: Long Iron with UMAXX

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1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name : Mixture Product code : : Long Iron with UMAXX 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet Harrell's 720 Kraft Rd. Lakeland, Fl, T Emergency telephone number Emergency number : ChemTrec SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Skin Irrit. 2 Eye Irrit. 2B Carc. Not classified Aquatic Acute 2 H315 H320 H Label elements GHS-US labelling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) GHS07 : Warning : H315 - Causes skin irritation H320 - Causes eye irritation H401 - Toxic to aquatic life : P264 - Wash... thoroughly after handling P273 - Avoid release to the environment P280 - Wear protective gloves/protective clothing/eye protection/face protection P302+P352 - IF ON SKIN: Wash with plenty of soap and water P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P321 - Specific treatment (see... on this label) P332+P313 - If skin irritation occurs: Get medical advice/attention P337+P313 - If eye irritation persists: Get medical advice/attention P362 - Take off contaminated clothing and wash before reuse P501 - Dispose of contents/container to Other hazards 2.4. Unknown acute toxicity (GHS-US) No data available SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 04/16/2015 EN (English) Page 1

2 Full text of H-phrases: see section Mixture Name Product identifier % GHS-US classification iron(ii) sulfate, heptahydrate (CAS No) Acute Tox. 4 (Oral), H302 Aquatic Acute 2, H401 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Assure fresh air breathing. Allow the victim to rest. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : May cause cancer by inhalation. Symptoms/injuries after eye contact : Causes serious eye irritation Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store aways from other materials. 04/16/2015 EN (English) 2/7

3 SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. : Wash... thoroughly after handling Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials : Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. : Strong bases. Strong acids. : Sources of ignition. Direct sunlight. Storage temperature : >= 25 (5-42) C 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters USA ACGIH ACGIH TWA (mg/m³) 1 mg/m³ 8.2. Exposure controls Personal protective equipment Hand protection Eye protection Respiratory protection : Avoid all unnecessary exposure. : Wear protective gloves. : Chemical goggles or safety glasses. : Wear appropriate mask. : Do not eat, drink or smoke during use. 04/16/2015 EN (English) 3/7

4 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Colour Odour Odour threshold : Liquid : Green. ph : <= 2 Relative evaporation rate (butylacetate=1) Melting point : Characteristic odour. Freezing point : <= 0 C Boiling point : >= 100 C Flash point Self ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Density Solubility Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits : None : >= g/ml : Soluble in water VOC content : <= 10 g/l SECTION 10: Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong bases Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 oral rat 1480 mg/kg (Rat) 04/16/2015 EN (English) 4/7

5 Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) : Causes skin irritation. ph: <= 2 : Causes eye irritation. ph: <= 2. Specific target organ toxicity (repeated exposure) Aspiration hazard Potential Adverse human health effects and symptoms Symptoms/injuries after inhalation Symptoms/injuries after eye contact SECTION 12: Ecological information Toxicity Ecology - water LC50 fishes 1 EC50 Daphnia 1 LC50 fish 2 EC50 Daphnia 2 : Based on available data, the classification criteria are not met. : May cause cancer by inhalation. : Causes serious eye irritation. : Toxic to aquatic life. 925 mg/l (96 h; Poecilia reticulata) 7.2 mg/l (48 h; Daphnia magna; Metal ion) > 200 mg/l (48 h; Leuciscus idus) 152 mg/l (48 h; Daphnia magna; Anhydrous form) Persistence and degradability Long Iron with UMAXX Persistence and degradability Persistence and degradability Biodegradability in water: no data available. Biodegradability in soil: no data available. Adsorbs into the soil Bioaccumulative potential Long Iron with UMAXX Bioaccumulative potential Bioaccumulative potential Not bioaccumulative Mobility in soil Other adverse effects : Avoid release to the environment. SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations Ecology - waste materials SECTION 14: Transport information In accordance with DOT No dangerous good in sense of transport regulations : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to... : Avoid release to the environment. 04/16/2015 EN (English) 5/7

6 Additional information : No supplementary information available. ADR Transport document description : Transport by sea Air transport SECTION 15: Regulatory information US Federal regulations Not listed on the United States TSCA (Toxic Substances Control Act) inventory RQ (Reportable quantity, section 304 of EPA's 1000 lb List of Lists) : International regulations CANADA EU-Regulations Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC or 1999/45/EC Not classified National regulations US State regulations U.S. - Pennsylvania - RTK (Right to Know) List SECTION 16: : None. Full text of H-phrases: see section 16: Acute Tox. 4 (Oral) Acute toxicity (oral), Category Aquatic Acute 2 Hazardous to the aquatic environment AcuteHazard, Category Carc. Not classified Carcinogenicity Not classified Eye Irrit. 2B Serious eye damage/eye irritation, Category 2B Skin Irrit. 2 Skin corrosion/irritation, Category H302 Harmful if swallowed H315 Causes skin irritation H320 Causes eye irritation H401 Toxic to aquatic life 04/16/2015 EN (English) 6/7

7 NFPA health hazard NFPA fire hazard NFPA reactivity NFPA specific hazard : 2 - Intense or continued exposure could cause temporary incapacitation or possible residual injury unless prompt medical attention is given. : 0 - Materials that will not burn. : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. : None HMIS III Rating Health Flammability Physical Personal Protection : 2 Moderate Hazard - Temporary or minor injury may occur : 0 Minimal Hazard : 0 Minimal Hazard : C SDS US (GHS HazCom 2012) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 04/16/2015 EN (English) 7/7

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