Safety Data Sheet. according to Regulation (EC) No 1907/2006. Sauna-Duft-Konzentrat Eucalyptus extra stark

Transcription

1 Page 1 of 8 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture Dosage: 10 give ml on 1 litre of water, well mix. 1.. Details of the supplier of the safety data sheet Company name: Street: Place: Post-office box: Marburger Str Alsfeld Alsfeld Telephone: Telefax: Contact person: Internet: Responsible Department: info@finnsa.de Uwe Helm finnsa.de Verkauf 1.4. Emergency telephone number: Giftinformationszentrum (GIZ) der Länder Rheinland-Pfalz und Hessen SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Indications of danger: Xi - Irritant, N - Dangerous for the environment R phrases: Flammable. Irritating to eyes. May cause sensitisation by skin contact. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Vapours may cause drowsiness and dizziness. GHS classification Hazard categories: Flammable liquid: Flam. Liq. Respiratory/skin sensitization: Skin Sens. 1 Specific target organ toxicity - single exposure: STOT SE 2 Hazardous to the aquatic environment: Aquatic Chronic 2 Hazard Statements: Flammable liquid and vapour. May be harmful if swallowed. May cause an allergic skin reaction. May cause damage to organs (lung). Toxic to aquatic life with long lasting effects Label elements Hazardous components which must be listed on the label Limonen Signal word: Pictograms: Warning GHS02-GHS07-GHS08-GHS09

2 Page 2 of 8 Hazard statements H226 H0 H17 H71 H411 Flammable liquid and vapour. May be harmful if swallowed. May cause an allergic skin reaction. May cause damage to organs (lung). Toxic to aquatic life with long lasting effects. Precautionary statements P261 Avoid breathing smoke. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P2 Keep container tightly closed. P270 Do no eat, drink or smoke when using this product. P272 Contaminated work clothing should not be allowed out of the workplace. P27 Avoid release to the environment. P01+P0+P1 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P280 Wear protective gloves/protective clothing/eye protection/face protection. P0+P61+P5 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P52 Wash with plenty of water. P6 Wash contaminated clothing before reuse. P09+P11 IF exposed or if you feel unwell: Call a POISON CENTER or doctor/physician. P70+P78 In case of fire: Use CO2 to extinguish. P40+P25 Store in a well-ventilated place. Keep cool. P405 Store locked up. Special labelling of certain mixtures EUH208 Contains propan-2-ol; isopropyl alcohol; isopropanol, Limonen. May produce an allergic reaction. SECTION : Composition/information on ingredients.2. Mixtures

3 Page of 8 Hazardous components EC No CAS No Index No REACH No Chemical name Classification GHS classification isopropanol, isopropyl alcohol, propan-2-ol F - Highly flammable, Xi - Irritant R Quantity 25 - < 0 % Limonen Xn - Harmful, Xi - Irritant, N - Dangerous for the environment R Flam. Liq., Skin Irrit. 2, Skin Sens. 1, STOT SE 1, Asp. Tox. 1, Aquatic Chronic 1; H226 H15 H17 H70 H04 H410 L-Menthol Xi - Irritant R8 Skin Irrit. 2; H15 p-cymol Xn - Harmful, N - Dangerous for the environment R Flam. Liq., Asp. Tox. 1, Aquatic Chronic 2; H226 H04 H411 p-mentha-1,4(8)-dien Xn - Harmful, N - Dangerous for the environment R ,99 % 1 - < 5 % 1-2,49 % 1,-2,49 % Full text of R and H phrases: see Section 16. SECTION 4: First aid measures 4.1. Description of first aid measures General information If victim is at risk of losing consciousness, position and transport on their side. After inhalation Provide fresh air. Seek medical attention if problems persist. After contact with skin After contact with skin, wash immediately with: Water and soap. After contact with eyes In case of contact with eyes, rinse immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart. In case of troubles or persistent symptoms, consult an ophthalmologist. After ingestion Seek medical attention if problems persist. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Carbon dioxide (CO2). Dry extinguishing powder. Foam. Unsuitable extinguishing media High power water jet Special hazards arising from the substance or mixture In case of fire and/or explosion do not breathe fumes.

4 Page 4 of 8 SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Remove all sources of ignition Environmental precautions Do not allow to enter into surface water or drains. SECTION 7: Handling and storage 7.1. Precautions for safe handling Advice on safe handling Use only in well-ventilated areas. Keep away from sources of ignition. - No smoking. Advice on protection against fire and explosion Take precautionary measures against static discharge Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels Keep container tightly closed and in a well-ventilated place. Further information on storage conditions Protect against: heat. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Exposure limits (EH40) CAS No Substance ppm mg/m³ fibres/ml Category Origin Propan-2-ol TWA (8 h) WEL STEL (15 min) WEL Propane-1,2-diol, particulates - 10 TWA (8 h) WEL 8.2. Exposure controls - - STEL (15 min) WEL Protective and hygiene measures Keep away from food, drink and animal feedingstuffs. Take off immediately all contaminated clothing. Eye/face protection.tightly sealed safety glasses. Hand protection Before using check leak tightness / impermeability. The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working place concentration and quantity of hazardous substances. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves. Respiratory protection Respiratory protection necessary at: insufficient ventilation.work in well-ventilated zones or use proper respiratory protection. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state: Colour: liquid: colourless

5 Page 5 of 8 Odour: characteristic ph-value (at 20 C): 5-6 Test method Changes in the physical state Melting point: Initial boiling point and boiling range: Sublimation point: Flash point: Explosive properties not Explosive. Lower explosion limits: Upper explosion limits: Vapour pressure: Vapour pressure: Density: Water solubility: No data available 24 C 0,88 g/cm³ Immiscible SECTION 10: Stability and reactivity Conditions to avoid Hazardous decomposition products Further information No risks worthy of mention. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Irritant effect on the skin: Not an irritant. Irritant effect on the eye: Not an irritant. CAS No Chemical name Exposure routes Method isopropanol, isopropyl alcohol, propan-2-ol oral dermal Dose LD mg/kg LD mg/kg Species Ratte Kaninchen inhalative vapour LC ,5 mg/l Ratte Source Sensitising effects weakly sensibilizing. Additional information on tests The evaluation was carried out according to the calculation method of the Preparations Directive. Irritant. - Mutagen - Carcinogenicity

6 Page 6 of 8 - Teratogen - Phototoxicity SECTION 12: Ecological information Toxicity Toxic to fish Persistence and degradability No information available Bioaccumulative potential No information available Mobility in soil No information available Results of PBT and vpvb assessment not applicable Other adverse effects No information available. Further information 2 hazardous to water (WGK 2) Do not allow to enter into surface water or drains. SECTION 1: Disposal considerations 1.1. Waste treatment methods Advice on disposal Do not allow to enter into surface water or drains. Contaminated packaging Dispose of waste according to applicable legislation. Cleaning agent. Water (with cleaning agent). SECTION 14: Transport information Land transport (ADR/RID) UN number: UN UN proper shipping name: 14.. Transport hazard class(es): Packing group: Hazard label: Classification code: Limited quantity: Hazard No: Tunnel restriction code: FLAMMABLE LIQUID, N.O.S. (ISOPROPANOL (ISOPROPYL ALKOHOL)) III F1 LQ7 D/E Other applicable information (land transport) Special provisions: H E1 Transport category: Tunnel restriction code: D/E Marine transport (IMDG)

7 Page 7 of UN number: UN UN proper shipping name: 14.. Transport hazard class(es): Packing group: Hazard label: Marine pollutant: Limited quantity: EmS: FLAMMABLE LIQUID, N.O.S. (ISOPROPANOL (ISOPROPYL ALCOHOL)) III 5 L F-E, S-E Other applicable information (marine transport) Special provisions: 22, 0, 274, 944, 955 Air transport (ICAO) UN number: UN UN proper shipping name: 14.. Transport hazard class(es): Packing group: Hazard label: Limited quantity Passenger: IATA-packing instructions - Passenger: IATA-max. quantity - Passenger: IATA-packing instructions - Cargo: IATA-max. quantity - Cargo: Other applicable information (air transport) E1 Y L Environmental hazards ENVIRONMENTALLY HAZARDOUS: Special precautions for user Flammable liquids FLAMMABLE LIQUID, N.O.S. (ISOPROPANOL (ISOPROPYL ALCOHOL)) III 10 L yes L L Transport in bulk according to Annex II of MARPOL7/78 and the IBC Code not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture National regulatory information Water contaminating class (D): 2 - water contaminating SECTION 16: Other information Full text of R phrases referred to under Sections 2 and 10 Flammable. 11 Highly flammable. 6 Irritating to eyes. 8 Irritating to skin. 4 May cause sensitisation by skin contact. 50 Very toxic to aquatic organisms. 51 Toxic to aquatic organisms.

8 Page 8 of 8 51/5 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 52 Harmful to aquatic organisms. 5 May cause long-term adverse effects in the aquatic environment. 65 Harmful: may cause lung damage if swallowed. 67 Vapours may cause drowsiness and dizziness. Full text of H statements referred to under Sections 2 and H226 Flammable liquid and vapour. H0 May be harmful if swallowed. H04 May be fatal if swallowed and enters airways. H15 Causes skin irritation. H17 May cause an allergic skin reaction. H70 Causes damage to organs. H71 May cause damage to organs (lung). H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. (The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.)