SAFETY DATA SHEET according to 1907/2006/EC, Article 31

Transcription

1 SAFETY DATA SHEET according to 1907/2006/EC, Article 31 Page 1/ SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier date Product name REACH 1.3. Details of the supplier of the safety data sheet Company Address ALL INGREDIENTS IN THIS FORMULATION HAVE BEEN REGISTERED (WHERE REQUIRED) FOR APPLICABLE USES. Clairoy Maintenance Chemicals 29 Dyson Close, Rugby, Warwickshire CV21 4LG Web Telephone Fax Emergency telephone number Emergency telephone number Company SECTION 2: Hazards identification 2.1. Classification of the substance or mixture CLAIROY MAINTENANCE CHEMICALS NORMAL OFFICE HOURS Classification /4/ЕC Main hazards Classification - EC 1272/ Label elements Hazard pictograms C; R3 Symbols: C: Corrosive. Causes severe burns. Skin Corr. 1A: H314; Signal Word Hazard Statement Prevention Response Danger Skin Corr. 1A: H314 - Causes severe skin burns and eye damage. P260 - Do not breathe dust/fume/gas/mist/vapours/spray. P264 - Wash thoroughly after handling. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P301+P310 - IF SWALLOWED: IF SWALLOWED: Immediately call a POISON CENTER/doctor/. P301+P330+P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P303+P361+P33 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse Copyright 201 ChemSoft Limited. All rights reserved

2 date Page 2/ 2.2. Label elements Storage Disposal skin with water/shower. P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P30+P31+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 - If skin irritation or rash occurs: Get medical advice/attention. P337+P313 - If eye irritation persists: Get medical advice/attention. P363 - Wash contaminated clothing before reuse. P40 - Store locked up. P01 - Dispose of contents/container to requirements OF LOCAL AUTHORITIES SECTION 3: Composition/information on ingredients 3.2. Mixtures 67/48/EEC / 1999/4/EC Chemical Name Index No. CAS No. EC No. REACH Registration Number Conc. (%w/w) Classification Sulphuric acid % (Sulphuric acid % C; R3 (mist)) DYE 0-0.% M-factor. EC 1272/2008 Chemical Name Index No. CAS No. EC No. REACH Registration Number Conc. (%w/w) Classification Sulphuric acid % (Sulphuric acid % Skin Corr. 1A: H314; (mist)) DYE 0-0.% M-factor. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Eye contact Skin contact Ingestion May cause irritation to respiratory system. Seek medical attention if irritation or symptoms persist. Causes severe burns. Causes severe inflammation and may damage the cornea. Seek medical attention. Causes severe burns. Wash off immediately with plenty of soap and water. Remove contaminated clothing. Seek medical attention if irritation or symptoms persist. Ingestion causes burns to the respiratory tract. DO NOT INDUCE VOMITING. If swallowed, seek medical advice immediately and show this container or label. SECTION : Firefighting measures.1. Extinguishing media Use as appropriate: Carbon dioxide (CO2), Dry chemical, Foam..2. Special hazards arising from the substance or mixture Corrosive. Burning produces irritating, toxic and obnoxious fumes..3. Advice for firefighters Wear suitable respiratory equipment when necessary. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate personnel to a safe area. Wear suitable protective equipment Environmental precautions Do not allow product to enter drains. Prevent further spillage if safe. Copyright 201 ChemSoft Limited. All rights reserved

3 6.3. Methods and material for containment and cleaning up SECTION 7: Handling and storage 7.1. Precautions for safe handling date Page 3/ Absorb with inert, absorbent material. Transfer to suitable, labelled containers for disposal. Clean spillage area thoroughly with plenty of water. Avoid contact with eyes and skin Conditions for safe storage, including any incompatibilities SECTION 8: Exposure controls/personal protection 8.1. Control parameters Keep in a cool, dry, well ventilated area. Keep containers tightly closed Exposure Limit Values Sulphuric acid % (Sulphuric acid (mist)) WEL 8-hr limit ppm: - WEL 8-hr limit mg/m3: 0.0 WEL 1 min limit ppm: - WEL 1 min limit mg/m3: - WEL 8-hr limit mg/m3 total - WEL 1 min limit mg/m3 total - inhalable dust: inhalable dust: WEL 8-hr limit mg/m3 total - WEL 1 min limit mg/m3 total - respirable dust: respirable dust: 8.2. Exposure controls Appropriate engineering controls Individual protection measures Eye / face protection Skin protection - Handprotection Respiratory protection Not normally required. Wear chemical protective clothing. Approved safety goggles. Chemical resistant gloves (PVC). Not normally required. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Water solubility Appearance Liquid Colour Red Odour Mild ph 1.0 Relative density 1.8 NOMINAL SECTION 10: Stability and reactivity Chemical stability Soluble in water. SECTION 11: Toxicological information Information on toxicological effects Stable under normal conditions. REACTS WITH HYPOCHLORITES(BLEACH) TO GIVE OFF TOXIC FUMES OF CHLORINE. REACTS VIOLENTLY WHEN SMALL AMOUNTS OF WATER ARE ADDED TO THE PRODUCT. ALWAYS ADD PRODUCT TO WATER. Skin corrosion/irritation Causes burns. Causes severe burns. Risk of serious damage to eyes. Copyright 201 ChemSoft Limited. All rights reserved

4 Page 4/ SECTION 12: Ecological information Toxicity No data is available on this product Persistence and degradability date SECTION 13: Disposal considerations General information SECTION 14: Transport information Hazard pictograms Inorganic materials are inherently not boidegradable however those present in this formulation/product are either of no known significant environmetal hazard or are readilly neutralised to form inert salts. Dispose of in compliance with all local and national regulations UN number UN proper shipping name Transport hazard class(es) ADR/RID 8 IMDG 8 IATA Packing group Packing group 14.. Environmental hazards Environmental hazards Marine pollutant ADR/RID UN1830 SULPHURIC ACID II No No Hazard ID 80 Tunnel Category IMDG EmS Code IATA (E) Packing Instruction (Cargo) 8 Maximum quantity Packing Instruction (Passenger) Maximum quantity F-A S-B 30 L 81 1 L Copyright 201 ChemSoft Limited. All rights reserved

5 Page / SECTION 1: Regulatory information 1.2. Chemical safety assessment No chemical Safety assessment has been carried out by the supplier. SECTION 16: Other information Other information date Text of risk phrases in Section 3 Text of Hazard Statements in Section 3 Further information This document differs from the previous version in the following areas:. 1 - REACH. 2 - Response. R3 - Causes severe burns. Skin Corr. 1A: H314 - Causes severe skin burns and eye damage. The information supplied in this Safety Data Sheet is designed only as guidance for the safe use, storage and handling of the product. This information is correct to the best of our knowledge and belief at the date of publication however no guarantee is made to its accuracy. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any other process. Copyright 201 ChemSoft Limited. All rights reserved