Page: 1/11 BASF Safety data sheet according to Regulation (EC) No. 1907/2006 Date / Revised: Version: 1.0 Product: Agnique MBL 530 B

Transcription

1 Safety data sheet Page: 1/11 1. Identification of the substance/mixture and of the company/undertaking Product identifier Agnique MBL 530 B Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses: Component for agrochemicals, emulsifier Details of the supplier of the safety data sheet Company: BASF SE Ludwigshafen GERMANY Operating Division Care Chemicals Telephone: address: emd-ems-ehs-masterdata@basf.com Emergency telephone number International emergency number: Telephone: Hazards Identification Label elements Globally Harmonized System, EU (GHS) Pictogram:

2 Page: 2/11 Signal Word: Danger Hazard Statement: H318 H315 H412 Causes serious eye damage. Causes skin irritation. Harmful to aquatic life with long lasting effects. Precautionary Statements (Prevention): P280d Wear eye/face protection. P280c Wear protective gloves. P273 Avoid release to the environment. P264 Wash with plenty of water and soap thoroughly after handling. Precautionary Statements (Response): P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/physician. P303 + P352 IF ON SKIN (on hair): Wash with plenty of soap and water. P332 + P313 If skin irritation occurs: Get medical advice/attention. P362 Take off contaminated clothing and wash before reuse. Precautionary Statements (Disposal): P501 Dispose of contents/container to hazardous or special waste collection point. According to Regulation (EC) No 1272/2008 [CLP] Hazard determining component(s) for labelling: Benzenesulfonic acid, mono-c11-13-branched alkyl derivs., calcium salts According to Directive 67/548/EEC or 1999/45/EC Directive 1999/45/EC ('Preparation Directive') Hazard symbol(s) Xi Irritant. R-phrase(s) R38 Irritating to skin. R41 Risk of serious damage to eyes. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrase(s) S24/25 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28.2 After contact with skin, wash immediately with plenty of water. S37/39 Wear suitable gloves and eye/face protection.

3 Page: 3/11 Hazard determining component(s) for labelling: Benzenesulfonic acid, mono-c11-13-branched alkyl derivs., calcium salts Classification of the substance or mixture According to Regulation (EC) No 1272/2008 [CLP] Skin Corr./Irrit. 2 Eye Dam./Irrit. 1 Aquatic Chronic 3 According to Directive 67/548/EEC or 1999/45/EC Possible Hazards: Irritating to skin. Risk of serious damage to eyes. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. For the classifications not written out in full in this section the full text can be found in section 16. Other hazards According to Regulation (EC) No 1272/2008 [CLP] No specific dangers known, if the regulations/notes for storage and handling are considered. 3. Composition/Information on Ingredients Mixtures Chemical nature Blend based on: Anionic surfactant, Hydrocarbons, aromatic Hazardous ingredients (GHS) according to Regulation (EC) No. 1272/2008 Hexan-1-ol Content (W/W): >= 1 % - < 5 % CAS Number: EC-Number: REACH registration number: INDEX-Number: Acute Tox. 4 (oral) Acute Tox. 4 (dermal) Eye Dam./Irrit. 2A Flam. Liq. 3 H302 H226, H302, H312, H319 Solvent naphtha (petroleum), heavy arom.

4 Page: 4/11 Content (W/W): >= 10 % - < 20 % Asp. Tox. 1 CAS Number: Aquatic Chronic 2 EC-Number: H411, H304 INDEX-Number: Benzenesulfonic acid, mono-c11-13-branched alkyl derivs., calcium salts Content (W/W): >= 30 % - < 50 % Eye Dam./Irrit. 1 CAS Number: Skin Corr./Irrit. 2 H315, H318 Hazardous ingredients according to Directive 1999/45/EC Hexan-1-ol Content (W/W): >= 1 % - < 5 % CAS Number: EC-Number: REACH registration number: INDEX-Number: Hazard symbol(s): Xn R-phrase(s): 21/22, 36 Solvent naphtha (petroleum), heavy arom. Content (W/W): >= 10 % - < 20 % CAS Number: EC-Number: INDEX-Number: Hazard symbol(s): Xn, N R-phrase(s): 65, 51/53 Benzenesulfonic acid, mono-c11-13-branched alkyl derivs., calcium salts Content (W/W): >= 30 % - < 50 % CAS Number: Hazard symbol(s): Xi R-phrase(s): 38, 41 For the classifications not written out in full in this section, including the indication of danger, the hazard symbols, the R phrases, and the hazard statements, the full text is listed in section First-Aid Measures Description of first aid measures If adverse health effects develop seek medical attention. If inhaled: not relevant. On skin contact: After contact with skin, wash immediately with plenty of water. Change contaminated clothing and shoes. On contact with eyes:

5 Page: 5/11 Rinse immediately with plenty of running water (for 10 minutes), seek medical attention from a specialist. On ingestion: Rinse mouth and then drink ml of water. Most important symptoms and effects, both acute and delayed Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further important symptoms and effects are so far not known. Indication of any immediate medical attention and special treatment needed Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. Medical monitoring for at least 24 hours. 5. Fire-Fighting Measures Extinguishing media Suitable extinguishing media: carbon dioxide, foam, dry powder Unsuitable extinguishing media for safety reasons: water jet Special hazards arising from the substance or mixture Evolution of fumes/fog. Advice for fire-fighters Special protective equipment: Wear a self-contained breathing apparatus. Further information: If exposed to fire, keep containers cool by spraying with water. Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems. 6. Accidental Release Measures Personal precautions, protective equipment and emergency procedures Avoid all sources of ignition: heat, sparks, open flame. Do not breathe vapour/spray. Avoid contact with the skin, eyes and clothing. Use personal protective clothing. Information regarding personal protective measures see, chapter 8. Environmental precautions Do not discharge into drains/surface waters/groundwater. Methods and material for containment and cleaning up For small amounts: Pick up with suitable absorbent material. For large amounts: Pump off product. Dike spillage. For residues: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr). Dispose of absorbed material in accordance with regulations.

6 Page: 6/11 Reference to other sections Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and Handling and Storage Precautions for safe handling Handle in accordance with good industrial hygiene and safety practice. Ensure thorough ventilation of stores and work areas. Protection against fire and explosion: Avoid all sources of ignition: heat, sparks, open flame. Take precautionary measures against static discharges. Conditions for safe storage, including any incompatibilities Suitable materials for containers: carbon steel (iron) Further information on storage conditions: Keep container tightly sealed. 8. Exposure Controls/Personal Protection Control parameters Components with workplace control parameters : Solvent naphtha (petroleum), heavy arom.; Kerosine - unspecified : (2-Methoxymethylethoxy)propanol TWA value 308 mg/m3 ; 50 ppm (OEL (EU)) indicative Skin Designation (OEL (EU)) The substance can be absorbed through the skin : hexan-1-ol Exposure controls Personal protective equipment Respiratory protection: Respiratory protection in case of vapour/aerosol release. Hand protection: Chemical resistant protective gloves (EN 374) Suitable materials short-term contact and/or splashes (recommended: At least protective index 2, corresponding > 30 minutes of permeation time according to EN 374) Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) and other Manufacturer's directions for use should be observed because of great diversity of types. Eye protection: Tightly fitting safety goggles (splash goggles) (e.g. EN 166)

7 Page: 7/11 Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN in case of splashes or EN ISO in case of dust)., cold-protection suit (f.e. according to EN 342) General safety and hygiene measures Handle in accordance with good industrial hygiene and safety practice. 9. Physical and Chemical Properties Information on basic physical and chemical properties Form: liquid Colour: dark amber Odour: characteristic Flash point: > 75 C (ASTM D93) Density: 1.02 g/cm3 (20 C) (ISO 6883; QP2309.1; Density pycnometer) Self ignition: not self-igniting Thermal decomposition: No decomposition if stored and handled as prescribed/indicated. Viscosity, dynamic: < 1,500 mpa*s (25 C) (DIN EN ISO 2555) Other information Bulk density: Hygroscopy: Grain size distribution: not applicable Non-hygroscopic The substance / product is marketed or used in a non solid or granular form. 10. Stability and Reactivity Reactivity No hazardous reactions if stored and handled as prescribed/indicated. Chemical stability The product is stable if stored and handled as prescribed/indicated. Possibility of hazardous reactions Reacts with oxidizing agents. None if used for intended purpose. Conditions to avoid See MSDS section 7 - Handling and storage. Incompatible materials Substances to avoid: strong oxidizing agents, strong alkalies

8 Page: 8/11 Hazardous decomposition products aliphatic hydrocarbons, aromatic hydrocarbons, sulfur oxides 11. Toxicological Information Information on toxicological effects Acute toxicity Assessment of acute toxicity: Virtually nontoxic after a single ingestion. Experimental/calculated data: LD50 (oral): > 2,000 mg/kg Irritation Assessment of irritating effects: Skin contact causes irritation. May cause severe damage to the eyes. Respiratory/Skin sensitization Assessment of sensitization: Skin sensitizing effects were not observed in animal studies. Germ cell mutagenicity Assessment of mutagenicity: Mutagenicity tests revealed no genotoxic potential. Carcinogenicity Assessment of carcinogenicity: The whole of the information available provides no indication of a carcinogenic effect. Reproductive toxicity Assessment of reproduction toxicity: The results of animal studies gave no indication of a fertility impairing effect. Developmental toxicity Assessment of teratogenicity: No indications of a developmental toxic / teratogenic effect were seen in animal studies. Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity: No adverse effects were observed after repeated exposure in animal studies. Aspiration hazard No aspiration hazard expected.

9 Page: 9/11 Other relevant toxicity information The product has been assessed on the basis of the components available data. To some extent data gaps exist for individual components. According to our present knowledge and experience dangers which are not covered by the current labeling are not to be expected. The product has not been tested. The statement has been derived from the properties of the individual components. 12. Ecological Information Toxicity Assessment of aquatic toxicity: Acutely harmful for aquatic organisms. May cause long-term adverse effects in the aquatic environment. The product has not been tested. The statement has been derived from the properties of the individual components. Toxicity to fish: LC50 > mg/l Microorganisms/Effect on activated sludge: EC0 > mg/l Persistence and degradability Assessment biodegradation and elimination (H2O): Not readily biodegradable (by OECD criteria). Bioaccumulative potential Bioaccumulation potential: Significant accumulation in organisms is not to be expected. Mobility in soil (and other compartments if available) Assessment transport between environmental compartments: not determined Results of PBT and vpvb assessment According to Annex XIV of Regulation (EC) No.1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH): The product does not contain a substance fullfilling the PBT (persistent/bioaccumulative/toxic) criteria or the vpvb (very persistent/very bioaccumulative) criteria. Additional information Other ecotoxicological advice: The product has not been tested. The statement has been derived from the properties of the individual components. The product has been assessed on the basis of the components available data. To some extent data gaps exist for individual components. According to our present knowledge and experience dangers which are not covered by the current labeling are not to be expected.

10 Page: 10/ Disposal Considerations Waste treatment methods Dispose of in accordance with national, state and local regulations. Contact specialized companies about recycling. Contaminated packaging: Contaminated packaging should be emptied as far as possible and disposed of in the same manner as the substance/product. 14. Transport Information Land transport ADR RID Not classified as a dangerous good under transport regulations Not classified as a dangerous good under transport regulations Inland waterway transport ADN Hazardous good only when carried in inland waterway tanker (ADNR) Sea transport IMDG Not classified as a dangerous good under transport regulations Air transport IATA/ICAO Not classified as a dangerous good under transport regulations 15. Regulatory Information Safety, health and environmental regulations/legislation specific for the substance or mixture If other regulatory information applies that is not already provided elsewhere in this safety data sheet, then it is described in this subsection.

11 Page: 11/ Other Information Full text of the classifications, including the indication of danger, the hazard symbols, the R phrases, and the hazard statements, if mentioned in section 2 or 3: Xn Harmful. N Dangerous for the environment. Xi Irritant. 21/22 Harmful in contact with skin and if swallowed. 36 Irritating to eyes. 65 Harmful: may cause lung damage if swallowed. 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 38 Irritating to skin. 41 Risk of serious damage to eyes. Skin Corr./Irrit. Skin corrosion/irritation Eye Dam./Irrit. Serious eye damage/eye irritation Aquatic Chronic Hazardous to the aquatic environment - chronic Acute Tox. Acute toxicity Flam. Liq. Flammable liquid Asp. Tox. Aspiration hazard H302 Harmful if swallowed. H226 Flammable liquid and vapour. H312 Harmful in contact with skin. H319 Causes serious eye irritation. H411 Toxic to aquatic life with long lasting effects. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H318 Causes serious eye damage. The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. The data do not describe the product's properties (product specification). Neither should any agreed property nor the suitability of the product for any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed. Vertical lines in the left hand margin indicate an amendment from the previous version.