SECTION 1: Identification of the substance/mixture and of the company/undertaking

Transcription

1 Safety data sheet Page: 1/14 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Etingal S 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses: defoamer 1.3. Details of the supplier of the safety data sheet Company: BASF SE Ludwigshafen GERMANY Paper Chemicals Division Telephone: address: Paper-Chemicals@basf.com 1.4. Emergency telephone number International emergency number: Telephone: SECTION 2: Hazards Identification 2.1. Classification of the substance or mixture According to Regulation (EC) No 1272/2008 [CLP] Eye Dam./Irrit. 2 Skin Sens. 1 According to Directive 67/548/EEC or 1999/45/EC

2 Page: 2/14 Possible Hazards: Irritating to eyes. May cause sensitization by skin contact. For the classifications not written out in full in this section the full text can be found in section Label elements Globally Harmonized System, EU (GHS) Pictogram: Signal Word: Warning Hazard Statement: H319 H317 Causes serious eye irritation. May cause an allergic skin reaction. Precautionary Statements (Prevention): P280f Wear protective gloves and eye/face protection. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P272 Contaminated work clothing should not be allowed out of the workplace. P264 Wash with plenty of water and soap thoroughly after handling. Precautionary Statements (Response): P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P311 If skin irritation or rash occurs: Call a POISON CENTER or doctor/physician. P303 + P352 IF ON SKIN (on hair): Wash with plenty of soap and water. P362 Take off contaminated clothing and wash before reuse. P337 + P311 If eye irritation persists: Call a POISON CENTER or doctor/physician. Precautionary Statements (Disposal): P501 Dispose of contents/container to hazardous or special waste collection point. According to Regulation (EC) No 1272/2008 [CLP] Hazard determining component(s) for labelling: TRIISOBUTYLPHOSPHATE According to Directive 67/548/EEC or 1999/45/EC Directive 1999/45/EC ('Preparation Directive')

3 Page: 3/14 Hazard symbol(s) Xi Irritant. R-phrase(s) R36 R43 S-phrase(s) S26 S37 Irritating to eyes. May cause sensitization by skin contact. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves. Hazard determining component(s) for labelling: TRIISOBUTYLPHOSPHATE 2.3. Other hazards According to Regulation (EC) No 1272/2008 [CLP] If applicable information is provided in this section on other hazards which do not result in classification but which may contribute to the overall hazards of the substance or mixture. SECTION 3: Composition/Information on Ingredients 3.1. Substances 3.2. Mixtures Chemical nature alkyl phosphate, non-ionic surfactants Hazardous ingredients (GHS) according to Regulation (EC) No. 1272/2008 triisobutyl phosphate Content (W/W): >= 83 % - <= 88 % CAS Number: EC-Number: REACH registration number: Skin Sens. 1B H317 Poly(oxy-1,2-ethanediyl),.alpha.-(1-oxo-9-octadecenyl)-.omega.-hydroxy-,(Z)- / Ref.No.:

4 Page: 4/14 Content (W/W): >= 8 % - <= 13 % Skin Corr./Irrit. 2 H315 Hazardous ingredients according to Directive 1999/45/EC triisobutyl phosphate Content (W/W): >= 83 % - <= 88 % CAS Number: EC-Number: REACH registration number: Hazard symbol(s): Xi R-phrase(s): 43 Poly(oxy-1,2-ethanediyl),.alpha.-(1-oxo-9-octadecenyl)-.omega.-hydroxy-,(Z)- / Ref.No.: Content (W/W): >= 8 % - <= 13 % Hazard symbol(s): Xi R-phrase(s): 38 For the classifications not written out in full in this section, including the indication of danger, the hazard symbols, the R phrases, and the hazard statements, the full text is listed in section 16. SECTION 4: First-Aid Measures 4.1. Description of first aid measures Immediately remove contaminated clothing. If inhaled: If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical attention. On skin contact: Wash thoroughly with soap and water. On contact with eyes: Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist. On ingestion: Rinse mouth immediately and then drink plenty of water, seek medical attention Most important symptoms and effects, both acute and delayed Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11. Hazards: No hazard is expected under intended use and appropriate handling.

5 Page: 5/ Indication of any immediate medical attention and special treatment needed Treatment: Treat symptomatically. SECTION 5: Fire-Fighting Measures 5.1. Extinguishing media Suitable extinguishing media: water spray, dry powder, foam 5.2. Special hazards arising from the substance or mixture No particular hazards known Advice for fire-fighters Special protective equipment: Wear a self-contained breathing apparatus. Further information: Contain contaminated water/firefighting water. SECTION 6: Accidental Release Measures 6.1. Personal precautions, protective equipment and emergency procedures Breathing protection required Environmental precautions Do not empty into drains Methods and material for containment and cleaning up For small amounts: Pick up with suitable absorbent material. Dispose of absorbed material in accordance with regulations Reference to other sections Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13. SECTION 7: Handling and Storage 7.1. Precautions for safe handling Ensure thorough ventilation of stores and work areas. Protection against fire and explosion: Take precautionary measures against static discharges Conditions for safe storage, including any incompatibilities

6 Page: 6/14 Further information on storage conditions: Keep container tightly closed and dry; store in a cool place. Protect from temperatures below: 5 C Protect from temperatures above: 40 C 7.3. Specific end use(s) For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed. SECTION 8: Exposure Controls/Personal Protection 8.1. Control parameters Components with PNEC : Triisobutyl phosphate freshwater: mg/l marine water: mg/l intermittent release: 0.11 mg/l STP: 3.72 mg/l sediment (freshwater): 1.58 mg/kg sediment (marine water): mg/kg soil: mg/kg oral (secondary poisoning): No PNEC oral derived, as accumulation in organisms is not to be expected. Components with DNEL : Triisobutyl phosphate worker: Long-term exposure- systemic effects, Inhalation: 6.03 mg/m3 worker: Long-term exposure- systemic effects, dermal: 1.71 mg/kg consumer: Long-term exposure- systemic effects, oral: 0.86 mg/kg consumer: Long-term exposure- systemic effects, Inhalation: 1.49 mg/m3 consumer: Long-term exposure- systemic effects, dermal: 0.86 mg/kg 8.2. Exposure controls Personal protective equipment Respiratory protection: Suitable respiratory protection for higher concentrations or long-term effect: Gas filter for gases/vapours of organic compounds (boiling point >65 C, e. g. EN Type A) Hand protection: Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) and other Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g.

7 Page: 7/14 temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing. Eye protection: Safety glasses with side-shields (frame goggles) (e.g. EN 166) Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN in case of splashes or EN ISO in case of dust). General safety and hygiene measures Do not inhale gases/vapours/aerosols. Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment. SECTION 9: Physical and Chemical Properties 9.1. Information on basic physical and chemical properties Form: emulsion Colour: yellowish Odour: product specific Odour threshold: No data available. ph value: approx. 5 (20 C) solidification temperature: No data available. Boiling point: 264 C Flash point: 125 C (DIN 51758) Evaporation rate: No data available. Flammability: not applicable Lower explosion limit: For liquids not relevant for classification and labelling., The lower explosion point may be 5-15 C below the flash point. Upper explosion limit: For liquids not relevant for classification and labelling. Ignition temperature: > 200 C (DIN 51794) Vapour pressure: No data available. Density: g/cm3 (DIN 53217) (25 C) Relative density: No data available. Solubility in water: emulsifiable

8 Page: 8/14 Solubility (qualitative) solvent(s): organic solvents miscible Partitioning coefficient n-octanol/water (log Kow): 3.72 (measured) Self ignition: not self-igniting Thermal decomposition: No decomposition if stored and handled as prescribed/indicated. Viscosity, dynamic: No data available. Explosion hazard: not explosive Fire promoting properties: not fire-propagating 9.2. Other information Adsorption: log KOC: 3.05 Adsorption to solid soil phase is expected. (calculated) SECTION 10: Stability and Reactivity Reactivity No hazardous reactions if stored and handled as prescribed/indicated Chemical stability The product is stable if stored and handled as prescribed/indicated Possibility of hazardous reactions No hazardous reactions when stored and handled according to instructions Conditions to avoid See MSDS section 7 - Handling and storage Incompatible materials Substances to avoid: No substances known that should be avoided Hazardous decomposition products Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. SECTION 11: Toxicological Information Information on toxicological effects Acute toxicity Experimental/calculated data:

9 Page: 9/14 LD50 rat (oral): 6,208 mg/kg (BASF-Test) rat (by inhalation): (IRT) Inhalation-risk test (IRT): No mortality within 8 hours as shown in animal studies. The inhalation of a highly saturated vapor-air mixture represents no acute hazard. Irritation Assessment of irritating effects: Eye contact causes irritation. Not irritating to the skin. Experimental/calculated data: Skin corrosion/irritation rabbit: non-irritant (BASF-Test) Serious eye damage/irritation rabbit: Irritant. (BASF-Test) Respiratory/Skin sensitization Assessment of sensitization: Caused skin sensitization in animal studies. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Assessment of sensitization: Caused skin sensitization in animal studies. Germ cell mutagenicity Assessment of mutagenicity: The substance was not mutagenic in bacteria. The substance was not mutagenic in mammalian cell culture. The substance was not mutagenic in a test with mammals. Carcinogenicity Assessment of carcinogenicity: No data was available concerning carcinogenic activity. The whole of the information assessable provides no indication of a carcinogenic effect. Reproductive toxicity Assessment of reproduction toxicity: No effects have been reported in reproductive organs in long term animal studies. Developmental toxicity

10 Page: 10/14 Assessment of teratogenicity: No indications of a developmental toxic / teratogenic effect were seen in animal studies. Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity: The information available on the product provides no indication of toxicity on target organs after repeated exposure. Aspiration hazard not applicable SECTION 12: Ecological Information Toxicity Information on: triisobutyl phosphate Toxicity to fish: LC50 (96 h) mg/l, Leuciscus idus (static) Information on: triisobutyl phosphate Aquatic invertebrates: EC50 (24 h) mg/l, Daphnia magna (DIN Part 11) Information on: triisobutyl phosphate Aquatic plants: EC50 (72 h) mg/l (biomass), Scenedesmus subspicatus (DIN Part 9) Information on: triisobutyl phosphate Microorganisms/Effect on activated sludge: EC50 (0.5 h) > 100 mg/l, Pseudomonas putida (DIN Part 27 (draft)) Assessment of terrestrial toxicity: No data available concerning terrestrial toxicity Persistence and degradability

11 Page: 11/14 Elimination information: % CO2 formation relative to the theoretical value (28 d) (OECD 301B; ISO 9439; 92/69/EEC, C.4-C) (aerobic, activated sludge, domestic) Assessment of stability in water: In contact with water the substance will hydrolyse slowly Bioaccumulative potential Assessment bioaccumulation potential: Because of the n-octanol/water distribution coefficient (log Pow) accumulation in organisms is possible Mobility in soil Assessment transport between environmental compartments: The substance will not evaporate into the atmosphere from the water surface. Adsorption to solid soil phase is expected Results of PBT and vpvb assessment According to Regulation (EC) No.453/2010: The product does not fulfill the criteria for PBT (Persistent/bioaccumulative/toxic) and vpvb (very persistent/very bioaccumulative) Other adverse effects The product does not contain substances that are listed in Regulation (EC) 1005/2009 on substances that deplete the ozone layer Additional information Adsorbable organically-bound halogen (AOX): This product contains no organically-bound halogen. Other ecotoxicological advice: The product has not been tested. The statement has been derived from the properties of the individual components. SECTION 13: Disposal Considerations Waste treatment methods Must be disposed of or incinerated in accordance with local regulations.

12 Page: 12/14 Contaminated packaging: Uncontaminated packaging can be re-used. Packs that cannot be cleaned should be disposed of in the same manner as the contents. SECTION 14: Transport Information Land transport ADR Not classified as a dangerous good under transport regulations UN number: UN proper shipping name: Transport hazard class(es): Packing group: Environmental hazards: Special precautions for None known user RID Not classified as a dangerous good under transport regulations UN number: UN proper shipping name: Transport hazard class(es): Packing group: Environmental hazards: Special precautions for None known user Inland waterway transport ADN Not classified as a dangerous good under transport regulations UN number: UN proper shipping name: Transport hazard class(es): Packing group: Environmental hazards: Special precautions for None known user Transport in inland Not evaluated waterway vessel: Sea transport

13 Page: 13/14 IMDG Not classified as a dangerous good under transport regulations UN number: UN proper shipping name: Transport hazard class(es): Packing group: Environmental hazards: Special precautions for None known user Air transport IATA/ICAO Not classified as a dangerous good under transport regulations UN number: UN proper shipping name: Transport hazard class(es): Packing group: Environmental hazards: Special precautions for None known user UN number See corresponding entries for UN number for the respective regulations in the tables above UN proper shipping name See corresponding entries for UN proper shipping name for the respective regulations in the tables above Transport hazard class(es) See corresponding entries for Transport hazard class(es) for the respective regulations in the tables above Packing group See corresponding entries for Packing group for the respective regulations in the tables above Environmental hazards See corresponding entries for Environmental hazards for the respective regulations in the tables above Special precautions for user See corresponding entries for Special precautions for user for the respective regulations in the tables above Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Regulation: Not evaluated

14 Page: 14/14 Shipment approved: Not evaluated Pollution name: Not evaluated Pollution category: Not evaluated Ship Type: Not evaluated SECTION 15: Regulatory Information Safety, health and environmental regulations/legislation specific for the substance or mixture If other regulatory information applies that is not already provided elsewhere in this safety data sheet, then it is described in this subsection Chemical Safety Assessment Chemical Safety Assessment not required SECTION 16: Other Information Any other intended applications should be discussed with the manufacturer. Full text of the classifications, including the indication of danger, the hazard symbols, the R phrases, and the hazard statements, if mentioned in section 2 or 3: Xi Irritant. 43 May cause sensitization by skin contact. 38 Irritating to skin. Eye Dam./Irrit. Serious eye damage/eye irritation Skin Sens. Skin sensitization Skin Corr./Irrit. Skin corrosion/irritation H317 May cause an allergic skin reaction. H315 Causes skin irritation. The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. The data do not describe the product's properties (product specification). Neither should any agreed property nor the suitability of the product for any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed. Vertical lines in the left hand margin indicate an amendment from the previous version.