ROHM AND HAAS PLASTICS ADDITIVES BUILDING AND CONSTRUCTION SEGMENT Asia Pacific Region Product Range
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1 ROHM AND HAAS PLASTICS ADDITIVES BUILDING AND CONSTRUCTION SEGMENT Asia Pacific Region Product Range Rohm and Haas Company Rohm and Haas is a leading global provider of technically advanced material solutions for the building and construction, electronics, food and retail, household and personal care, packaging, transportation, water and industrial markets. Everyday we put our talents, skills and innovative technologies to work in helping our customers imagine the possibilities TM for their products that enhance the quality of everyday life for people around the world. In 2005, Rohm and Haas had sales of nearly 8.0 billion US dollars, a 10 percent increase over the previous year. The company has more than 100 manufacturing and research facilities in 27 countries, and about 17,000 employees worldwide. The company is organized in six business segments including coatings, performance chemicals, electronic materials, salt, adhesive and sealants and monomers. At Rohm and Haas, imagination means exploring the frontiers of technology and pushing beyond conventional boundaries to create products once thought impossible. Imagination is information racing at the speed of light through electronic devices. It is microscopic light-reflecting polymers that protect skin from harmful solar rays, and adhesives that help buildings stand firm against the violent shaking of earthquakes. All of these technologies are available today, and they are just glimpses of what Rohm and Haas imagination has made possible. As the leading specialty materials producer, with revolutionary developments in everything from electronic materials to polymers for paints to personal care products, Rohm and Haas will continue to bring innovation to market, imaging new possibilities to help you succeed in yours. Rohm and Haas Plastics Additives Rohm and Haas is a worldwide supplier of plastic additives used in a large variety of applications for vinyl, polyester, polycarbonate, and other engineering plastics or blends. Automotives parts, business machines, construction materials, packaging, home appliances, and consumer electronics owe their properties to these invisible workhorses, which add impact strength, clarity, chemical resistance, heat resistance, heat stability, weather resistance, color retention, greater output rates, melt strength and lubrification to base polymers. For more than 50 years, Rohm and Haas has been a pioneer in the development of plastic additives, introducing in 1956 the first MBS impact modifier, followed two
2 years later by the first processing aid and in 1968 by the first all-acrylic impact modifier. Performance Provider Product Series ACRYLIGARD ADVALUBE ADVAWAX ADVASTAB ADVAPAK PARALOID PARALOID EXL Acrylic Capstock Resin Specialty Lubricant Specialty Wax Methyl Tin Heat Stabilizer Multiple-function Methyl Tin Heat Stabilizer Impact Modifiers and Processing Aids Additives for Engineering Resins PARALOID KM-Series Acrylic Impact Modifiers Product Description PARALOID KM series Acrylic Impact Modifiers are designed using Rohm and Haas's finest core-shell technology. It is applicable for outdoor rigid PVC products such as window frames, panels, siding, fences, pipes, fitting and injection-molded parts. PARALOID KM series Acrylic Impact Modifiers are core-shell impact modifiers with a cross-linked poly-ba core and grafted poly-mma shell. Therefore, this product disperses as discrete particles in the matrix resin with best dispersing characteristic and product performance. PARALOID KM series Acrylic Impact Modifiers offer the following benefits compared to chlorinated polyethylene (CPE) or other acrylic impact modifiers: Best impact efficiency and impact retention. Excellent weatherability. Good resistance against sulphur staining. Improve surface gloss of profiles. Low post-extrusion shrinkage with best dimensional stability. High weld corner strength. Good processibility over a broad range of extrusion conditions.
3 Impact Efficiency The designed core-shell structure of PARALOID KM series acrylic impact modifiers provides best impact property over CPE. PARALOID KM-355P imparts excellent impact improvement both at room temperature and -10 C. Impact Strength Retention Retaining impact resistance is very important in building applications. The figure at right clearly demonstrates the superior performance of PARALOID KM355P impact modifier over competitive products. Charpy Impact Retention (Xenon-arc) Performance Comparison between KM-355P and CPE in PVC Window Profile Item/ Impact Modifier KM-355P (6 phr) CPE (8 phr) Post-extrusion Shrinkage Weld Corner Strength 100 C, 1 hour (%) (KN) Vicat Temperature B 50 ( C) Low Temperature Falling Weight Impact Number of Break -10 C, 1.5 m Gloss / (%) /10 38
4 Product Range and Performance Product Room Temperature Impact Strength Low Temperature Impact Strength Characteristics KM-355P **** *** Good impact efficiency, fast fusion, high gloss KM-357 **** ***** Superior low temperature impact strength KM-366 ***** **** Excellent impact efficiency, good processibility Note: more "*" means better Physical Properties No. Item Unit Specification Range KM-355P KM-357 KM Volatiles Content % Max. 1.0 Max. 1.0 Max Izod Impact KJ/m 2 Min. 80 Min. 100 Min Particle Size Distribution >850 micron <45 micron % % Max. 0.5 Max 7.0 Max. 0.4 Max Max. 0.5 Max Bulk Density g/cm ~ ~0.56 PARALOID HIA-80 Clear Weatherable Impact Modifier Product Description PARALOID HIA-80 Impact Modifier combines high impact performance and excellent clarity with weathering resistance for use in clear outdoor applications. Most weatherable acrylic impact modifier (AIM) and methyl-methacrylate-butadienestyrene (MBS) impact modifiers could not be used in clear and weatherable application. It is due to different refractive indexes of AIM against the vinyl polymer as well as poor weathering of Butadiene of MBS.
5 In contrast, PARALOID HIA-80 Impact Modifier imparts the best of both properties with high clarity and excellent impact performance. Impact Efficiency and Optical Properties PARALOID HIA-80 Impact Modifier provides the best balance of impact strength and optical properties in clear vinyl polymer. Weatherability PARALOID HIA-80 Impact Modifier is able to maintain the impact strength of vinyl sheet longer than competitive modifier. PARALOID HIA-80 modified sheet still has a high level of ductility even after 700 hours of exposure. After Xenon-arc weathering, PARALOID HIA-80 exhibits much less yellowing than MBS modifiers.
6 PARALOID K-SERIES Processing Aids Product Description PARALOID K-series are methyl methacrylate type processing aids for PVC used mainly in building applications, such as window frames, panels, siding, fences, sign boards, roofing sheets, pipes, fittings, injection-molded parts and foamed products. PARALOID K-series processing aids offer the following benefits over competitive products for PVC: Enhance faster fusion at lower processing temperature. Improve cohesion of melt and its homogeneity. Improve melt strength, extensibility and elasticity. Prevent melt fracture, improve smoother product surface and quality. Well disperse in PVC matrix. Enhance products with higher surface gloss. Lower foam density. Uniform cell structure.
7 Product Range and Application Product Promote Fusion Metal Strength Metal Release Dispersion Die Swell Application Window Profile Pipe and Fitting Injection Rigid Foam Rigid Foam Molding K-175P * * ***** ***** ** K-125P **** **** *** **** **** K-400P ***** ***** *** **** **** K-440 **** ***** *** **** ***** Note: more "*" means better Promote Fusion PARALOID K-series processing aids promote and homogenize PVC fusion drastically. Below graphs clearly indicated its fusion efficiency.
8 Physical Properties No. Item Unit Specification Range 1 Volatiles Content % Max Particle Size Distribution >850 micron <45 micron % % Max. 1.0 Max Bulk Density g/cm K175P( ) Recommended Formulation PVC Window Profile Formulation One Tin Stabilizer PVC Window Profile Formulation Two Lead Stabilizer PVC (K-65~68) 100 PVC (K-65~68) 100 Carstab TH ~1.5 Lead One-Pack Stabilizer 4.0~6.0 PARALOID KM Product 4.5~6.5 PARALOID KM Product 5.0~7.0 PARALOID K125P 0.5~1.5 PARALOID K125P 0.5~1.5 PARALOID K175P 0.5~1.0 PARALOID K175P 0.5~1.0 Calcium Stearate 1.0~1.5 Titanium Dioxide 4.0~10.0 Paraffin Wax 0.4~1.0 Calcium Carbonate 5.0~10.0 OPE Wax 0.1~0.3 Titanium Dioxide 4.0~10.0 Calcium Carbonate 5.0~12.0 PVC Foam Sheet & Profile Formulation PVC Pipe Formulation PVC (K-57~60) 100 PVC (K-65~68) 100 ADVASTAB TM-950F 1.7~2.0 ADVASTAB TM ~0.6 PARALOID K400P 7.0~10.0 PARALOID K125P 0.7~1.0 PARALOID K175P 1.0~2.0 Calcium Stearate 0.6~1.0 Calcium Stearate 0.6~1.2 Paraffin Wax 1.0~1.2 Paraffin Wax 0.5~1.0 OPE Wax 0.1~0.2 OPE Wax 0.1~0.2 Titanium Dioxide 0.5~2.0 Sodium Bicarbonate 1.0~1.5 Calcium Carbonate 3.0~5.0 Azodicarbonamide 0.2~0.5 Titanium Dioxide 1.0~5.0 Calcium Carbonate 3.0~5.0 PARALOID Plastics Additives - Safe Handling Recommendations PARALOID plastics additives should be kept away from flames, hot pipes, heaters or other sources of heat. Adequate precautions should be taken to keep all dust levels below values that are hazardous to health and safety. In the case of eye or skin contact, eyes should be flushed with water to remove dust particles and affected skin areas washed with soap and water. ADVASTAB Methyltin Stabilizers Product Description ADVASTAB Methyltin-series stabilizers are proven, high efficiency liquid methyltin mercaptide stabilizer for rigid vinyl building and construction application: various extrusion profiles and pelletized injection parts, such as window
9 frames, panels, siding, fences, pipes, fittings, injection-molded parts and foamed products. Methyltin Stabilizer Working Principle Comparison of Three Types of Tin Stabilizer Type Chemical Structure Heat Stability Performance Methyl Tin C-Sn Best Butyl Tin C-C-C-C-Sn Better Octyl Tin C-C-C-C-C-C-C-C-Sn Good ADVASTAB Methyltin-series stabilizers performance characteristic: Highly effective stabilizer, achieving high output rate and good finished product quality. Allows for efficient use of regrind. Provides superior early color as well as long-term color hold. ADVASTAB TM-950F has demonstrated increased gas yield with azo blowing agents which results in greater weight savings. Product Range and Application Product TM-291 TH-811 TM-950F Appearance Brown liquid Clear liquid Clear liquid Tin Content, % Sulfur Content, % Tri-methyl Tin Content, % 25 C Color (Gardner) Viscosity (@25 C, CS) Window Profile Application Pipe and Fitting 12 < < PVC Foam <
10 Standard Packaging Drum, net weight kg (500 lb) Handling and Storage ADVASTAB TM-291, TH-811 and TM-950F are liquid tin mercaptide heat stabilizer and should be handled with normal precautions used in good industrial practices for organic liquids. Use adequate ventilation. Wear rubber gloves. Wear eye protection. In case of contact with skin, wash thoroughly with soap and water. In case of contact with eyes, flush with water and get medical attention. Refer to Material Safety Data Sheet (MSDS) for safety and health information. Store in cool and dry area. Indoor storage is recommended. Stainless steel is recommended for piping, valves and pumps used to handle these materials. Further enquiry of above mentioned products on its application, technical document and information. Please contact your local ROHM AND HAAS representatives. ACRYLIGARD CS-281 Capstock Acrylic Polymer Product Description To fulfill the demand for high quality colored PVC co-extrusion market, ROHM AND HAAS has developed all-acrylic polymer, ACRYLIGARD, for co-extrusion as capstock over PVC substrate. PVC has proven to be unsatisfactory as a capstock particularly when the material is pigmented with darker colors. In contrast, ACRYLIGARD has an excellent weatherability as well as color hold which can be applied as a capping layer for door/window frame, panels, sidings and roof tiles. ACRYLIGARD CS-281 offers the following benefits: Applicable in all kind of color with excellent weathering and color hold. Excellent impact strength. Excellent melt strength and shrinkage level when co-extruded with PVC. High gloss imparted classic and stylish to the finished profile. Excellent Weatherability The 100% acrylic polymer is generally very stable toward UV light and this provides a perfect weathering material for outdoor application. A full four years natural weathering testing was conducted in US Arizona and Florida and the results demonstrated that Acryligard outperformed all other capstock resins. In addition Acryligard has been widely accepted by the Chinese market in such applications as co-extruded profiles, panels and siding.
11 Excellent Physical Properties Apart from good weathering resistance, Acryligard also has a good balance between mechanical and surface properties. With Acryligard on the finished product, customers enjoy high gloss, surface evenness as well as high impact strength compared to the poor impact of PMMA and low gloss and surface scratch resistance of ASA. Performance Comparison with Competing Products Product Competing PMMA Competing ASA Acryligard CS Gloss Falling Weight Impact Breakage (1.5 m, -10 C) Shore-D Hardness Pencil Hardness 72 3/ H 64 1/10 68 HB 75 1/10 70 H Note: Ball drop impact is based on c-extruded PVC window profile Excellent Processability In general, processing parameters play a very important part on the capping quality. A relative close melt flow property between PVC and capping material is important for a smooth extrusion to take place. Acryligard processing temperature is between 180 C and 220 C which is very similar to the processing temperature of PVC. As a result it is very easy to adapt Acryligard to PVC co-extrusion. Standard Colors
12 The Plastics Additives business of Kureha Chemical was purchased by Rohm and Haas Company in Some products formerly sold under the Kureha name have been re-branded "PARALOID". Rohm and Haas Company is a raw materials supplier, not an end-use manufacturer of product. Development of a final formulation, testing, application, and ultimate performance of the end-use product is fully the responsibility of the formulator. These suggestions and data are based on information we believe to be reliable. They are offered in good faith but, as conditions and methods of use of our products are beyond our control, Rohm and Haas Company makes no warranties, either expressed or implied, concerning the final end-use product. Rohm and Haas Company expressly disclaims any implied warranty of fitness for a particular purpose. We recommend that the prospective user determine the suitability of our materials and suggestions before adopting them on a commercial scale. Suggestions for uses of our product or the inclusion of descriptive material from patents and the citation of specific patents in this publication should not be understood as recommending the use of our products in violation of any patent, or as permission or license to use any patents of the Rohm and Haas Company. PARALOID, PARALOID EXL, ADVASTAB, ADVAWAX, ADVALUBE, ADVAPAK, ADVAFLEX, VINYZENE, BIO-PRUF, BIO-PRUF TREATED, ACRYLIGARD, and EZ-FLO are trademarks of Rohm and Haas Company or of its subsidiaries or affiliates. Rohm and Haas, 2007 All rights reserved.
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