SAFETY DATA SHEET. SECTION 1: Identification of the substance/mixture and of the company/undertaking

Transcription

1 SAFETY DATA SHEET SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name or designation of the mixture SDS number 7688 Metal Adhesive Component A Product code Ford Internal Ref.: Issue date Version number 1.0 Revision date Supersedes date Product use 11February March February2013 professional use 1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Uses advised against adhesives None known 1.3. Details of the supplier of the safety data sheet Company name Ford Motor Company Ltd. Address Parts Distribution Centre Royal Oak Way South UKNN 11 5NT Daventry, Northants United Kingdom Telephone number Company name FordWerke GmbH Address EdselFordStr. 214 D50769 Köln Germany Telephone number +49 (0) HSEBBS@bayer.com Emergency telephone (mo. fr. 09:00 16:00) number SECTION 2: Hazards identification 2.1. Classification of the substance or mixture The mixture has been assessed and/or tested for its physical, health and environmental hazards and the following classification applies. Classification according to Directive 67/548/EEC or 1999/45/EC as amended Classification Xi;R36/38, R43, N;R51/53 The full text for all Rphrases is displayed in section 16. Hazard summary Physical hazards Health hazards Environmental hazards Specific hazards Main symptoms 2.2. Label elements Not classified for physical hazards. Irritating to eyes and skin. May cause sensitisation by skin contact. Occupational exposure to the substance or mixture may cause adverse health effects. Toxic to aquatic organisms, May cause longterm adverse effects in the aquatic environment. Irritating to mouth, throat, and stomach. Irritating to eyes and skin. Do not breathe dust/fume/gas/mist/vapors/spray. Toxic to aquatic organisms, may cause longterm adverse effects in the aquatic environment. Irritating to eyes and skin. Irritating to mouth, throat, and stomach. Label according to Directive 67/548/EEC or 1999/45/EC as amended Contains: EC number 1,4BIS(2, 3EPO XYPRO POXY) BUTANE, Epoxy Phenol Novolac, Particulat e, REACTION PRODUCT: BISPHENOL A(EP ICHLO RHYDRIN) EPOXY RESIN (NUMBER AVERAGE MOLECULARW EIGHT ), REACTION PRODUCT: BISPHENOL A(EP ICHLO RHYDRIN) EPOXY RESIN (NUMBER AVERAGE MOLECULARW EIGHT <= 700) Ford Internal Ref.: Version No.: 1.0 Revision date: 05March2013 Issue date: 11February / 8

2 EC label Rphrases Sphrases Irritant Authorisation number Supplemental label information Dangerous for the environment R36/38 Irritating to eyes and skin. R43 May cause sensitisation by skin contact. R51/53 Toxic to aquatic organisms, May cause longterm adverse effects in the aquatic environment. S24 Avoid contact with skin. S26 In case of contact with eyes, Rinse immediately with plenty of water and seek medical advice. S35 This material and its container must be disposed of in a safe way. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S61 Avoid release to the environment. Refer to special instructions/ Safety data sheets Other hazards Not assigned. SECTION 3: Composition/information on ingredients 3.2. Mixtures General information Contains epoxy constituents. May produce an allergic reaction. Read and follow manufacturer's recommendations. Chemical name % CASNo. / EC No. REACH Registration No. INDEX No. Notes REACTION PRODUCT: BISPHENOLA(EPICHLO RHYDRIN) EPOXY RESIN (NUMBER AVERAGE MOLECULARWEIGHT <= 700) Classification: DSD: Xi;R36/38, R43, N;R51/53 CLP: Skin Irrit. 2;H315, Skin Sens. 1;H317, Eye Irrit. 2;H319, Aquatic Chronic 2;H411 Epoxy Phenol Novolac, Particulate Classification: DSD: Xi;R36/38, R43, N;R51/53 CLP: Skin Irrit. 2;H315, Skin Sens. 1;H317, Eye Irrit. 2;H319, Aquatic Chronic 2;H411 1,4BIS(2,3EPOXYPRO POXY) BUTAN E Classification: DSD: Xn;R20/21, Xi;R36/38, R43 CLP: Acute Tox. 4;H312, Skin Irrit. 2;H315, Skin Sens. 1;H317, Eye Irrit. 2;H319, Acute Tox. 4;H332 REACTION PRODUCT: BISPHENOLA(EPICHLO RHYDRIN) EPOXY RESIN (NUMBER AVERAGE MOLECULARWEIGHT ) Classification: DSD: Xi;R36/38, R43 CLP: Skin Irrit. 2;H315, Skin Sens. 1;H317, Eye Irrit. 2;H319 CLP: Regulation No. 1272/2008. DSD: Directive 67/548/EEC. PBT: persistent, bioaccumulative and toxic substance. vpvb: very persistent and very bioaccumulative substance. #: This substance has been assigned Community workplace exposure limit(s). Composition comments The full text for all R and Hphrases is displayed in section 16. Ford Internal Ref.: Version No.: 1.0 Revision date: 05March2013 Issue date: 11February / 8

3 SECTION 4: First aid measures General information 4.1. Description of first aid measures Inhalation Skin contact Eye contact Ingestion 4.2. Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Take off contaminated clothing and shoes immediately. Move to fresh air. For breathing difficulties, oxygen may be necessary. Call a physician if symptoms develop or persist. Immediately flush skin with plenty of water. Get medical attention if irritation develops and persists. Remove and isolate contaminated clothing and shoes. Wash clothing separately before reuse. Flush eyes immediately with large amounts of water. Get medical attention if irritation develops and persists. Get medical attention immediately. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Irritant effects. SECTION 5: Firefighting measures General fire hazards 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media 5.2. Special hazards arising from the substance or mixture Hazardous combustion products 5.3. Advice for firefighters Special protective equipment for firefighters Special fire fighting procedures SECTION 6: Accidental release measures Water spray, carbon dioxide, dry powder or polar resistant foam. Do not use water jet as an extinguisher, as this will spread the fire. Irritating fumes and gases may be released upon thermal processing or during combustion. Carbon monoxide, carbon dioxide and other hydrocarbon fragments. Wear full protective clothing, including helmet, selfcontained positive pressure or pressure demand breathing apparatus, protective clothing and face mask. Cool containers / tanks with water spray. Move containers from fire area if you can do it without risk. Dike fire control water for later disposal. Water runoff can cause environmental damage Personal precautions, protective equipment and emergency procedures For nonemergency personnel For emergency responders Keep unnecessary personnel away. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep upwind. Keep out of low areas. Ventilate closed spaces before entering them. Keep unnecessary personnel away. Use personal protection recommended in Section 8 of the MSDS Environmental precautions Avoid release to the environment. Refer to special instructions/safety data sheets. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Contact local authorities in case of spillage to drain/aquatic environment. Avoid discharge into drains, water courses or onto the ground Methods and material for containment and cleaning up Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Prevent entry into waterways, sewer, basements or confined areas. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination Reference to other sections Never return spills in original containers for reuse. For waste disposal, see section 13. For personal protection, see section 8. For waste disposal, see section 13. Ford Internal Ref.: Version No.: 1.0 Revision date: 05March2013 Issue date: 11February / 8

4 SECTION 7: Handling and storage 7.1. Precautions for safe handling 7.2. Conditions for safe storage, including any incompatibilities Do not breathe dust/fume/gas/mist/vapors/spray. Avoid contact with skin. Avoid contact with eyes. Avoid contact with clothing. Do not use in areas without adequate ventilation. Avoid prolonged exposure. When using, do not eat, drink or smoke. Wash hands thoroughly after handling. Avoid release to the environment. Handle and open container with care. Persons susceptible for allergic reactions should not handle this product. Store in a wellventilated place. Store in original tightly closed container. Store in a cool, dry place. Keep away from food, drink and animal feeding stuffs. Use care in handling/storage. Store in accordance with local/regional/national/internat ional regulation. Storage Temperature: Between 10 C and 25 C 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits Biological limit values Recommended monitoring procedures 8.2. Exposure controls Appropriate engineering controls No exposure limits noted for ingredient(s). No biological exposure limits noted for the ingredient(s). Follow standard monitoring procedures. Ensure adequate ventilation, especially in confined areas. Individual protection measures, such as personal protective equipment Eye/face protection Skin protection Hand protection Nitrile rubber. Avoid contact with eyes. Faceshield. Glove thickness 0,4 mm Break through time >= 480 min Glove recommendation: Camatril Velours 730 (KächeleCama GmbH, source of supply see or comparable product. Hand protection in case of splash contact: Nitrile rubber. Glove thickness 0,4 mm Break through time >= 480 min Glove recommendation: Camatril Velours 730 (KächeleCama GmbH, source of supply see or comparable product. The protective gloves to be used must comply with the specification of EU directive 89/686/EC and the resultant standard EN374. The above given information is based on laboratory test in line with EN374. The recommendation is only valid for the supplied product and the stated application. Special working conditions, like heat or mechanical strain, which deviate from the test conditions, can reduce the protective effect provided by the recommended glove. Other Personal protection equipment should be chosen according to the CEN standards and in discussion with the supplier of the personal protective equipment. Avoid contact with the skin. Wear chemical protective equipment that is specifically recommended by the manufacturer. Wear protective gloves. Respiratory protection Thermal hazards Hygiene measures Environmental exposure controls Use a positivepressure airsupplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where airpurifying respirators may not provide adequate protection. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Physical state When using, do not eat, drink or smoke. Avoid contact with eyes. Avoid contact with skin. Avoid contact with clothing. Wash hands before breaks and immediately after handling the product. Handle in accordance with good industrial hygiene and safety practices. Environmental manager must be informed of all major releases. Liquid. Ford Internal Ref.: Version No.: 1.0 Revision date: 05March2013 Issue date: 11February / 8

5 Odour Form Colour Odour threshold ph Melting point/freezing point Initial boiling point and boiling range Paste. colourless to brown. Odourless. > 200 C (> 392 F) Flash point > C (> F) Closed cup ( DIN ) Evaporation rate Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit lower (%) Flammability limit upper (%) Vapour pressure < C Vapour density Relative density Solubility(ies) Partition coefficient (noctanol/water) Decomposition temperature Viscosity Explosive properties Oxidizing properties 9.2. Other information insoluble Density C VOC (Weight %) 0 % SECTION 10: Stability and reactivity Reactivity None under normal conditions Chemical stability Material is stable under normal conditions Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. Hazardous polymerisation can occur with elevated temperatures Conditions to avoid Will decompose at temperatures exceeding 200 C Incompatible materials Acids. Amines. Bases. Strong oxidizing agents Hazardous decomposition products SECTION 11: Toxicological information General information Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. Information on likely routes of exposure Ingestion Inhalation Skin contact Eye contact Symptoms Irritating to skin. Irritating to eyes Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory sensitisation No data available. Irritating to skin. Irritating to eyes. Ford Internal Ref.: Version No.: 1.0 Revision date: 05March2013 Issue date: 11February / 8

6 Skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity single exposure Specific target organ toxicity repeated exposure Aspiration hazard Mixture versus substance information Other information May cause sensitisation by skin contact. SECTION 12: Ecological information Toxicity Toxic to aquatic organisms, may cause longterm adverse effects in the aquatic environment. Avoid discharge into drains, water courses or onto the ground. Components Species Test results REACTION PRODUCT: BISPHENOLA(EPICHLORHYDRIN) EPOXY RESIN (NUMBER AVERAGE MOLECULARWEIGHT <= 700) ( ) Aquatic Algae Crustacea Fish Persistence and degradability EC50 EC50 LC Bioaccumulative potential Partition coefficient noctanol/water (log Kow) Bioconcentration factor (BCF) Green algae (Selenastrum capricornutum) Water flea (Daphnia magna) Rainbow trout,donaldson trout (Oncorhynchus mykiss) No data is available on the degradability of this product Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Residual waste Contaminated packaging EU waste code Disposal methods/information Not a PBT or vpvb substance or mixture. 220 mg/l, 96 hours mg/l, 24 hours mg/l, 96 hours Dispose of in accordance with local regulations. Avoid discharge into water courses or onto the ground. Empty containers should be taken to an approved waste handling site for recycling or disposal. The Waste code should be assigned in discussion between the user, the producer and the waste disposal company. EWCcode: SECTION 14: Transport information ADR UN number UN proper shipping name Transport hazard class(es) Subsidiary class(es) This material and its container must be disposed of as hazardous waste. Must be incinerated in a suitable incineration plant holding a permit delivered by the competent authorities. Do not discharge into drains, water courses or onto the ground. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance with all applicable regulations. UN3082 Environmentally hazardous substance, liquid, n.o.s. (REACTION PRODUCT: BISPHENOLA(EPICHLORHYDRIN) EPOXY RESIN (NUMBER AVERAGE MOLECULARWEIGHT <= 700)) 9 Ford Internal Ref.: Version No.: 1.0 Revision date: 05March2013 Issue date: 11February / 8

7 14.4. Packing group III Environmental hazards Yes Tunnel restriction code E Labels required Special precautions for user IATA UN number UN UN proper shipping Environmentally hazardous substance, liquid, n.o.s. (REACTION PRODUCT: name BISPHENOLA(EPICHLORHYDRIN) EPOXY RESIN (NUMBER AVERAGE MOLECULARWEIGHT <= 700)) Transport hazard 9 class(es) Subsidiary class(es) Packing group III Environmental hazards Yes Labels required ERG Code 9L Special precautions for user IMDG UN number UN UN proper shipping name Environmentally hazardous substance, liquid, n.o.s. (REACTION PRODUCT: BISPHENOLA(EPICHLORHYDRIN) EPOXY RESIN (NUMBER AVERAGE MOLECULARWEIGHT <= 700)), Marine pollutant Transport hazard class(es) Subsidiary class(es) Packing group III Environmental hazards Marine pollutant Yes Labels required EmS No. FA, SF Special precautions for user Transport in bulk This substance/mixture is not intended to be transported in bulk. according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulations Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex I Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex II Regulation (EC) No. 850/2004 on persistent organic pollutants, Annex I as amended Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 1 as amended Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 2 as amended Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 3 as amended Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex V as amended Regulation (EC) No. 166/2006 Annex II Pollutant Release and Transfer Registry Regulation (EC) No. 1907/2006, REACH Article 59(1) Candidate List as currently published by ECHA Authorisations Ford Internal Ref.: Version No.: 1.0 Revision date: 05March2013 Issue date: 11February / 8

8 Regulation (EC) No. 143/2011 Annex XIV Substances Subject to Authorisation Restrictions on use Regulation (EC) No. 1907/2006, REACH Annex XVII Substances subject to restriction on marketing and use as amended Directive 2004/37/EC: on the protection of workers from the risks related to exposure to carcinogens and mutagens at work Not regulated. Directive 92/85/EEC: on the safety and health of pregnant workers and workers who have recently given birth or are breastfeeding Not regulated. Other EU regulations Directive 96/82/EC (Seveso II) on the control of majoraccident hazards involving dangerous substances Not regulated. Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work 1,4BIS(2,3EPOXYPROPOXY)BUTAN E (CAS ) REACTION PRODUCT: BISPHENOLA(EPICHLORHYDRIN) EPOXY RESIN (NUMBER AVERAGE MOLECULARWEIGHT <= 700) (CAS ) Directive 94/33/EC on the protection of young people at work 1,4BIS(2,3EPOXYPROPOXY)BUTAN E (CAS ) REACTION PRODUCT: BISPHENOLA(EPICHLORHYDRIN) EPOXY RESIN (NUMBER AVERAGE MOLECULARWEIGHT <= 700) (CAS ) Other regulations National regulations Chemical safety assessment SECTION 16: Other information List of abbreviations References Information on evaluation method leading to the classification of mixture Full text of any statements or Rphrases and Hstatements under Sections 2 to 15 Revision information Training information Disclaimer The product is classified and labelled in accordance with EC directives or respective national laws. This Safety Data Sheet complies with the requirements of Regulation (EC) No 1907/2006. Young people under 18 years old are not allow to work with this product according to the EU Directive 94/33/EC on the protection of young people at work. Contains epoxy constituents. See information supplied by the manufacturer. No Chemical Safety Assessment has been carried out. R20/21 Harmful by inhalation and in contact with skin. R36/38 Irritating to eyes and skin. R43 May cause sensitisation by skin contact. R51/53 Toxic to aquatic organisms, May cause longterm adverse effects in the aquatic environment. H312 Harmful in contact with skin. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H411 Toxic to aquatic life with long lasting effects. The information in the sheet was written based on the best knowledge and experience currently available. Ford Internal Ref.: Version No.: 1.0 Revision date: 05March2013 Issue date: 11February / 8

9 Attachment to the Safety Data Sheet Product Name: Metal Adhesive Component A Page: 1/1 Ford Int. Ref. No.: Print Date: Involved Products: FinisCode 1. Part of Kit: Part number 2U7J M2G400 BA 2U7J M2G400 AA Container Size: 80 ml Metal Adhesive Kit 2 Component J / GBEN