SAFETY DATA SHEET. according to 1907/2006/EC, Article 31. Zenith 5N Carpet Shampoo (040800, )
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1 SAFETY DATA SHEET according to 1907/2006/EC, Article 31 Page 1/6 Zenith 5N Carpet Shampoo (04000, ) date SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name Zenith 5N Carpet Shampoo (04000, ) Product code YELLOW 1.2. Relevant identified uses of the substance or mixture and uses advised against Product Use [SU22] Professional uses: Public domain (administration, education, entertainment, services, craftsmen); [PC35] Washing and cleaning products (including solvent based products); 1.3. Details of the supplier of the safety data sheet Company Address Web Zenith Hygiene Group plc A1M Business Centre Dixons Hill Road Welham Green Herts AL9 7JE United Kingdom Telephone Emergency telephone number Emergency telephone number SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification - 67/54/EEC Main hazards Classification - EC 1272/200 Xi; R36 Symbols: Xi: Irritant. Irritating to eyes. Eye Irrit. 2: H319; 2.2. Label elements Hazard pictograms Signal Word Warning Hazard Statement Eye Irrit. 2: H319 - Causes serious eye irritation. Precautionary Statement: P264 - Wash thoroughly after handling. Prevention P20 - Wear protective gloves/protective clothing/eye protection/face protection. Precautionary Statement: P305+P351+P33 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact Response lenses, if present and easy to do. Continue rinsing.
2 2/6 Zenith 5N Carpet Shampoo (04000, ) date 2.2. Label elements P337+P313 - If eye irritation persists: Get medical advice/attention. SECTION 3: Composition/information on ingredients 3.1. Substances 67/54/EEC / 1999/45/EC Chemical Name Index No. CAS No. EC No. REACH Registration Di Methoxy Propanol ((2-methoxymethylethoxy) propanol) Number Conc. (%w/w) % Classification % Xn; R22 Xi; R41 sodium alkylbenzenesulphonate % Xn; R22 Xi; R3-41 EC 1272/200 Chemical Name Index No. CAS No. EC No. REACH Registration Conc. Classification Number (%w/w) Di Methoxy Propanol % ((2-methoxymethylethoxy) propanol) % Acute Tox. 4: H302; Eye Dam. 1: H31; sodium alkylbenzenesulphonate % Acute Tox. 4: H302; Skin Irrit. 2: H315; Eye Dam. 1: H31; SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Eye contact Skin contact Ingestion Move the exposed person to fresh air. Seek medical attention. Irritating to eyes. Rinse immediately with plenty of water for 15 minutes holding the eyelids open. Seek medical attention if irritation or symptoms persist. Wash off immediately with plenty of soap and water. Remove contaminated clothing. Seek medical attention if irritation or symptoms persist. Ingestion may cause nausea and vomiting. Seek medical attention if irritation or symptoms persist. DO NOT INDUCE VOMITING Most important symptoms and effects, both acute and delayed Inhalation Eye contact Skin contact Ingestion May cause irritation to respiratory system. Irritating to eyes. No irritation expected. Irritant Indication of any immediate medical attention and special treatment needed No information available on clinical testing and medical monitoring. Specific toxicological information on substances, if available, can be found in section 11. SECTION 5: Firefighting measures 5.1. Extinguishing media Use extinguishing media appropriate to the surrounding fire conditions Special hazards arising from the substance or mixture Burning produces irritating, toxic and obnoxious fumes Advice for firefighters Wear suitable respiratory equipment when necessary. SECTION 6: Accidental release measures
3 3/6 Zenith 5N Carpet Shampoo (04000, ) date 6.1. Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation of the working area. Wear suitable protective equipment Environmental precautions Do not allow product to enter drains. Prevent further spillage if safe Methods and material for containment and cleaning up Absorb with inert, absorbent material. Sweep up. Transfer to suitable, labelled containers for disposal. Clean spillage area thoroughly with plenty of water Reference to other sections For personal protective equipment see subsection.2. For disposal considerations see section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Avoid contact with eyes. Ensure adequate ventilation of the working area. Adopt best Manual Handling considerations when handling, carrying and dispensing Conditions for safe storage, including any incompatibilities Keep in a cool, dry, well ventilated area. Keep containers tightly closed. Store in correctly labelled containers Specific end use(s) No specific advice for end use available. SECTION : Exposure controls/personal protection.1. Control parameters.1.1. Exposure Limit Values Di Methoxy Propanol ((2-methoxymethylethoxy) propanol) WEL -hr limit ppm: 50 WEL -hr limit mg/m3: 30 WEL 15 min limit ppm: - WEL 15 min limit mg/m3: -.2. Exposure controls Adopt best Manual Handling considerations when handling, carrying and dispensing. Take off immediately all contaminated clothing. Wash hands after handling the product Appropriate engineering controls.2.2. Individual protection measures Eye / face protection Skin protection - Handprotection Respiratory protection Ensure adequate ventilation of the working area. Use appropriate personal protective equipment. Safety glasses. Not normally required. Not normally required. Do not breathe gas/fumes/vapour/spray. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties
4 4/6 Zenith 5N Carpet Shampoo (04000, ) date 9.1. Information on basic physical and chemical properties State Colour Odour Liquid Yellow Characteristic ph Melting point Freezing Point Boiling point Flash point Evaporation rate Flammability limits Vapour Flammability Fat Solubility Partition coefficient Autoignition temperature Viscosity Explosive Oxidising Solubility Soluble in water 9.2. Other information Conductivity Surface tension Specific gravity 1.01 g/cm³ SECTION 10: Stability and reactivity Reactivity No reactivity hazards known under normal storage and use conditions Chemical stability Stable under normal conditions Possibility of hazardous reactions No special hazards known Conditions to avoid None. SECTION 11: Toxicological information Information on toxicological effects Skin corrosion/irritation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Irritating to eyes. No mutagenic effects reported. No carcinogenic effects reported. No observed effect level Toxicological Information Inhalation Rat LC50/15min: NDA Oral Rat LD50: 300-2,000 mg/kg Dermal Rabbit LD50: 2,000 mg/kg Dermal Rat LD50: NDA Oral Mouse LD50: NDA Dermal Guinea Pig LD50: NDA sodium alkylbenzenesulphonate Inhalation Rat LC50/15min: NDA Dermal Rat LD50: NDA Oral Rat LD50: NDA Dermal Rabbit LD50: NDA Oral Mouse LD50: NDA Dermal Guinea Pig LD50: NDA SECTION 12: Ecological information
5 5/6 Zenith 5N Carpet Shampoo (04000, ) date Toxicity Daphnia EC50/4h: mg/l Fish LC50/96h: mg/l Algae IC50/72h: mg/l sodium alkylbenzenesulphonate Algae EC50/72h: NDA Daphnia LC50/4h: NDA Guppy LC50/96h: NDA Persistence and degradability No data is available on this product Bioaccumulative potential No data is available on this product Mobility in soil No data is available on this product Results of PBT and vpvb assessment Substances that fulfill the criteria for PBT/vPvB, if any, are listed in section Other adverse effects No other adverse effects known. SECTION 13: Disposal considerations General information Dispose of in compliance with all local and national regulations. Disposal of packaging Dispose of in compliance with all local and national regulations. Empty containers can be cleaned with water. Further information European Waste Catalogue: SECTION 14: Transport information ADR/RID IMDG IATA Further information SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Ingredients according to EC Detergent regulations shown in section 16 if applicable Chemical safety assessment A chemical safety assessment has not been carried out on the mixture. SECTION 16: Other information Other information LC: Lethal concentration. LD: Lethal dose. NDA -. NOAEC: No observed adverse effect concentration.
6 6/6 Zenith 5N Carpet Shampoo (04000, ) date Other information NOAEL: No observed adverse effect level. NOEC: No observed effect concentration. NOEL: No observed effect level. PBT: Persistent, bioaccumulative and toxic. vpvb. Very persistent and very bioaccumulative. *R01 - Polymer REACH number not available. Text of risk phrases in Section 3 Text of Hazard Statements in Section 3 This document differs from the previous version in the following areas: Classification of the substance or mixture Classification - EC 1272/ Hazard pictograms. 2 - Signal Word. 2 - Precautionary Statement: Prevention. 2 - Precautionary Statement: Response. R22 - Harmful if swallowed. R3 - Irritating to skin. R41 - Risk of serious damage to eyes. Acute Tox. 4: H302 - Harmful if swallowed. Eye Dam. 1: H31 - Causes serious eye damage. Skin Irrit. 2: H315 - Causes skin irritation. Further information The information supplied in this Safety Data Sheet is designed only as guidance for the safe use, storage and handling of the product. This information is correct to the best of our knowledge and belief at the date of publication however no guarantee is made to its accuracy. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any other process.
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