless otherwise is specified, all Pass or Fail results are given without uncertainity considered. When uncertainity is taken into account, the result may be borderline. Borderline results need to be re-tested to determine their disposition up to customer s decision. Opinions and interpretations expressed herein are outside the scope of UKAS accreditation. Tests marked (*) in this test report are not included in the UKAS accreditation schedule for this laboratory.

3 R E S U L T S Page 3 of 7 Azo Dyestuff 64 LFGB :2004 Determination of Certain aromatic Amines derived from azo colorants followed by GC- MS Analysis Part 1&2&3&4&5 1)Composite sample of 170 g Glossy paper,70 g 1.Wood free paper,120 g A3 paper PASS 30 ppm 2)Composite sample of 300 g Bristol paper,240 g Triplex paper PASS 30 ppm INTERPRETATION OF AZO-DYES TEST RESULTS: AS PER GERMAN TEST PROCEDURE FOR DETECTION OF CARCINOGENIC AMINES IN DYED MATERIALS PUBLISHED IN THE OFFICIAL COMPILATION OF TEST METHODS TEXTILE ACCORDING TO 64 LFGB , LEATHER ACCORDİNG TO 64 LFGB , PES ACCORDING TO 64 LFGB , EXTRACTED BY CITRATE BUFFERED SOLUTION ph 6 AT 70 C AND DETECTED BY GC/MS AND CONTROLLED BY HPLC/DAD AND THIN LAYER CHROMATOGRAPHIC ANALYSIS. FORBIDDEN AMINE CAS NO 4-AMINOBIPHENYL BENZIDINE CHLORO-O-4-CHLOR-O-TOLUIDINE NAPHTHYLAMINE *O-AMINOAZOTOLUENE *2-AMINO-4-NITROTOLUENE P-CHLOROANILINE ,4-DIAMINOANISOLE ,4 -DIAMINOBIPHENYLMETHANE ,3 -DICHLOROBENZIDINE ,3 -DIMETHOXYBENZIDINE ,3 -DIMETHYLBENZIDINE ,3 -DİMETHYL-4,4 DIAMINOBIPHENYLMETHANE P-CRESIDINE ,4 -METHYLENE-BIS-(2 CHLOROANILINE) ,4 -OXYDIANILINE ,4 -THIODIANILINE O-TOLUIDINE ,4-TOLUYLENDIAMINE ,4,5-TRIMETHYLANILINE O-ANISIDINE **P-AMINOAZOBENZENE NOTE:* The amines o-amino-azotoluene and 2-amino-4-nitrotoluene are detected by its splitted product o-toluidine and 2,4- toluylenediamine. **Azo colorants that are able to form 4-aminoazobenzene, generate under the condition of this method aniline and 1,4- phenylendiamine. The presence of these colorants can not be reliably ascertained without additional information, e.g. chemical structure of the colorant used. Remark < = Less Than ppm(part per million)= mg/ kg Detection Limit = 5 ppm Total Uncertainity = ±10%

4 R E S U L T S Page 4 of 7 Determination of Perfluorooctane sulfonates (PFOS) & Perfluorooctanoic Acid (PFOA) INTERTEK IHTM AL : Solvent Extraction Followed By Liquid Chromotographic- Mass Spectrometric(LS-MS-MS) Analysis Part 1 Part 2 Part 3 Part 4 Part 5 Detection Limit =0.25 ppb /0.5 µg/m² ND Not Detected (<0,25 ppb / <0.5 µg/m²) Requirement 1µg/m² according to 2006/122/EC (Total Uncertainty=±4 %)

5 R E S U L T S Page 5 of 7 Free Formaldehyde JIS LAW 112 Determination of Free Formaldehyde Content by UV-VIS Spectrophotometer : 2000 Part 1 <10 ppm 20 ppm Part 2 <10 ppm 20 ppm Part 3 <10 ppm 20 ppm Part 4 <10 ppm 20 ppm Part 5 <10 ppm 20 ppm ppm (Part per million) =mg / kg Detection Limit =10 ppm < Less Than (Total uncertainty=±6 %)

6 R E S U L T S Page 6 of 7 Toxic Elements Analysis BS EN 71-3:1995 : Acid extraction method was used and toxic elements content were determined by Inductively Coupled Plasma- ICP_OES. RESULT IN ppm PASS/FAIL Requirement (ppm) Part 1 Antimony (Sb) <2 ppm PASS 60 Part 2 Antimony (Sb) <2 ppm PASS 60 Part 3 Antimony (Sb) <2 ppm PASS 60 Part 4 Antimony (Sb) <2 ppm PASS 60 ppm (Part per million) =mg / kg < =Less Than (Total uncertainty=s quoted have been corrected for uncertainty. -)

7 R E S U L T S Page 7 of 7 Toxic Elements Analysis BS EN 71-3:1995 : Acid extraction method was used and toxic elements content were determined by Inductively Coupled Plasma- ICP_OES. RESULT IN ppm PASS/FAIL Requirement (ppm) Part 5 Antimony (Sb) <2 ppm PASS 60 ppm (Part per million) =mg / kg < =Less Than (Total uncertainty=s quoted have been corrected for uncertainty. -) ## END OF TEST REPORT ##