: Ferrous Fumarate. Food industry: supplement Emergency telephone number Country Organisation/Company Address Emergency number Comment

Transcription

1 Date of issue:11/3/2015 Revision date:11/3/2015 Supersedes:7/2/2015 Version: 4.3 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Substance Substance name : Ferrous Fumarate Chemical name : Iron (II) Fumarate EC no : CAS No : Product code : 2357, 2358, 2359, 2360, 2361, 2362, 2363, Formula : C4H4O2Fe 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use of the substance/mixture : Food Additives in Nutrients Food industry: supplement Uses advised against 1.3. Details of the supplier of the safety data sheet Supplier JOST CHEMICAL EUROPE SPRL rue du Bois Portal n 30/1-3 B Andenne - BELGIQUE T F info@josteurope.com Manufacturer Jost Chemical Co Lackland Rd Saint Louis, Missouri T F justin.kuehnel@jostchemical.com Emergency telephone number Country Organisation/Company Address Emergency number Comment United Kingdom National Poisons Information Service (Birmingham Centre) City Hospital Dudley Road B18 7QH Birmingham UK only, Monday to Friday, to hours SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixture/Substance: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II) Not classified 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Child-resistant fastening Tactile warning 2.3. Other hazards Adverse physicochemical, human health and environmental effects PBT: not yet assessed vpvb: not yet assessed : To our knowledge, this product does not present any particular risk, provided it is handled in accordance with good occupational hygiene and safety practice. SECTION 3: Composition/information on ingredients 3.1. Substance Substance type : Mono-constituent Name : Ferrous Fumarate CAS No : EC no : /3/2015 EN (English) 1/6

2 Name Product identifier % Ferrous Fumarate (CAS No) (EC no) Full text of H-statements: see section Mixture Not applicable SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Remove person to fresh air and keep comfortable for breathing. Move the affected person away from the contaminated area and into the fresh air. : Immediately remove contaminated clothing or footwear. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. : Immediately rinse with water for a prolonged period while holding the eyelids wide open. Consult an ophthalmologist if irritation persists. Rinse eyes with water as a precaution. : Drink plenty of water. Do NOT induce vomiting. Call a POISON CENTER or doctor/physician if you feel unwell. Call a poison center or a doctor if you feel unwell Most important symptoms and effects, both acute and delayed Symptoms/injuries after skin contact : May cause moderate irritation. Symptoms/injuries after eye contact : Slight irritation. Symptoms/injuries after ingestion : Vomiting. Nausea. Feeling of weakness Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Carbon dioxide. Water spray. Dry powder. Foam Special hazards arising from the substance or mixture Fire hazard. Explosion hazard. Hazardous decomposition products in case of : Toxic fumes may be released. fire 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Cool down the containers exposed to heat with a water spray. Do not dispose of fire-fighting water in the environment. : Do not enter fire area without proper protective equipment, including respiratory protection. Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Protective equipment Emergency procedures For emergency responders Protective equipment : Protective clothing. Gloves. Safety glasses. See "Material-Handling" to select protective clothing. : Ventilate spillage area. Avoid contact with skin and eyes. : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection" Environmental precautions Avoid release to the environment. Prevent entry to sewers and public waters Methods and material for containment and cleaning up For containment : Collect all waste in suitable and labelled containers and dispose according to local legislation. Methods for cleaning up : Recover mechanically the product. Collect spillage. Take up liquid spill into absorbent material. This material and its container must be disposed of in a safe way, and as per local legislation. Clean contaminated surfaces with an excess of water. Caution : this product can cause the floor to be very slippery. Other information : Dispose of materials or solid residues at an authorized site Reference to other sections For further information refer to section /3/2015 EN (English) 2/6

3 SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Ensure good ventilation of the work station. Wear personal protective equipment. : Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Storage conditions : Store in a well-ventilated place. Keep cool Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Appropriate engineering controls Personal protective equipment Materials for protective clothing Hand protection Eye protection Skin and body protection Respiratory protection : Extraction to remove dust at its source. Ensure good ventilation of the work station. : Dust/aerosol mask with filter type P1. Gloves. Safety glasses. : Wear suitable protective clothing, gloves and eye/face protection : Impermeable protective gloves : Chemical goggles or safety glasses : Wear suitable protective clothing : Dust production: dust mask with filter type P1 Environmental exposure controls : Avoid release to the environment. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Appearance : Powder. Molecular mass : g/mol Colour : red. orange. Odour : odourless. Odour threshold ph : 5-6 ph solution : 25 g/l (20 C) Relative evaporation rate (butylacetate=1) Melting point : > 280 C Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) n flammable Vapour pressure Relative vapour density at 20 C Relative density Solubility : Partially soluble. Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties 11/3/2015 EN (English) 3/6

4 Oxidising properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity The product is non-reactive under normal conditions of use, storage and transport Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid None under recommended storage and handling conditions (see section 7) Incompatible materials Hazardous decomposition products Thermal decomposition generates : Iron oxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Ferrous Fumarate ( ) LD50 oral rat Causes serious eye damage Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard 3850 mg/kg (Published Data) t classified (Based on available data, the classification criteria are not met) ph: 5-6 t classified (Based on available data, the classification criteria are not met) ph: 5-6 SECTION 12: Ecological information Toxicity Ecology - general : The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Component Ferrous Fumarate ( ) PBT: not yet assessed vpvb: not yet assessed Other adverse effects 11/3/2015 EN (English) 4/6

5 SECTION 13: Disposal considerations Waste treatment methods Waste treatment methods Waste disposal recommendations SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN : Dispose of contents/container in accordance with licensed collector s sorting instructions. : Dispose in a safe manner in accordance with local/national regulations UN number Not regulated for transport UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport hazard class(es) ADR Transport hazard class(es) (ADR) IMDG Transport hazard class(es) (IMDG) IATA Transport hazard class(es) (IATA) ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information supplementary information available Special precautions for user - Overland transport - Transport by sea - Air transport - Inland waterway transport - Rail transport Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable 11/3/2015 EN (English) 5/6

6 SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations No REACH Annex XVII restrictions Ferrous Fumarate is not on the REACH Candidate List Contains no substance on the REACH candidate list Ferrous Fumarate is not on the REACH Annex XIV List Contains no REACH Annex XIV substances National regulations Listed on the AICS (Australian Inventory of Chemical Substances) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on the Korean ECL (Existing Chemicals List) Listed on INSQ (Mexican national Inventory of Chemical Substances) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Listed on the United States TSCA (Toxic Substances Control Act) inventory Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Indication of changes: This sheet was updated (refer to the date at the top of this page). SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 11/3/2015 EN (English) 6/6