Food industry: supplement

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1 SECTION 1: Identification 1.1. Identification Product form Substance name Chemical name Ferrous Fumarate Date of issue: 10/05/2015 Revision date: 10/05/2015 Supersedes: 06/01/2015 Version: 1.1 : Substance : Ferrous Fumarate : Iron (II) Fumarate CAS No : Product code : 2357, 2358, 2359, 2360, 2361, 2362, 2363, Formula : C 4H 4O 2Fe 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture 1.3. Details of the supplier of the safety data sheet Jost Chemical Co Lackland Rd. Saint Louis, Missouri T F justin.kuehnel@jostchemical.com Emergency telephone number : Food Additives in Nutrients Food industry: supplement Emergency number : CHEMTREC SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Not classified 2.2. Label elements GHS-US labeling No labeling applicable 2.3. Other hazards 2.4. Unknown acute toxicity (GHS US) Not applicable SECTION 3: Composition/Information on ingredients 3.1. Substance Substance type : Mono-constituent Full text of H-phrases: see section Mixture Not applicable SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Remove person to fresh air and keep comfortable for breathing. Move the affected person away from the contaminated area and into the fresh air. : Immediately remove contaminated clothing or footwear. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. : Immediately rinse with water for a prolonged period while holding the eyelids wide open. Consult an ophtalmologist if irritation persists. Rinse eyes with water as a precaution. : Drink plenty of water. Do NOT induce vomiting. Call a POISON CENTER or doctor/physician if you feel unwell. Call a poison center/doctor/physician if you feel unwell Most important symptoms and effects, both acute and delayed Symptoms/injuries after skin contact : May cause moderate irritation. Symptoms/injuries after eye contact : Slight irritation. 10/05/2015 EN (English US) Page 1

2 Symptoms/injuries after ingestion : Vomiting. Nausea. Feeling of weakness Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Carbon dioxide. Water spray. Dry powder. Foam Special hazards arising from the substance or mixture Fire hazard. Explosion hazard. Reactivity : The product is non-reactive under normal conditions of use, storage and transport Advice for firefighters Firefighting instructions Protection during firefighting : Cool down the containers exposed to heat with a water spray. Do not dispose of fire-fighting water in the environment. : Do not enter fire area without proper protective equipment, including respiratory protection. Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Protective equipment Emergency procedures For emergency responders Protective equipment : Protective clothing. Gloves. Safety glasses. See "Material-Handling" to select protective clothing. : Ventilate spillage area. Avoid contact with skin and eyes. : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection" Environmental precautions Avoid release to the environment. Prevent entry to sewers and public waters Methods and material for containment and cleaning up For containment : Collect all waste in suitable and labeled containers and dispose according to local legislation. Methods for cleaning up : Recover mechanically the product. Collect spillage. Take up liquid spill into absorbent material. This material and its container must be disposed of in a safe way, and as per local legislation. Clean contaminated surfaces with an excess of water. Caution : this product can cause the floor to be very slippery. Other information : Dispose of materials or solid residues at an authorized site Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Ensure good ventilation of the work station. Wear personal protective equipment. : Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Storage conditions : Store in a well-ventilated place. Keep cool. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Appropriate engineering controls : Extraction to remove dust at its source. Ensure good ventilation of the work station. 10/05/2015 EN (English US) 2/6

3 Personal protective equipment : Dust/aerosol mask with filter type P1. Gloves. Safety glasses. Materials for protective clothing : Wear suitable protective clothing, gloves and eye/face protection. Hand protection : protective gloves. Eye protection : Chemical goggles or safety glasses. Safety glasses. Skin and body protection : Wear suitable protective clothing. Respiratory protection : Dust production: dust mask with filter type P1. Environmental exposure controls : Avoid release to the environment. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Appearance : Powder. Color : red orange Odor : odorless Odor threshold ph : 5-6 ph solution : 25 g/l (20 C) Melting point : > 280 C Freezing point Boiling point Flash point Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) Explosion limits Explosive properties Oxidizing properties Vapor pressure Relative density Relative vapor density at 20 C Molecular mass : g/mol Solubility : Partially soluble. Log Pow Auto-ignition temperature Decomposition temperature Viscosity Viscosity, kinematic Viscosity, dynamic 9.2. Other information SECTION 10: Stability and reactivity Reactivity The product is non-reactive under normal conditions of use, storage and transport Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use. 10/05/2015 EN (English US) 3/6

4 10.4. Conditions to avoid None under recommended storage and handling conditions (see section 7) Incompatible materials Hazardous decomposition products Thermal decomposition generates : Iron oxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion SECTION 12: Ecological information Toxicity Ecology - general (Based on available data, the classification criteria are not met) (Based on available data, the classification criteria are not met) ph: 5-6 (Based on available data, the classification criteria are not met) ph: 5-6 : May cause moderate irritation. : Slight irritation. : Vomiting. Nausea. Feeling of weakness. : The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects Effect on the global warming : No known ecological damage caused by this product. 10/05/2015 EN (English US) 4/6

5 SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Not regulated for transport : Dispose in a safe manner in accordance with local/national regulations. TDG TDG Proper Shipping Name Transport by sea Proper Shipping Name (IMDG) Air transport Proper Shipping Name (IATA) : Not regulated for transport : Not regulated for transport : Not regulated for transport SECTION 15: Regulatory information US Federal regulations Ferrous Fumarate ( ) Listed on the United States TSCA (Toxic Substances Control Act) inventory All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory This product or mixture does not contain a toxic chemical or chemicals in excess of the applicable de minimis concentration as specified in 40 CFR (a) subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part International regulations CANADA EU-Regulations National regulations Ferrous Fumarate ( ) Listed on the AICS (Australian Inventory of Chemical Substances) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on the Korean ECL (Existing Chemicals List) Listed on INSQ (Mexican national Inventory of Chemical Substances) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) US State regulations California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental and/or reproductive harm SECTION 16: Other information Indication of changes : This sheet was updated (refer to the date at the top of this page). Revision date : 10/05/ /05/2015 EN (English US) 5/6

6 NFPA health hazard NFPA fire hazard NFPA reactivity : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given. : 0 - Materials that will not burn. : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. HMIS III Rating Health Flammability Physical : 1 Slight Hazard - Irritation or minor reversible injury possible : 0 Minimal Hazard - Materials that will not burn : 0 Minimal Hazard - Materials that are normally stable, even under fire conditions, and will NOT react with water, polymerize, decompose, condense, or self-react. Non-Explosives. SDS US (GHS HazCom 2012) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 10/05/2015 EN (English US) 6/6

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