Colonnes GC TEKNOKROMA

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1 Colonnes GC Applications GC - Chemical Biological & Industrial ANALYSIS OF SOLVENTS Column: TRB-WAX, P/N TR-0 Dimensions: 0m x 0.mm x.0μm Injection: wet needle, split, 0ºC Carrier gas: H, constant pressure psi (. KPa). Oven program: ºC/min to 0ºC(min) Detector: FID, 0ºC 0 - Acetone - Methyl acetate - Ethyl acetate - Methanol + MEK - Isopropanol - Ethanol - MIKB - Methoxypropyl acetate - Isobutyl acetate 0- Toluene - Methoxypropanol - n-butyl acetate - Isobutanol - n-butanol - p,m-xylenes - o-xylene - Ethylglycol - Diacetone alcohol - Butyl glycol SEPARATION OF MONOMERS IN PAINTS Column: Meta.WAX, P/N TR-0 Dimensions: 0m x 0.mm x.0μm Injection: μl Monomers mixture (0ppm, 00ppm toluene in DMSO), split :0, 0ºC Carrier gas: He, psi (. KPa) Oven temperature: ºC/min to 0ºC(min) Detector: FID, 0ºC SEPARATION OF NITROSOAMINES Column: TR-WAX DB, P/N TR- Dimensions: m x 0.mm x 0.0μm Injection: μl standard 00 ppm in n-hexane, split :0, 0ºC Carrier gas: H, constant pressure psi (. KPa) Oven temperature: 0ºC/min to ºC/min to 0ºC(0min) Detector: FID, 0ºC - Methyl acrylate - Toluene - Butyl acrylate - Styrene - N-nitrosodimethylamine - N-nitrosodiethylamine - N-nitrosodiisopropylamine - N-nitrosodi-n-propylamine - N-nitrosodi-n-butylamine - N-nitrosopiperidine - N-nitrosopyrrolidine - N-nitrosomorpholine - N-nitroso-n-methyl-n-phenylamine 0- N-nitrosodiphenylamine 0 A.I.T FRANCE

2 Applications GC - Chemical Biological & Industrial Colonnes GC SEPARATION OF SOLVENTS Column: TRB-, P/N TR-0 Dimensions: 0m x 0.mm x.μm Injection: 0.μL standard in Ethanol/HO (:), split :, 0ºC Carrier gas: He, constant pressure. psi (. KPa). Oven temperature: 0ºC/min to 00ºC(0min) Detector: FID, 0ºC SEPARATION OF ACETIC ACID AND ACETIC ANHYDRIDE Column: TRB-, P/N TR-0 Dimensions: 0m x 0.mm x.0μm Injection: wet needle (solvent mixture), split :00, 00ºC Carrier gas: H, constant pressure psi (0. KPa). Oven program: 0ºC Detector: FID, 0ºC - Acetaldehyde - Methanol - Ethanol - Acetone - -Propanol (Isopropanol) - -Propanol - Ethyl acetate - -Butanol - Cyclohexane 0- Benzene - Isobutanol - -Butanol - Acetal - -Methyl--butanol (isoamyl alcohol) - -Methyl--butanol (amyl alcohol) - -Methyl--pentanol - Ethyl butyrate - Acetic acid - Acetic anhydride 0 SEPARATION OF SOLVENTS Column: TRB-, P/N TR-0 Dimensions: 0m x 0.mm x.0μm Injection: wet needle (solvent mixture), split :00, 0ºC Carrier gas: He, constant pressure psi (. KPa). Oven program: ºC (isothermal) Detector: FID, 0ºC - Methanol - Ethanol - Acetone - Acetonitrile - Methylene chloride SEPARATION OF PAE (PHTHALATE ALKYL ESTER) MIX EPA Column: Meta. X, P/N TR-0 Dimensions: 0m x 0.mm x 0.μm Injection: μl standard (.ng/g in Hexane), 0ºC Carrier gas: H, constant pressure psi (. KPa). Oven temperature: 0ºC/min to 0ºC(min) Detector: FID, 0ºC - Dimethyl phthalate - Diethyl phthalate - Di-n-butyl phthalate - Butyl benzyl phthalate - Bis--ethylhexyl phthalate - Dioctyl phthalate

3 Colonnes GC Applications GC - Chemical Biological & Industrial SEPARATION OF SOLVENTS Column: TRB-, P/N TR-00 Dimensions: m x 0.mm x.0μm Injection: 0.μL, split :, 0ºC Carrier gas: H, constant pressure. psi (. KPa). Oven temperature: ºC/min to 0ºC Detector: FID, 0ºC 0 - Heptane - Acetone - Tetrahydrofurane - Ethyl acetate - Isopropyl acetate - Methanol - MEK - Isopropanol - Ethanol 0- n-propyl acetate - MIBK - n-propanol - Toluene - Butyl acetate - Methoxypropanol - Methoxypropyl acetate SEPARATION OF SOLVENTS Column: TRB-WAX, P/N TR- Dimensions: 0m x 0.mm x.μm Injection: μl standard (00 ng/ml comp.), split :, 0ºC Carrier gas: He, constant pressure psi (. Kpa) Oven temperature: ºC/min to ºC Detector: FID, 0ºC Chromatogram provided by Jaume Piedrabuena from Danisco 0 Heptane (isomers mixture) Acetone Tetrahydrofurane Ethyl acetate Isopropyl acetate Methanol MEK Isopropanol Ethanol 0 n-propyl acetate MIBK n-propanol Toluene Butyl acetate Methoxypropanol Methoxypropyl acetate IMPURITIES OF ETHANOL Column: TRB-G, P/N TR-0 Dimensions: 0m x 0.mm x.0μm Injection: μl standard alcohols (0 ppm/comp), split :, 00ºC Carrier gas: He, constant pressure. psi (. KPa). Oven temperature: ºC/min to 0ºC(min) Detector: FID, 00ºC - Methanol - Ethanol - Isopropanol - n-propanol - Ethyl acetate - -Butanol - Isobutanol - -Butanol - Amylics alcohols 0- Ethyl butyrate 0 A.I.T FRANCE

4 Applications GC - Environmental Colonnes GC CHLORINATED PESTICIDES Column: Meta.X, P/N TR-0 Dimensions: 0m x 0.mm x 0.μm Injection: μl chlorinated pesticide mix, splitless (0, min), 0ºC (0-0 ppb oncolumn) Carrier gas: H, constant pressure 0 psi (. KPa) Oven program: 0ºC (min) to ºC/min to ºC/min to ºC/min Detector: ECD, 0ºC 0 0 tetrachloro-m-xylene alpha-bhc beta-bhc gamma-bhc delta-bhc heptachlor aldrin heptachlor epoxide gamma-chlordane 0 endosulfan I alpha-chlordane dieldrin, -DDE endrin endosulfan II, -DDD endrin aldehyde enduosulfan sulfate, -DDT 0 endrin ketone methoxychlor decachlorobiphenyl CHLORINATED PESTICIDES Column: TRB-MS, P/N TR-0 Dimensions: 0m x 0.mm x 0.μm Injection: 0.μL chlorinated pesticide mix, splitless (0, min), 0ºC (00-00 pg on-column) Carrier gas: H, constant pressure 0 psi (. KPa) Oven program: 0ºC (min) to ºC/min to ºC/min to ºC/min (min). Detector: ECD, 0ºC 0 0 tetrachloro-m-xylene alpha-bhc beta-bhc gamma-bhc delta-bhc heptachlor aldrin heptachlor epoxide gamma-chlordane 0 endosulfan I alpha-chlordane dieldrin, -DDE endrin endosulfan II, -DDD endrin aldehyde enduosulfan sulfate, -DDT 0 endrin ketone methoxychlor decachlorobiphenyl

5 Colonnes GC Applications GC - Environmental CHLORINATED PESTICIDES Column: Meta.X, P/N TR-0 Dimensions: 0m x 0.mm x 0.μm Injection: 0,μL chlorinated pesticide mix, splitless, 0ºC (0-0 ppb on-column) Carrier gas: Helium, constant flow.ml/min. Oven program: 00ºC (0.min) to ºC/min to ºC/min to ºC/min (0.min). Detector: ECD, 0ºC tetrachloro-m-xylene alpha-bhc beta-bhc gamma-bhc delta-bhc heptachlor aldrin heptachlor epoxide gamma-chlordane 0 endosulfan I alpha-chlordane dieldrin, -DDE endrin endosulfan II, -DDD endrin aldehyde enduosulfan sulfate, -DDT 0 endrin ketone methoxychlor decachlorobiphenyl ALDEHYDES IN AIR SAMPLE Column: TRB-, P/N TR-0 Dimensions: 0m x 0.mm x 0.μm Injection: μl Aldehydes in Air Sample after extraction (derivatisized with DNPH), splitless ( min), 0ºC Carrier gas: He, constant flow ml/min Oven temperature: 0ºC/min to 00ºC Detector: MS, 0ºC (transfer lilne) Chromatogram provided by F. Sisteré from IUCT SEPARATION OF BTEX ISOMERS Column: TRB-, P/N TR-0 Dimensions: 0m x 0.mm x.μm Injection: μl BTEX sample (0 ppm on column), 0ºC Carrier gas: H,. psi (. KPa) Oven temperature: ºC/min to 0ºC(0min) Detector: FID, 0ºC - Benzene - Toluene - Ethylbenzene - m-xylene - p-xylene - o-xylene - Glycerine - Dinitrobenzene - Formaldehyde-DNPH - Acetaldehyde-DNPH - Propanaldehyde-DNPH -,-Dinitrophenylhydrazine (DNPH) A.I.T FRANCE

6 Applications GC - Environmental Colonnes GC OPTIMUN RESOLUTION IN SEMIVOLATILE COMPOUNDS ANALYSIS Column: META.X, P/N TR-0 Dimensions: 0m x 0.mm x 0.0μm Injection: 0, μl, splitless, min. 00ºC Carrier gas: He, 0,ml/min. constant flow Oven temperature: ºC ( ) to 0ºC/min. to ºC/min. Detector: MS, full scan -0 AMU, 0ºc transfer line Sample: EPA 0 standard (0/00 ng/μl) The low level of bleeding at 0ºC will perylene (M/Z ) at the traces level. - Methyl methanesulfonate - Ethyl methanesulfonate - Phenol - Aniline - bis (-Chloroethyl) ether - -Chlorofenol -,-Dichlorobenzene -,-Dichlorobenzene - Benzyl alcohol 0-,-Dichlorobenzene - -Methylphenol - bis(-chloroisopropyl)ether - -Methyl phenol - -Methyl phenol The low level of bleeding at 0ºC will allow the quantification of Benzo (ghi) perylene (M/Z ) at the traces level. - Acetophenone - N-nitroso-di-n-propylamine - Hexachloroethane - Nitrobenzene - Isophorone 0- -Nitrophenol -,-Dimethylphenol - bis(-chloroethoxy)methane - Benzoic acid -,-Dichlorophenol -,,-Trichlorobenzene - Naphtalene - -Chloraniline -,-Dichlorophenol - Hexachloropropene 0- Hexacloro-, -butadiene - -Chloro--methylphenol -Safrole - -Methylnaphthalene - -Methylnaphthalene - Hexachlorocyclopentadiene -,,,-Tetrachlorobenzene -,,-Trichlorophenol -,,-Trichlorophenol - Isosafrole (cis&trans) 0- -Chloronaphthalene - -Nitroaniline -,-Naphthoquinone - Dimethylphthalate -,-Dinitrobenzene -,-Dinitrotoluene - Acenaphthylene - -Nitroaniline - Acenaphthene -,-Dinitrophenol 0- -Nitrophenol - Pentachlorobenzene -,-Dinitrotoluene - Dibenzofuran -,,,-Tetrachlorophenol - Diethyl phtalate - -Chlorophenyl phenyl ether - Fluorene - -Nitroaniline -,-Dinitro-methylphenol 0- Diphenylamine - Azobenzene -,,-Trinitrobenzene - Phenacetin - -Bromophenyl phenyl ether - Hexachlorobenzene - Pentachlorophenol - Pentachloronitrobenzene - Dinoseb Phenantrene 0 Anthracene Di-n-butylphtalate - -Nitroquinoline-n-oxide - Isodrin - Fluoranthene - Benzidine - Pyrene - Aramite B - Aramite A - Chlorobenzilate 0- Butyl benzyl phtalate - Kepone -, -Dichlorobenzidine - Benzo (a) anthracene - bis (-Ethylhexyl) phthalate - Chrysene - Di-n-octyl phthalate - Benzo (b) fluoranthene - Benzo (k) fluoranthene - Benzo (a) pyrene 0- -Methylchlorantrene - Indeno (,,-cd) pyrene - Dibenz (a,h) anthracene - Benzo (g,h,i) perylene

7 Colonnes GC Applications GC - Environmental PESTICIDES ANALYSIS Column: Meta X P/N TR-0 Dimensions: 0m x 0.mm x 0.μm Injection:.0 μl standard, 0 ppm in Isooctane, splitless, 0ºC Carrier gas: He, constant pressure, psi ( kpa) Oven program: 00ºC (,min.) to 0ºC/min. to ºC/min. Detector: 0ºC, scan 0-00 amus Chromatogram supplied by J. Díaz from Chromatography Department, IQS. - -Hexachlorocyclohexane - Hexachlorobenzene - -Hexachlorobenzene - -Hexachlorocyclohexane - Heptachlor - -Hexachlorocyclohexane - Aldrin - Heptachlor epoxide - Endosulfan I 0- p,p - DDE - Dieldrin - Endrin - Endosulfan II - p.p -DDD - Endrin Aldehyde - Endosulfan sulfate - p.p -DDT - Metoxychlor PURIFIER SLUDGE ANALYSIS Column: Meta X P/N TR-0 Dimensions: 0m x 0.mm x 0.μm Injection:.0 μl standard (split :0), 0ºC Carrier gas: He, psi ( kpa) Oven temperature: 0ºC (min.) to 00ºC 0ºC/min. Detector: MS, full scan 0-0 amu, 0ºC Sample: Urban purifier sludge (0ppm di (-ethylhexyl) phthalate, DEHP) Chromatogram from B. Bagó, J. Díaz. Chromatography Dep. IQS. A.I.T FRANCE

8 Applications GC - Foods & Flavors Colonnes GC HYDROGENATED SOYA OIL Column: TR-CN00, P/N TR- Dimensions: 0m x 0.mm x 0.0μm Injection: 0.μL Hydrogenated Soya Oil, split :0, 0ºC Carrier gas: H, psi (. KPa) Oven program: to 0ºC(min) Detector: FID, 0ºC - C:0 - C:trans - C:cis SEPARATION OF FAMES Column: TR-WAXOmega, P/N TR-0 Dimensions: 0m x 0.mm x 0.μm Injection: μl test SP--, split :0, 0ºC Carrier gas: H,. psi (. KPa) Oven temperature: 00ºC (Isothermal) Detector: FID, 0ºC 0 - C:0 - C:0 - C:0 - C:n - C:n - C:n - C:n - C0:0 - C0:n (EPA) 0- C:0 - C:n - C:0 - C:n - C:0 - C:n (DHA) - C:n SEPARATION OF FAMES Column: TR-CN00, P/N TR- Dimensions: 0m x 0.mm x 0.0μm Injection: μl SP- (0 mg/ml), split :00, 0ºC Carrier gas: He, 0. cm/s at ºC Oven program: ºC/min to 0ºC(min) Detector: FID, 0ºC C:0 (butyric) - C:0 (caproic) - C:0 (caprylic) - C0:0 (capric) - C:0 (undecanoic) - C:0 (lauric) - C:0 (tridecanoic) - C:0 (myristic) - C: (myristoleic) 0- C:0 (pentadecanoic) - C: (cis-0-pentadecanoic) - C:0 (palmitic) - C: (palmitoleic) - C:0 (heptadecanoic) - C: (cis-0-heptadecenoic) - C:0 (stearic) - C:nc (oleic) - C:nt (elaidic) + - C:nc (linoleic) 0- C:nt (linolelaidic) - C:n ( -linolenic) - C:n ( -linolenic) - C0:0 (arachidic) - C0:n (cis--eicosenoic) - C0: (cis-,-eicosadienoic) - C0:n (cis-,,-eicosatrienoic) - C0:n (cis-,,-eicosatrienoic) - C0:n (arachidonic) - C0:n (cis-,,,,-eicosapentaenoic) 0- C:0 (henicosanoic) - C:0 (behenic) - C:n (er ucic) - C: (cis-,-docosadienoic) - C:n (cis-,,0,,,-docosahexaenoic) - C:0 (tricosanoic) - C:0 (lignoceric) - C:n (nervonic)

9 Colonnes GC Applications GC - Foods & Flavors PHENOLS-ANSIOLES IN WINE Column: TR-MS P/N TR-0 Dimensions: 0m x 0.mm x 0.μm Injection: 0ºC, μl (St 00 ppb), split (0:) Carrier gas: H,, ml/min. psi ( kpa) to 0ºC Oven temperature: 0ºC to 0ºC 0ºC/min. Detector: ECD, 0ºC PHENOLS-ANSIOLES IN WINE (FAST CHROMATOGRAPHY) Column: META.X P/N TR-0 Dimensions: 0m x 0.0mm x 0.0μm Injection: 0ºC,0,μL (St 0 ppb), split (00:) Carrier gas: H, 0 psi (. kpa) Oven temperature: 00ºC to 0ºC/min. Detector: ECD, 0ºC - Trichlorophenol - Trichloroanisole - Tetrachlorophenol - Tetrachloroanisole - Pentachlorophenol - Pentachloroanisole - Trichlorophenol - Trichloroanisole - Tetrachlorophenol - Tetrachloroanisole - Pentachlorophenol - Pentachloroanisole Exceptional symmetry of the peaks at traces level PHYTOSANITARY ANALYSIS IN WINE Column: Meta.X P/N TR-0 Dimensions: 0m x 0.mm x 0.μm Injection:,0 μl split (:00), 0ºC Carrier gas: He, ml/min. Oven temperature: 0ºC to 0,ºC/min. to Detector: ECD, 00ºC, make up Argon/methane (/) Sample: Phytosanitary standard INCAVI, (0-0 μg/l of each component) Chromatogram supplied by M. Jaldo, J. García (Incavi) and J. Marco (Torres, S.A.) - Methylchlorpyrifos - Methylparathion - Vinclozoline - Fenitrothion - Malathion - Chlorpyrifos - Captan - Penconazol 0- Folpet - Chlozolinate - Triadimenol + Procimidione - Triadimenol - Hexocanozol - Captafol - Iprodione - Bromopropylate - Fenarimol - Cyalotrin 0- Fenvalerate - Fenvalerate - Azoxystrobine A.I.T FRANCE

10 Applications GC - Foods & Flavors Colonnes GC SEPARATION OF VOLATILES IN ALCOHOLIC BEVERAGES Column: TRB-WAX, P/N TR-0 Dimensions: 0m x 0.mm x.0μm Injection: μl, split Carrier gas: He, psi (. KPa) Oven temperature: ºC/min to 0ºC Detector: FID, ºC - Acetaldehyde - Ethyl acetate - Methanol - Ethanol (0%) - -Butanol - -Propanol - Isobutanol - Allyl alcohol - -Butanol 0- Isoamyl alcohols - Ethyl lactate ANALYSIS OF GLYCOLS IN WINE Column: TRB-FFAP, P/N TR-0 Dimensions: 0m x 0.mm x.0μm Injection: μl, split Carrier gas: He, psi (. KPa) Oven temperature: ºC/min to 00ºC(0 min) Detector: FID, ºC - Isoamyl alcohol - Ethyl lactate - Acetic acid - Levo-,-butanediol - Meso-,-butanediol -,-Propanediol - Glycerine ANALYSIS OF POLYOLS IN WINE Column: TRB-FFAP, P/N TR-0 Dimensions: 0m x 0.mm x 0.μm Injection: μl, split (00:), glycols standard, 0ºC Carrier gas: H, ml/min (0ºC) Oven temperature: ºC/min to 00ºC(0 min) Detector: FID, ºC - Ethanol -,-Butanediol -,-Propanediol - Ethylene glycol -,-Butanediol - Glycerol PHENOLS EPA 0 Column: TRB-, P/N TR-0 Dimensions: 0m x 0.mm x 0.μm Injection: μl, split, to ng/comp, 0ºC Carrier gas: H, psi (. KPa) Oven temperature: ºC/min to 0ºC Detector: FID, 0ºC - Phenol - Chorophenol - -Nitrophenol -,-Dimethylphenol -,-Dichlorophenol - -Chloro--methylphenol -,,-Trichlorophenol -,-Dinitrophenol - -Nitrophenol 0- -Methyl-,-dinitrophenol - Pentachlorophenol