THE POSSIBILITY OF CREATING BIORAFINERY IN POLISH BIOECONOMY

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1 THE POSSIBILITY OF CREATING BIORAFINERY IN POLISH BIOECONOMY Krzysztof Biernat Ph.D Coordinator of Polish Technology Platform for Biofuels Deputy Director of Institute for Ecology and Bioethics of CSW Automotive Industry Institute PROJECT CO-FINANCED BY THE EUROPEAN REGIONAL DEVELOPMENT FOUND UNDER THE INNOVATIVE ECONOMY OPERATIONAL PROGRAMME

2 BIOREFINERY DEFINITION The integrated "bio-economy industrial plant", applying a variety of technologies in order to obtain products such as chemicals, biofuels, food, feed ingredients, biomaterials (including fibers) and heat and power, striving for maximize the added value, taking into account the three pillars of sustainability: environment, economy and society. 2

3 BIOREFINERY SYSTEM The object, which is able to carry out the biomass conversion to products for the fuels, energy, and chemicals production. Corresponding to oil refineries one substrate many products 3

4 TECHNOLOGY PATHWAYS 4

5 DIFFERENT BIOREFINERY CONCEPTS whole-crop biorefinery; green biorefinery; lignorefinery; two-platforms biorefinery; waste biorefinery (WtL&WtE processes); biorafinery using existing infrastructure of conventional oil refinery. 5

6 MAIN TARGETS (1) Complex processing of biomass and residues into a spectrum of chemical products with the highest possible efficiency Implementation of biorefinery concept into existing oil refinery technology with taking into account technological, logistic, ecological and social aspects Technology of conversion solid biomass and residues into liquid form and complex sustainable processing into biofuel and value-added products 6

7 MAIN TARGETS (2) Adaptation of existing oil refinery technology (distillation, refination, thermal and cathalytical cracking, hydrogenation processes) for converting of purified and liquid feedstock (biooil) into biofuel for car engines and power plants Biorefineries using potential of existing small oil refineries can be beneficial for region development by using local feedstocks and human resources 7

8 A BLOCK DIAGRAM 8

9 HTU TECHNOLOGY DIAGRAM 9

10 DISTRIBUTION OF PYROLYSIS PRODUCTS 20% Gas Biocarbon 30% 50% Biooil 10

11 BACKGROUND OF CONCEPTION In Poland there is a few low-efficient oil refineries, which untapped technological, infrastructure and human potential could be used with biorefinery complex building. The potential can be used with further processing and refine processed biomass to the liquid form. Planned undertaking widely reduces capital costs and enable of chemical substances obtaining and biofuels production, which are fulfill modern engines and heat devices qualitative requirements. That s why it assumed to build an experimental biorefinery using technology potential of little oil refinery in Poland. 11

12 R&D MAIN PROBLEM Optimisation of biomass and residues pirolysis processes or new biomass conversion processes Technology of production value-added co-products Adaptation of existing production technologies for converting bio-oil into biofuels, also second generation biofuels Technology of converting co-products into marketable products 12

13 SELEKTIVE PYROLISIS/FURFURAL ROUTE 13

14 FURFURAL APPLICATION Currently China is at the forefront of production and consumption of furfural (over 80% of global capacity and 72% of world consumption in 2010). 88% of the furfural produced is used for the synthesis of furfuryl alcohol, which has many important industrial applications. FF is used also as a solvent in lubricating oils and butadiene extractions (5% of total use). Furfural is not miscible with gasoline and diesel fuel, is not chemically stable but its derivatives obtained through catalytic conversion can be used as alternative fuels and fuel components. 14

15 WILLOW TG/DTG ANALYSIS 15

16 THE LAB-SCALE SELECTIVE PYROLISYS 1,6 g biomass pretreated with 5% ZnCl2 aq solution was used in each experiment after sonication and drying Pyrolysis was carried out in flowing pipe reactor, prior to the experiment the sample was flushed with 50 ml/min N2 (99,995% Airproducts) for 1h, followed by heating up to 600 C with rate of 100 K/min Vapours were condensated in ice-water mixture. In typical experiment was obtained 0,8 g of liquid products, 0,5 g of biocarbon and 0,3 g of gas products like: chlorometane, furans, 2-metylofuran, hydrogen and methane 16

17 THANK YOU FOR YOUR ATTENTION 17

18 reception : office: fax.: Jagiellońska 55 Str Warszawa Poland info@pimot.eu Krzysztof Biernat tel.: k.biernat@pimot.eu PROJECT CO-FINANCED BY THE EUROPEAN REGIONAL DEVELOPMENT FOUND UNDER THE INNOVATIVE ECONOMY OPERATIONAL PROGRAMME

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