Process Intensification Network NL. Welcome at the Member meeting Henk Akse - Chairman Frank van der Pas Agentschap NL

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1 Process Intensification Network NL Welcome at the Member meeting Henk Akse - Chairman Frank van der Pas Agentschap NL

2 Facts Objective PIN NL Develop and disseminate knowledge about Process Intensification in Dutch Process Industries Start Spring 1998 (Feijenoord stadion) Member companies 33 Focus of activities PI Quick Scans in Chemicals, Food and Pharma 2007 present Milestone European PI Roadmap beginning 2008 Current status First series PI Quick Scans continuing (3 in May 2010) Second series In Depth Scans just started (LyondellBasell Maasvlakte PO-11) Next PIN NL meeting Wednesday November 10 th 2010

3 Reactive extrusion TD ER Adv. HEX - plate TD ER Centrifugal adsorption technology TD ER Adv. HEX - spiral TD ER Centrifugal extractors TD ER Static mixers-heat exchangers TD ER Rotating Packed Beds TD ER Rotor-stator mixers TD ER Multistream heat exchangers TD ER Goodies from PI Quick Scan? Spinning Disc Reactors (SDRs) TD ER Microchannel heat exchangers TD ER Viscous heating TD ER Structured internals for mass transfer operations TD ER Ejector (Venturi) -based reactors TD ER Static mixers TD ER Micro mixers TD ER Foam reactors TD ER Monolith reactors TD ER Millisecond reactors TD ER Other structured catalytic reactors (KATAPAK s, parallel pasage etc.) TD ER Short term Hydrodynamic cavitation reactors TD ER Impinging streams reactor TD ER Pulsedcompression reactor TD ER Sonochemical reactors TD ER Ultrasound-enhanced crystallization TD ER 50 Direct suggestions for PI equipment Micro (channel) reactors TD ER Membrane reactors (non-selective) TD ER pay Ultrasound-enhanced phase dispersion / mass transfer TD ER Supersonic gas-liquid reactors TD ER Static mixers-reactors TD ER Adsorptive distillation TD ER Extractive crystallization TD ER Extractive distillation TD ER Supersonic gas-solid reactors TD ER Electric field-enhanced extraction-dispersion TD ER Heat-integrated distillation TD ER Membrane absorption/stripping TD ER Process redesign: grassroot / hybrid Electric field-enhanced heat transfer TD ER Electric field enhanced mixing TD ER Electric field enhanced operations - other (e.g. fouling prevention) TD ER Membrane adsorption TD ER Membrane crystallization TD ER Substantially less capital investment Electrochemical reactors ER TD Induction - ohmic heating ER TD Membrane distillation TD ER Microwave drying / Heating TD ER Distillation - pervaporation systems TD ER Microwave separation TD ER Microwave reactors - non cat TD ER Microwave reactors - cat TD ER Microwave reactors - polymer TD ER Membrane extraction TD ER 64 Substantially higher energy efficiency Photochemical reactors TD ER Hex Reactor TD ER Membrane reactor (selective) TD ER Plasma reactors TD ER SMBR TD ER 66 Substantially smaller footprint4.1.1 Continuous Oscillatory Baffled Reactors TD ER Rotating Annular Chromatographic Reactor TD ER Gas-solid-solid trickle flow reactor TD ER back times Medium/ long output Reverse flow reactors TD ER Chemical looping TD ER Reactive condensation TD ER Reactive extraction TD ER Reactive absorption TD ER Reactive crystallization / precipitation TD ER Pulsing operation of multiphase reactors TD ER Pulsedchromatografic reactors TD ER Pulsedcombustion drying TD ER Reactive distillation TD ER Pervaporation assisted Reactive distillation TD ER Reactive comminution TD ER Supercritical reactions TD ER Supercritical separation TD ER Cryogenic separations TD ER

4 PIN NL meetings present : PIN-NL meeting locatie Rijnmond (voorafgaand aan Masterclass PI van Deltalinqs) : 10 jarige jubileumbijeenkomst PIN-NL bij Shell Research in Amsterdam: Deze bijeenkomst richtte zich op de energieaspecten van PI en op de voortgang met de 'roadmap' : PIN-NL meeting Huntsman Rozenburg - agenda Februari 2007: Interview met prof.dr.ir. Andrzej Stankiewicz: "In de chemische industrie zijn nog tientallen procenten energiebesparing mogelijk" : PIN-NL Meeting TU Delft - agenda : PIN-NL Meeting Akzo Nobel : PIN-NL Meeting tijdens NPS-5 - agenda : Introductiecursus Procesintensificatie - verslag : PIN-NL Meeting Zeton, - agenda : PIN-NL Meeting tijdens NPS-4 - agenda

5 PIN NL member companies 1 ABB Lummus Heat Transfer BV 18 Process Design Centre 2 Agentschap NL 19 PFW Aroma chemicals b.v. 3 AkerKvaerner 20 Procede Group BV 4 Akzo Nobel 21 Process Design Center 5 BioMCN 22 Serenix 6 Bodec Proces Technology 23 Shell Exploration & Production 7 Delft University of Technology 24 Shell Global Solutions International BV 8 DMV International 25 Shell International Chemicals 9 Dow Chemicals Terneuzen 26 Shell Nederland Chemie 10 DSM 27 TNO 11 Eastman Chemical Company 28 Traxxys 12 ECN 29 TU Delft 13 House of Innovation 30 TU Eindhoven 14 Huntsman 31 Universiteit Twente 15 Hygear 32 Universiteit Wageningen 16 IdéActive BV 33 Zeton BV 17 Klaren B.V.

6 PI scanned companies present Air Liquide; Terneuzen AkzoNobel MCA; Delfzijl AkzoNobel Functional Chemicals BV; Herkenbosch Albemarle; Amsterdam Chemtura Netherlands B.V. Amsterdam Cindu chemicals B.V.; Uithoorn CP Kelco; Nijmegen Delamine; Delfzijl Dishman Netherlands; Veenendaal DMV International; Veghel DOW Chemical; Terneuzen DSM Special Products; Rotterdam Botlek Galvano; Hengelo Hexion Specialty Chemicals, Pernis Kemira Chemicals B.V.; Tiel Koch Raffinaderij; Rozenburg Kollo Silicon Carbide, Farmsum Linde; IJmuiden Lyondell; Botlek Lyondell; Maasvlakte Meneba; Weert NedMag; Veendam Neville Chemicals; Uithoorn Norit; Klazienaveen Nuplex Resins B.V. polycondensation; Bergen op Zoom Nuplex Resins B.V. polyaddition; Bergen op Zoom Sabic Innovative Plastics; Bergen op Zoom Shell Nederland Chemie, Moerdijk Shin-Etsu PVC B.V. Shin-Etsu VC B.V. Unimills; Zwijndrecht Zuid Chemie; Sas van Gent

7 Organisations focusing on PI PIN-UK: Network on Process Intensification (An active network on PI exists in the United Kingdom. More information is available through their website) - pig.ncl.ac.uk/links1.htm ECN (Providing a.o. HEX technology) - TNO-MEP (Providing a.o. HEX technology) - Food Technology Centre, Wageningen University (Integrated Extrusion-Extraction, Volumetric Heating, Membrane Emulsification) - Dechema (Gesellschaft für Chemische Technik und Biotechnologie) - AIChE (Publishes Chemical Engineering Progress and organizes symposia) - IMM (Institut für Mikro Technik Mainz) - School of Chemical Engineering And Advanced Materials, University of Newcastle upon Tyne (Providing a.o. HEX technology; High Gee distillation, Research on rotating disc reactions) - BHR Group Cranfield, UK (Test facilities, Prepared report Potentials for HEX for SenterNovem PIN NL in 1988, Organises PI conferences, OSPRI testfacilities for on site PI testing) - Universität Dortmund, Technische Chemie - Reactionstechnik (Microtechnology) - Faculty of Chemical Engineering and Chemistry, Laboratory of Chemical Reactor Engineering, University of Eindhoven (Research on transient and micro reactor systems) - GRETH (Groupement pour la Recherche sur les Echangeurs Thermiques) - Reactor and Catalyst engineering, University of Delft (structured catalyst and reactor research) - Chemical Reaction Engineering & Process Intensification Group -

8 Program Timing Title of Presentation Speaker Function PIN NL intro Ir. Henk Akse Chairman, CEO Traxxys MIPs and other novel selective resins for effective separations Dividing wall columns: which wall separates Dutch industry from application? Anthony R Rees MA DPhil Dr. Hartmut Schoenmakers + coauthor from BASF CEO of MIP Technologies Lund Sweden Former head of Corporate Technology BASF Ludwigshafen Combining reactions and separations using Ionic Liquids Tea / coffee break Rotating Packed Beds: a Swirl into Cost efficient Separation? Dr.ir. Maaike C. Kroon Prof.dr.ir. Henk van den Berg + coauthor from DOW Chemical Assistant professor TU Delft Professor plant & process design University of Twente Spinning Disc & Rotating Foam Dr.ir. John van der Schaaf Assistant professor University of Eindhoven OMEGA; successful process intensification at Shell Ir. Arthur Rots Team leader EO/EG Shell Global Solutions Amsterdam

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