Safety Data Sheet Lupasol P Revision date : 2012/01/18 Page: 1/7

Transcription

1 Revision date : 2012/01/18 Page: 1/7 1. Product and Company Identification Company BASF Mexicana S.A. de C.V. Av. Insurgentes Sur 975 Col. CD. De Los Deportes, C.P , MEXICO 24 Hour Emergency Response Information Tel.: or CHEMTREC Int.: Synonyms: Polyethyleneimine 2. Hazards Identification Emergency overview CAUTION: Harmful if swallowed. May cause sensitization by skin contact. Because of ph, may cause skin and eye burns. Avoid inhalation of mists/vapours. Use with local exhaust ventilation. Wear protective clothing. Wear full face shield if splashing hazard exists. State of matter: liquid Colour: colourless to slightly yellow Odour: product specific Potential health effects Primary routes of exposure: Routes of entry for solids and liquids include eye and skin contact, ingestion and inhalation. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquified gases. Irritation / corrosion: Not irritating to the eyes. Not irritating to the skin. Chronic toxicity: Carcinogenicity: No data available concerning carcinogenic effects. Repeated dose toxicity: Reproductive toxicity: No data available concerning reproduction toxicity.

2 Revision date : 2012/01/18 Page: 2/7 Genotoxicity: The substance was not mutagenic in a test with mammals. Signs and symptoms of overexposure: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section Composition / Information on Ingredients CAS Number Content (W/W) Hazardous ingredients >= <= 55.0 % NJTS NVE >= <= 55.0 % Water 4. First-Aid Measures General advice: Remove contaminated clothing. If inhaled: If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical attention. If on skin: Wash thoroughly with soap and water. If in eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open. If swallowed: Rinse mouth immediately and then drink plenty of water, seek medical attention. Note to physician Treatment: Treat symptomatically. 5. Fire-Fighting Measures Flash point: > 100 C (DIN EN 22719; ISO 2719) Autoignition: > 200 C (DIN 51794) Lower explosion limit: Upper explosion limit: Self-ignition temperature: not self-igniting Suitable extinguishing media: water spray, dry powder, foam Hazards during fire-fighting: The substances/groups of substances mentioned can be released in case of fire. carbon monoxide, carbon dioxide, corrosive gases/vapours, toxic gases/vapours Cool endangered containers with water-spray. Protective equipment for fire-fighting: Wear a self-contained breathing apparatus. Further information: Fire debris must be disposed of in accordance with offical regulations.

3 Revision date : 2012/01/18 Page: 3/7 6. Accidental release measures Personal precautions: Use personal protective clothing. Environmental precautions: Do not discharge into drains/surface waters/groundwater. Do not discharge into the subsoil/soil. Cleanup: For residues: Pick up with suitable absorbent material. Dispose of absorbed material in accordance with regulations. 7. Handling and Storage Handling General advice: Ensure thorough ventilation of stores and work areas. Wear suitable gloves and eye/face protection. Protection against fire and explosion: No special precautions necessary. Storage General advice: Keep container tightly closed and dry; store in a cool place. 8. Exposure Controls and Personal Protection Personal protective equipment Hand protection: Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) and other, Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing. Eye protection: Safety glasses with side-shields (frame goggles) (e.g. EN 166) Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN in case of splashes or EN ISO in case of dust). General safety and hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Avoid contact with the skin, eyes and clothing. 9. Physical and Chemical Properties Form: Odour: Odour threshold: Colour: liquid product specific colourless to slightly yellow

4 Revision date : 2012/01/18 Page: 4/7 ph value: approx. 12 ( 100 g/l, 23 C) (DIN ISO 976) solidification temperature: approx. -10 C (DIN ISO 3016) Boiling point: approx. 100 C ( 1,013 hpa) Information on: Water Vapour pressure: 23.4 hpa ( 20 C) Literature data Density: approx g/cm3 ( 20 C) (DIN 51757) Relative density: Vapour density: Partitioning coefficient n-octanol/water (log Pow): Viscosity, dynamic: 18,000-40,000 (DIN EN ISO 2555 (RV)) mpa.s Solubility in water: ( 20 C) miscible Solubility (qualitative): miscible solvent(s): Water Other Information: If necessary, information on other physical and chemical parameters is indicated in this section. 10. Stability and Reactivity Conditions to avoid: No conditions to avoid anticipated. Substances to avoid: acids Hazardous reactions: No hazardous reactions if stored and handled as prescribed/indicated. Decomposition products: Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. Oxidizing properties: not fire-propagating 11. Toxicological information Acute toxicity Oral: Type of value: LD50 Species: rat (male/female) Value: > < 2,000 mg/kg (OECD Guideline 423) Irritation / corrosion Skin: Species: rabbit Result: non-irritant Method: OECD Guideline 404 Eye: Species: rabbit Result: non-irritant Method: OECD Guideline 405 Sensitization:

5 Revision date : 2012/01/18 Page: 5/7 Guinea pig maximization test Species: guinea pig Result: Caused skin sensitization in animal studies. Method: OECD Guideline Ecological Information Fish Acute: OECD 203; ISO 7346; 92/69/EEC, C.1 static Brachydanio rerio/lc50 (96 h): 7.1 mg/l Nominal concentration. Aquatic invertebrates Acute: OECD Guideline 202, part 1 static Daphnia magna/ec50 (48 h): 8.84 mg/l Nominal concentration. Microorganisms Toxicity to microorganisms: DIN EN ISO 8192-OECD /302/EEC,P. C activated sludge/ec20 (0.5 h): 60 mg/l Depending on local conditions and existing concentrations, disturbances in the biodegradation process of activated sludge are possible. Degradability / Persistence Biological / Abiological Degradation Test method: OECD Guideline 302 B (aerobic), activated sludge, domestic Method of analysis: DOC reduction Degree of elimination: approx % (28 d) Evaluation: Moderately/partially eliminated from water. Bioaccumulation The product has not been tested. Other adverse effects: Do not allow to enter soil, waterways or waste water channels. 13. Disposal considerations Waste disposal of substance: Must be disposed of or incinerated in accordance with local regulations. Container disposal: Uncontaminated packaging can be re-used. Packs that cannot be cleaned should be disposed of in the same manner as the contents. 14. Transport Information Land transport TDG

6 Revision date : 2012/01/18 Page: 6/7 Not classified as a dangerous good under transport regulations Sea transport IMDG Hazard class: 9 Packing group: III ID number: UN 3082 Hazard label: 9, EHSM Marine pollutant: Proper shipping name: YES ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains POLYETHYLENEIMINE) Air transport IATA/ICAO Hazard class: 9 Packing group: III ID number: UN 3082 Hazard label: Proper shipping name: 9, EHSM ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains POLYETHYLENEIMINE) 15. Regulatory Information Federal Regulations Not applicable 16. Other Information NFPA Hazard codes: Health : 2 Fire: 0 Reactivity: 0 Special: HMIS III rating Health: 2 Flammability: 1 Physical hazard: 0 NFPA and HMIS use a numbering scale ranging from 0 to 4 to indicate the degree of hazard. A value of zero means that the substance possesses essentially no hazard; a rating of four indicates extreme danger. Although similar, the two rating systems are intended for different purposes, and use different criteria. The NFPA system was developed to provide an on-the-spot alert to the hazards of a material, and their severity, to emergency responders. The HMIS system was designed to communicate workplace hazard information to employees who handle hazardous chemicals. We support worldwide Responsible Care initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products. MSDS Prepared by: BASF NA Product Regulations MSDS Prepared on: 2012/01/18 is a registered trademark of BASF Mexicana or BASF SE

7 Revision date : 2012/01/18 Page: 7/7 IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY OUR COMPANY HEREUNDER ARE GIVEN GRATIS AND WE ASSUME NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. END OF DATA SHEET