SAFETY DATA SHEET according to 1907/2006/EC, Article 31

Transcription

1 SAFETY DATA SHEET according to 1907/006/EC, Article 31 Page 1/9 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier date Product name Product code QADP Relevant identified uses of the substance or mixture and uses advised against Product Use Description 1.3. Details of the supplier of the safety data sheet Company Address Web [SU] Professional uses: Public domain (administration, education, entertainment, services, craftsmen); [SU3] Industrial uses: Uses of substances as such or in preparations at industrial sites; [SU1] Consumer uses: Private households (= general public = consumers); SUPAGARD LIMITED 19-7 Gavinton Street Muirend Glasgow G44 3EF Telephone Fax address of the competent person 1.4. Emergency telephone number Emergency telephone number SECTION : Hazards identification James.Smyth@supagard.com James.Smyth@supagard.com 8.30am to 5.00pm.1. Classification of the substance or mixture.1.1. Classification /45/ЕC Main hazards.1.. Classification - EC 17/008.. Label elements Hazard pictograms Xi; R36 Symbols: Xi: Irritant. Irritating to eyes. Skin Irrit. : H315; Eye Dam. 1: H318; Aquatic Chronic 3: H41;

2 date Page /9.. Label elements Signal Word Hazard Statement Precautionary Statement: Prevention Precautionary Statement: Response Precautionary Statement: Disposal.3. Other hazards Other hazards Danger Skin Irrit. : H315 - Causes skin irritation. Eye Dam. 1: H318 - Causes serious eye damage. Aquatic Chronic 3: H41 - Harmful to aquatic life with long lasting. P10 - Keep out of reach of children. P103 - Read label before use. P64 - Wash thoroughly after handling. P73 - Avoid release to the environment. P80 - Wear protective gloves/protective clothing/eye protection/face protection. P30+P35 - IF ON SKIN: Wash with plenty of water/. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 -Immediately call a POISON CENTER/doctor/. P31 - Specific treatment (see on this label). P33+P313 - If skin irritation occurs: Get medical advice/attention. P501 - Dispose of contents/container to an approved waste contractor. PBT not identified as a PBT substance. SECTION 3: Composition/information on ingredients 3.. Mixtures 67/548/EEC / 1999/45/EC Chemical Name Index No. CAS No. EC No. REACH Registration Conc. Classification Number (%w/w) Glycerol (Glycerol, mist) % M-factor. Amides, C8-C18(even numbered) and C18(Unsaturated), N,N-Bis(Hydroxyethyl) 1-Propanaminium, N- (3-aminopropyl) --hydroxy-n,n-dimethyl-3-sulfo-, N-(C8-18(even numbered)acyl) derivs, hydroxides, inner salts Reaction products of C1-18-(even numbered)-alkylamines and acrylic acid and sodium hydroxide % Xi; R % Xi; R % Xi; R38-41 Sodium Laureth Sulphate 1-10% Xi; R36/38 sodium hydroxide % C; R35 Benzenesulphonic Acid Mono C10-C13 Alkyl Dervis Sodium Salts % Xn; R Xi; R38-41

3 date Page 3/9 3.. Mixtures EC 17/008 Chemical Name Index No. CAS No. EC No. REACH Registration Conc. Classification Number (%w/w) Glycerol (Glycerol, mist) % M-factor. Amides, C8-C18(even numbered) and C18(Unsaturated), N,N-Bis(Hydroxyethyl) 1-Propanaminium, N- (3-aminopropyl) --hydroxy-n,n-dimethyl-3-sulfo-, N-(C8-18(even numbered)acyl) derivs, hydroxides, inner salts Reaction products of C1-18-(even numbered)-alkylamines and acrylic acid and sodium hydroxide % Skin Irrit. : H315; Eye Dam. 1: H318; Aquatic Chronic : H411; % Eye Dam. 1: H318; Aquatic Chronic 3: H41; % Skin Irrit. : H315; Eye Dam. 1: H318; Sodium Laureth Sulphate 1-10% Skin Irrit. : H315; Eye Irrit. : H319; Aquatic Chronic 3: H41; sodium hydroxide % Skin Corr. 1A: H314; Benzenesulphonic Acid Mono % Acute Tox. 4: H30; Skin Irrit. C10-C13 Alkyl Dervis Sodium Salts : H315; Eye Dam. 1: H318; Aquatic Chronic 3: H41; Alkyloxypolyethyleneoxyethanol % Acute Tox. 4: H30; Skin Irrit. : H315; Eye Dam. 1: H318; Acute Tox. 4: H33; Further information Product Shelf Life Active Ingredients RECOMMENDED SHELF LIFE 1 YEAR FROM DATE OF DELIVERY. Ingredients % Non-ionic Surfactants, 5-15% Anionic Surfactants, Benzisothiazolinone, CI 4090, CI 1000, Parfum (Amyl Cinnamal, Geraniol). SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Eye contact Skin contact Ingestion Move the exposed person to fresh air. Rinse immediately with plenty of water. Contact lenses should be removed. Remove contaminated clothing. Wash with water and soap as a precaution. DO NOT INDUCE VOMITING. Rinse mouth thoroughly. 4.. Most important symptoms and, both acute and delayed Inhalation Eye contact Skin contact Ingestion Irritating to respiratory system. Causes serious eye damage. Irritating to skin. Irritating to mucous membranes Indication of any immediate medical attention and special treatment needed Inhalation Eye contact Skin contact Ingestion General information SECTION 5: Firefighting measures 5.1. Extinguishing media Move the exposed person to fresh air. Seek medical attention if irritation or symptoms persist. Contact lenses should be removed. Rinse immediately with plenty of water. Seek medical attention if irritation or symptoms persist. Seek medical attention if irritation or symptoms persist. Drink 1 to glasses of water. Seek medical attention if irritation or symptoms persist. If you feel unwell, seek medical advice (show the label where possible). Treat symptomatically. This product is not flammable. Use fire-extinguishing media appropriate for surrounding materials.

4 4/9 5.. Special hazards arising from the substance or mixture 5.3. Advice for firefighters Further information SECTION 6: Accidental release measures Burning produces irritating, toxic and obnoxious fumes. Wear suitable respiratory equipment when necessary. date In the event of a fire and/or explosion do not breath fumes. Standard procedure for chemical fires. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment Personal precautions, protective equipment and emergency procedures 6.. Environmental precautions Wear suitable protective equipment Methods and material for containment and cleaning up Advise local authorities if large spills cannot be contained Reference to other sections For large spills:. Absorb with inert, absorbent material. Sweep up. Transfer to suitable, labelled containers for disposal. Clean spillage area thoroughly with plenty of water. For small spills:. Flush down the drain with plenty of water. See section, 7, 8, 13 for further information. SECTION 7: Handling and storage 7.1. Precautions for safe handling Adopt best Manual Handling considerations when handling, carrying and dispensing. 7.. Conditions for safe storage, including any incompatibilities 7.3. Specific end use(s) Suitable packaging Store in a cool, dry area. Keep container tightly closed. Keep out of the reach of children. Store in original container. Plastic containers. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Exposure Limit Values Occupational exposure controls.

5 date Page 5/ Exposure Limit Values Glycerol (Glycerol, mist) WEL 8-hr limit ppm: - WEL 8-hr limit mg/m3: 10 WEL 15 min limit ppm: - WEL 15 min limit mg/m3: - WEL 8-hr limit mg/m3 total - WEL 15 min limit mg/m3 total - inhalable dust: inhalable dust: WEL 8-hr limit mg/m3 total - WEL 15 min limit mg/m3 total - respirable dust: respirable dust: sodium hydroxide WEL 8-hr limit ppm: - WEL 8-hr limit mg/m3: - DNEL: Derived no-effect level. WEL 15 min limit ppm: - WEL 15 min limit mg/m3: WEL 8-hr limit mg/m3 total - WEL 15 min limit mg/m3 total - inhalable dust: inhalable dust: WEL 8-hr limit mg/m3 total - WEL 15 min limit mg/m3 total - respirable dust: respirable dust: Exposure Pattern - Workers Amides, C8-C18(even numbered) and C18(Unsaturated), N,N-Bis(Hydroxyethyl) sodium hydroxide Long-term - inhalation - Systemic 73.4 mg/m³ Long-term - dermal - Systemic 4.16 mg/kg Long-term - inhalation - Systemic 1 mg/m³ Long-term - inhalation - Local 1 mg/m³ Exposure Pattern - General population Amides, C8-C18(even numbered) and C18(Unsaturated), N,N-Bis(Hydroxyethyl) sodium hydroxide Long-term - inhalation - Systemic 1.73 mg/m³ Long-term - dermal - Systemic.5 mg/kg Long-term - oral - Systemic 6.5 mg/kg Long-term - inhalation - Systemic 1 mg/m³ Long-term - inhalation - Local 1 mg/m³ 8.. Exposure controls Eye / face protection Skin protection - Handprotection Respiratory protection Environmental exposure controls Adopt best Manual Handling considerations when handling, carrying and dispensing. Avoid contact with skin and eyes. Handle in accordance with good industrial hygiene and safety practice. Use appropriate personal protective equipment. Wear suitable protective clothing and eye/face protection. Avoid contact with eyes. If splashes are likely to occur, wear: safety glasses with side-shields. Rubber gloves. No personal respiratory protective equipment normally required. In case of insufficient ventilation wear suitable respiratory equipment. Prevent further leakage or spillage if safe to do so.

6 6/9 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Liquid Colour No data available Odour Pleasant Odour threshold No data available ph 6-8 Melting point No data available Initial boiling point No data available Flash point No data available Evaporation rate No data available Flammability (solid, gas) No data available Vapour pressure No data available Vapour density No data available Relative density No data available Partition coefficient No data available Autoignition temperature No data available 9.. Other information Viscosity No data available Explosive properties No data available Oxidising properties No data available Solubility Soluble in water Conductivity No data available Surface tension No data available Gas group No data available Benzene Content No data available Lead content No data available VOC (Volatile organic compounds) SECTION 10: Stability and reactivity Reactivity No data available date Stable under normal conditions. No specific reactivity hazards associated with this product Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products Stable under normal conditions. No particular stability concerns. Strong acids. Strong oxidising agents. Protect from frost. SECTION 11: Toxicological information Information on toxicological No incompatible groups noted. No Hazardous decomposition products when stored and handled correctly. Burning produces irritating, toxic and obnoxious fumes. Skin corrosion/irritation Irritating to skin.

7 7/9 date Information on toxicological Serious eye damage/irritation Respiratory or skin sensitisation Repeated or prolonged exposure Mixtures Hazard Information Toxicological Information SECTION 1: Ecological information 1.1. Toxicity 1.. Persistence and degradability Not anticipated under normal conditions of use. Causes serious eye damage. Not anticipated under normal conditions of use. Irritating to respiratory system. Irritating to skin. Prolonged contact may cause defatting of the skin. Irritating to eyes, respiratory system and skin. Irritating to mucous membranes. No data available. No data available. No data available No data available 1.3. Bioaccumulative potential Substance biodegrades at a moderate rate and inherently biodegradable according to the OECD guide lines. Partition coefficient No data available sodium hydroxide No data available 1.4. Mobility in soil 1.5. Results of PBT and vpvb assessment 1.6. Other adverse No data available. SECTION 13: Disposal considerations Waste treatment methods General information Disposal of packaging SECTION 14: Transport information UN number 14.. UN proper shipping name Dispose of waste and residues in accordance with local authority requirements. Dispose of in compliance with all local and national requirements. Do NOT reuse empty containers. Empty containers can be sent to landfill after cleaning, if in compliance with local and national regulations.

8 8/ Transport hazard class(es) Packing group Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture date Regulations REGULATION (EC) No 1907/006 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 18 December 006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 000/1/EC Chemical safety assessment SECTION 16: Other information Other information Text of risk phrases in Section 3 Text of Hazard Statements in Section 3 COMMISSION REGULATION (EU) No 453/010 of 0 May 010 amending Regulation (EC) No 1907/006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 000/1/EC. No information available. This document differs from the previous version in the following areas: Toxicity. R - Harmful if swallowed. R35 - Causes severe burns. R36/38 - Irritating to eyes and skin. R38 - Irritating to skin. R41 - Risk of serious damage to eyes. Skin Irrit. : H315 - Causes skin irritation. Eye Dam. 1: H318 - Causes serious eye damage. Aquatic Chronic : H411 - Toxic to aquatic life with long lasting. Aquatic Chronic 3: H41 - Harmful to aquatic life with long lasting. Eye Irrit. : H319 - Causes serious eye irritation. Skin Corr. 1A: H314 - Causes severe skin burns and eye damage. Acute Tox. 4: H30 - Harmful if swallowed. Acute Tox. 4: H30+H33 - Harmful if swallowed or if inhaled Labelling for contents non-ionic surfactants 0% - < 5% allergenic fragrances 0% - < 5% Further information The information supplied in this Safety Data Sheet is designed only as guidance for the safe use, storage and handling of the product. This information is correct to the best of our knowledge and belief at the date of publication however no guarantee is made to its accuracy. This information

9 9/9 date Further information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any other process.