Car Interior Material Testing (CIMT)

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1 Car Interior Material Testing (CIMT) Emission and Material Testing of Interior Materials and Parts: Test Methods Chances & Benefits Air Quality Seminar May, 2007 University of Warwick Dr. Lutz Mayer 1

2 AGENDA 1 When you need to be sure SGS an overview 2 Automotive Services 3 CIMT Car Interior Material Testing 2

3 SGS in words and figures Founded in ,000 employees worldwide Global network of about 1,000 laboratories and offices around the world Revenue 2006: 2,414 billion EUR Active in Germany since ,600 employees nationwide 30 locations in Germany 3

4 SGS 127 years of competence inspection testing Inspection, verification, testing and certification SGS SA is the world s leading company within these fields We compare and analyze commodities, products and services, complex technical methods as well as business systems certification verification 4

5 Business Segments of SGS and INSTITUT FRESENIUS Agricultural Services Automotive Services Consumer Testing Services Environmental Services Industrial Services Life Science Services Minerals Services Oil, Gas & Chemicals Services Systems and Services Certification Technical Staffing Services Trade Assurance Services 5

6 SGS Our Guiding Principles Independence and neutrality We don t engange in manufacturing nor do we have trading interests SGS Code of Integrity and Professional Conduct The commitment of our employees as guarantee of absolute confidentiality concerning all information Best in class QS/QM certification Accreditation and certification according to highest standards 6

7 2 SGS Automotive Services 7

8 SGS Automotive Services, Germany Automotive Services Matthias Popp CTS Car Interior Material Testing (CIMT) CTS Failure Analysis SGS Automotive SGS OGC / Automotive services SGS ICS / Automotive services Lutz Mayer, PhD Olaf Günnewig, PhD Christian Naumann Bernd Schwarz Sven Schirmer 8

9 3 CIMT Car Interior Material Testing 9

10 Locations Rostock Wilhelmshaven HAMBURG Bremen Berlin Hannover Herten Dortmund Taunusstein Sulzbach Speyer Dresden München Taunusstein: Berlin: Dresden: Dortmund: Herten: Headquarter, Bioanalytics, Special Analytics, Mineral Waters, Beverages Pharma, Waste Microelectronic Business Line Automotive Failure&Damage Analysis Mechanical tests Water, Waste Water, Soil CTS Automotive Car Interior Material Testing 10

11 HIGH-TECH-ANALYTIC Investment: Since 2003: Euro Central Lab: Individual logistical ways Soil Drinking water Waste water Automotive 11

12 HIGH-TECH-ANALYTICS Staff: 2006: 75 employees Benchmarks: > 900 samples per day > 500 parameters Conc. 0,001µg/kg (ppt) 12

13 Development of Division Car Interior Material Testing (CIMT) CTS Automotive/Herten Accreditation by DaimlerChrysler Start up of commercial testings Modernization & Extension of technical equipment (2 nd production line) Recommendation by VW, VOLVO, SAAB Recommendation by BMW, Porsche Accreditation by Toyota (only two institutes in Europe) First IF department with flexible accreditation acc. DIN Implementation of chamber tests: weathering test, hot light fastness, hot light ageing, Emission Test Chamber Reaccreditation by TOYOTA Implementation of sun tests/solar climatic tests resistance test Reaccreditation acc. DIN 17025; flexible test fields: emission and material tests Extension of technical equipment: TDS/GC/MS (3 rd production line) nd emission test chamber, 1.5 m³ weathering test chamber 13

14 Description of the market for CIMT CIMT is accredited/ recommended by BMW DaimlerChrysler GM Porsche Toyota Volvo VW Group Most approvals in the European market. OEM Automotive system suppliers Tier 1 Automotive suppliers Tier 2 3 (current number of clients > 450) 14

15 Market mechanism: Top sales down approach Test Results Accepted only by recommended labs OEM Tier 1-3 Specifications List of test labs Test Results Recommendation/ Accreditation Car Interior Material Testing SGS INSTITUT FRESENIUS GmbH CTS Automotive / Herten Materials/ Parts 15

16 Business Relationships Locations of the CIMT clients Revenue Germany 66% Europe/WW 33% > 450 clients in more than 30 countries number of samples in in about investigations 16

17 CIMT: Fields of testing (extract) test materials: all non-metallic materials, including foam, plastic, lacquer, fabrics, leather, rubber etc. Emission testings Odour VOC of materials, composites FOG of materials, composites Determination of hazardous substances The emission test lab with the highest amount of VOC tests in Europe. Material testings UV, Colour stability Hot light fastness Hot light ageing, warm ageing Weathering, Solar simulation Climatic stress test Burning behaviour Resistance tests Total number of methods: 120 according to OEM STD: 90 according to VDA/DIN/EU: 30 17

18 Emission Testings Requirement: reduction of emission (odour, VOC, FOG) Solution: odour and emission tests Odour characterization, VOC, FOG Test samples: all kind of materials, composites up to parts/systems (e.g. seats, door panel, instrument panel) Detection of hazardous substances Benefits: Odour ranking Detection of VOC/FOG sources Reduction of hazardous substances health care More legal certainty regarding liability Technical approval entrance on restricted market (US CARB) 77 accredited test methods ISO and by OEM high acceptance 18

19 Odour Testings TSM 0505 G VDA

20 Odour Testings TSM 0505 G 20

21 Definitions Emissions VOC FOG Emissions (under the influence of heat) are differentiated into VOC & FOG VOC: Volatile Organic Compounds FOG: all fogging substances which condense on surfaces and form coatings primarily on windscreens and rear windows 21

22 Fogging Testings DIN A & B PV 3015 Volvo VCS 1027, 2719 Renault / PSA D etc. 22

23 Emission Testings DIN A & B reflectometric & gravimetric fogging test Result determination of 60 - reflectory data against cleaned glass or weight of foil before and after the test G / mg Advantages influence of fogging on windows (reflexes, etc.) quantity of fogging (T)FOG Disadvantages no information about substances additional tests required 23

24 Emission Testings Headspace GC/FID VDA 277/PV 3341/Volvo VCS 1027,

25 Emission Testings VDA 277/PV 3341/Volvo VCS 1027,

26 Emission Testings Result VDA 277/PV 3341/Volvo VCS 1027, 2749 Total carbon emission in µg C/g (µg carbon per g sample) Advantages Quantification TVOC Determination of individual substances is possible Disadvantages No differentiation between VOC & FOG High temperature for a long time: pyrolysis possible Additional high-effort steps needed to determine individual substances 26

27 TDS/GC/MS VDA

28 TDS/GC/MS VDA 278 Desorption conditions VOC 90 C FOG 120 C 28

29 Emission Testings VDA 278 Result VOC & FOG in ppm (mg/kg) in toluene or hexadecane equivalents Advantages VOC & FOG as single parameter Low temperatures (no pyrolyzing) Disadvantage Analyzing composites only under additional expense possible Coupled with GC/MS: identification of single substances Quantification 29

30 Toyota Test Methods provided by CIMT TSM 0500 G Burning behaviour TSM 0503 G Fogging test according to method b TSM 0505 G Odour test with qualification TSM 0508 G Currently: Cooperation between Toyota Europe and SGS Institut Fresenius GmbH VOC test by using Tedlar bags TSM 0509 G VOC test by using TDS and HPLC VDA

31 TDS (Toyota): Volatile Hydrocarbons 31

32 TDS (Toyota) : Volatile Hydrocarbons 32

33 DNPH (Toyota): Aldehydes and Ketones 33

34 TOYOTA TSM 0509G 34

35 Emission Test Chamber VCE 1000 GS / -3 C total: TVOC Screening (Carbotrap/TDS) BTXE/S Aldehydes, ketones, amines N-nitrosoamine Phthalic acid esters Fogging US Carb Test PPV Circular VDA 276 Part 1 C total: TVOC BTXE/S Aldehydes, ketones Fogging VDA 276 Part 2 Ammonia Formaldehyde Phenol 35

36 Emission Test Chamber VCE 1000 Range of Specimens 36

37 Thank you for your attention! SGS INSTITUT FRESENIUS GmbH Am Technologiepark 10 D Herten Telefon: +49 (0) Telefax: +49 (0) Internet:

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