Phoenix. 10 litres œ MAPP PCS Warning MAPP PCS 04453

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1 Phoenix MAPP PCS For protection against leaf blotch (Septoria tritici/ Mycosphaerella gramincola) on wheat and triticale and leaf blotch (Rhynchosporium secalis) on barley and triticale. A suspension concentrate formulation containing 500 g/l (39.5% w/w) folpet. Contains folpet and hexamethylene tetramine: may produce an allergic reaction. 10 litres œ Warning Suspected of causing cancer. Very toxic to aquatic life with long lasting effects. Contains folpet and hexamethylene tetramine. May produce an allergic reaction. Keep out of reach of children. UK only: Dispose of contents/container to a licensed hazardous waste disposal contractor or collection site except for empty, clean containers which can be disposed of as non-hazardous waste. Ireland only: Dispose of contents/container to a licensed waste disposal contractor or collection site except for triple rinsed, empty containers which can be disposed of as non-hazardous waste. To avoid risks to human health and the environment, comply with the instructions for use. MAPP PCS FR D/ R3.2.4AUG14

2 Crop Winter wheat, spring wheat, winter barley, spring barley and triticale SAFETY PRECAUTIONS This leaflet/booklet is part of the approved label. For advice on medical emergencies, fires or major spills telephone the UK National Chemical Emergency Centre on +44 (0) UK only: The (COSHH) Control of Substances Hazardous to Health Regulations may apply to the use of this product at work. Operator Protection Engineering control of operator exposure must be used where reasonably practicable in addition to the following personal protective equipment. WEAR SUITABLE PROTECTIVE GLOVES when handling the concentrate or handling contaminated surfaces. UK only: However, engineering controls may replace personal protective equipment if a COSHH assessment shows they provide an equal or higher standard of protection. WASH CONCENTRATE from skin or eyes immediately. WASH HANDS AND EXPOSED SKIN before eating or drinking and after work. IF YOU FEEL UNWELL, seek medical advice immediately (show the label where possible). Environmental Protection Do not contaminate water with the product or its container. Do not clean application equipment near surface water. Avoid contamination via drains from farmyards and roads. IMPORTANT INFORMATION FOR PROFESSIONAL USE ONLY AS AN AGRICULTURAL FUNGICIDE Maximum individual dose (litres of product/ha) Maximum total dose (litres of product/ha/crop) 1 Latest time of application Before end of heading/ inflorescence fully emerged (GS 59) READ THE LABEL BEFORE USE. USING THIS PRODUCT IN A MANNER THAT IS INCONSISTENT WITH THE LABEL MAY BE AN OFFENCE. FOLLOW THE CODE OF PRACTICE FOR USING PLANT PROTECTION PRODUCTS. UK only: To protect aquatic organisms respect an unsprayed buffer zone distance to surface water bodies in line with LERAP requirements. Ireland only: To protect aquatic organisms respect an unsprayed buffer of 5 metres to surface water bodies. UK only: DO NOT ALLOW DIRECT SPRAY from horizontal boom sprayers to fall within 5m of the top of the bank of a static or flowing water body unless a Local Environmental Risk Assessment for Pesticides (LERAP) permits a narrower buffer zone, or within 1m of the top of a ditch which is dry at the time of application. Aim spray away from water. UK only: This product qualifies for inclusion within the Local Environmental Risk Assessment for Pesticides (LERAP) scheme. Before each spraying operation from a horizontal boom sprayer, either a LERAP must be carried out in accordance with HSE s published guidance or the statutory buffer zone must be maintained. The results of the LERAP must be recorded and kept available for three years. Storage and Disposal KEEP IN ORIGINAL CONTAINER, tightly closed, in a safe place. DO NOT RE-USE CONTAINER FOR ANY PURPOSE.

3 DIRECTIONS FOR USE IMPORTANT: This information is approved as part of the Product Label. All instructions within this section must be read carefully in order to obtain safe and successful use of this product. Resistance PHOENIX contains folpet, a protectant fungicide from the phthalimide chemical group with multisite contact activity. For resistance management purposes, it s mode of action is classified as M4 under the FRAC* code which indicates low-risk without any signs of resistance or cross-resistance developing. For current advice on resistance management contact your agronomist or specialist advisor, and visit the FRAG-UK website. Disease control in wheat, barley and triticale For the reduction of leaf spot (Septoria tritici/ Mycosphaerella graminicola) in winter and spring wheat and triticale and leaf blotch (Rhynchosporium secalis) in winter and spring barley and triticale. PHOENIX may be applied in a programme of 2 suitably timed sprays. Dose rate 1.5 L/ha per application Septoria leaf spot (Septoria tritici/mycosphaerella graminicola) in winter and spring wheat and triticale As PHOENIX is a protectant fungicide with contact activity, it is important to apply the first spray before the disease becomes established in the crop (normally GS 30-33). A second spray should be timed to protect new growth from disease and therefore needs to be applied prior to further infection. This is normally 3 weeks after the first application, but may be sooner under conditions of rapid growth and high disease pressure. Where disease infection or reinfection has occurred prior to application, PHOENIX should be mixed with alternative chemistry, e.g. epoxiconazole, to provide curative activity (see Compatibility section). 2 Leaf blotch (Rhynchosporium secalis) in winter and spring barley and triticale As PHOENIX is a protectant fungicide with contact activity, it is important to apply the first spray before the disease becomes established in the crop (normally GS 30-33). A second spray should be timed to protect new growth from disease infection. This is normally 3 weeks after the first application, but may be sooner under conditions of rapid growth and high disease pressure. Where disease infection or reinfection has occurred prior to application, PHOENIX should be mixed with alternative chemistry, e.g. epoxiconazole, to provide curative activity (see Compatibility section). Water volume Apply PHOENIX in a water volume of L/ha. Qualified recommendation: Lower water volumes of 100 L/ha may also be used, however these have not been supported by effectiveness or crop safety data. As PHOENIX has contact activity, it is important to achieve a good coverage of the crop when spraying. Mixing and spraying For use by tractor mounted/trailed sprayer only. Before spraying it is important to check all hoses, filters and nozzles, and to ensure that the sprayer is clean and correctly calibrated to give an accurate application at the correct volume. Half fill sprayer tank with clean water. Add the required amount of PHOENIX to the water and commence agitation. On emptying the container, RINSE CONTAINER THOROUGHLY by using an integrated pressure rinsing device or manually rinsing three times. Add washings to sprayer at time of filling and dispose of container safely. Add the remainder of the water whilst continuing to agitate the mixture until spraying is complete. Apply PHOENIX as a medium spray (as defined by the BCPC) in cereals. Thoroughly clean the sprayer and measuring equipment after using PHOENIX.

4 Compatibility Approval holder and Marketing Company UK only: PHOENIX may be tank-mixed with Adama Agricultural Solutions UK Ltd Opus or Cortez which must be applied at the Unit 15, Thatcham Business Village recommended rate of use against these diseases. Colthrop Way Ireland only: Consult Adama Agricultural Solutions Thatcham UK Ltd or your distributor for details on the products Berkshire which may be mixed with PHOENIX in Ireland. RG19 4LW Telephone: + 44 (0) Maintain agitation during the mixing process and Technical Helpline: + 44 (0) continue until the spraying is complete. Do not leave For UK: in spray tank for long periods without using. For Ireland: Caution After spraying a herbicide, sprayer tanks and equipment should be thoroughly cleaned before using PHOENIX. CONDITIONS OF SUPPLY All products supplied by us are of high grade and conform to specification at the time of delivery, but, as we cannot exercise control over their subsequent storage, handling, mixing or use or the weather conditions before, during and after application which may affect the performance of the products, all conditions and warranties, statutory or otherwise, as to the quality or fitness for any purpose of our products are excluded and no responsibility or liability will be accepted by us or our re-sellers for any failure in performance, damage or injury to person or property whatsoever arising from the storage, handling, application or use of the products. These conditions cannot be varied by our staff or agents whether or not they supervise or assist in the use of such products. 3 Phoenix and Cortez are registered trademarks of a company of the Adama Group. Opus is a registered trademark of BASF Adama Agricultural Solutions UK Ltd *FRAC: Fungicide Resistance Action Committee R3.2.4AUG14

5 This Safety Data Sheet does not form part of the approved label. Following the instructions on the pesticide Product Label for the specified uses should ensure that the product is used safely and efficaciously for those uses. SAFETY DATA SHEET Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) Annex II Revision Date 12-Nov-2013 Version 2 Product No. FNG /1 Publish Date 12-Nov-2013 R-6289-EU MCW-296 SC Section 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier PHOENIX Pure substance/mixture Mixture 1.2. Relevant identified uses of the substance or mixture and uses advised against Recommended use Fungicide Uses advised against No information available 1.3. Details of the supplier of the safety data sheet Supplier address Adama Agricultural Solutions UK Ltd Unit 15, Thatcham Business Village, Colthrop Way Thatcham, Berkshire RG19 4LW Tel: +44 (0) Fax: +44 (0) For further information, please contact address 1.4. Emergency telephone number Emergency telephone National Chemical Emergency Centre (UK): Tel: +44 (0) (24 hours) Section 2: HAZARD IDENTIFICATION 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Carcinogenicity Category 2 - (H351) Acute aquatic toxicity Category 1 - (H400) Classification according to Directive 67/548/EEC or 1999/45/EC. Full text of R-phrases: see Section 16. Carc. cat 3;R40 - N;R Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms Signal word Warning

6 Hazard statements Precautionary statements EU Specific hazard statements Additional phrases for PPP 2.3. Other hazards No information available. H351 - Suspected of causing cancer H400 - Very toxic to aquatic life P102 - Keep out of reach of children P201 - Obtain special instructions before use P281 - Use personal protective equipment as required P501 - Dispose of contents/container to an approved waste disposal plant EUH208 - Contains folpet and methenamine. May produce an allergic reaction EUH401 - To avoid risks to human health and the environment, comply with the instructions for use SP1 - Do not contaminate water with the product or its container Section 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2 Mixture Weight -% CAS No. EC No. Index No. Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to 67/548/EEC M- Factor REACH Registration Number Folpet Acute Tox. 4 (H332) Xn; R20 M=10 - Eye Irrit. 2 (H319) Skin Sens. 1 (H317) Carc. 2 (H351) Aquatic Acute 1 (H400) Xi; R36 R43 Carc.Cat.3; R40 N; R50 Sulfonated N/A - - Skin Irrit. 2 (H315) Xi; R36/38 - aromatic polymer, sodium salt Eye Irrit. 2 (H319) Fumaric acid X Eye Irrit. 2 (H319) Xi; R36 - Methenamine Flam. Sol. 2 (H228) F; R11 - Skin Sens. 1 (H317) R43 Full text of R-phrases: see Section 16. Full text of H- and EUH-phrases: see Section 16. Section 4: FIRST AID MEASURES 4.1. Description of first aid measures Eye contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Keep eye wide open while General advice In case of accident or unwellness, seek rinsing. If symptoms persist, call a medical advice immediately (show physician. directions for use or safety data sheet if possible). First aider: Pay attention to Ingestion Rinse mouth. Drink plenty of water. If self-protection! symptoms persist, call a physician. Inhalation Remove to fresh air. If breathing is Self-protection of Use personal protective equipment as irregular or stopped, administer artificial the first aider required. respiration. Call a physician Most important symptoms and effects, both acute and Skin contact Wash off immediately with soap and delayed plenty of water while removing all Symptoms None known contaminated clothes and shoes. Consult a physician if necessary Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically.

7 Section 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media No information available Special hazards arising from the substance or mixture No specific hazard known Advice for firefighters In the event of fire, wear self-contained breathing apparatus. In the event of fire and/or explosion do not breathe fumes. Section 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions Use personal protective equipment as required. For emergency responders Use personal protection recommended in Section Environmental precautions Prevent entry into waterways, sewers, basements or confined areas. Do not flush into surface water or sanitary sewer system Methods and material for containment and cleaning up Methods for cleaning up Take up mechanically, placing in appropriate containers for disposal Reference to other sections Other information See also Sections 8 and 13. Section 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Advice on safe handling Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Wash contaminated clothing before reuse. Do not breathe dust/fumes/gas/mist/vapours/spray. Do not eat, drink or smoke when using this product. General hygiene considerations When using do not eat, drink or smoke. Wash contaminated clothing before reuse Conditions for safe storage, including any incompatibilities Storage conditions Keep container tightly closed in a dry and well-ventilated place. Keep out of the reach of children Specific end use(s) Risk Management Methods (RMM) The information required is contained in this Material Safety Data Sheet. Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Austria Switzerland Methenamine Poland Norway Ireland TWA: 4 mg/m 3 TWA: 3 mg/m 3 STEL: 6 mg/m 3 Derived No Effect Level (DNEL) No information available. Predicted No Effect Concentration (PNEC) No information available Exposure controls Engineering controls Ensure adequate ventilation, especially in confined areas. Personal protective equipment Eye/face protection Tight sealing safety goggles. Body protection Suitable protective clothing. General hygiene considerations When using do not eat, drink or smoke. Wash contaminated clothing before reuse. Environmental exposure controls Do not allow into any sewer, on the ground or into any body of water.

8 Section 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Property Values Method Remarks Appearance Physical state : Liquid Colour : Beige white Odour : Organic slight Odour threshold : No data available ph : CIPAC MT 75.3 Melting point/freezing point C : No data available Boiling point/boiling range C : No data available Flash point C : >80 EEC A.9 Evaporation rate : Not applicable Flammability (solid, gas) : Not applicable Upper/lower flammability or : No data available explosive limits Vapour pressure : No data available Vapour density : No data available Relative density : EEC A.3 22 C Solubility(ies) : ---- Not applicable Partition coefficient (n-octanol/water) Log Pow : See Section 12 for more information Autoignition temperature C : >400 EEC A.15 Decomposition temperature C : No data available Kinematic viscosity mm 2 /s 40 C : 1500 CIPAC MT C Explosive properties : Not an explosive Oxidising properties : No data available 9.2. Other information Bulk density g/ml : Surface tension mn/m : ---- No data available Section 10: STABILITY AND REACTIVITY Reactivity Not available Chemical stability Stable under normal conditions Possibility of hazardous reactions None under normal processing Conditions to avoid Heat, flames and sparks Incompatible materials No information available Hazardous decomposition products

9 Section 11: TOXICOLOGY INFORMATION Information on toxicological effects Acute toxicity Values Species Method Remarks Oral LD50 mg/kg : >5000 Rat OECD 401 Dermal LD50 mg/kg : >2000 Rat OECD 402 Inhalation LC50 mg/l/4h : >5.28 Rat OECD 403 Skin corrosion/irritation : Non-irritating to the skin Rabbit OECD 404 Serious eye damage/eye irritation : Not irritating to eyes Rabbit OECD 405 Respiratory/skin sensitisation : Not a skin sensitiser Guinea pig OECD 406 Chronic toxicity Germ cell mutagenicity Folpet : Not classified Carcinogenicity Folpet : Carcinogenic category 2 Reproductive toxicity Folpet : Not toxic for the reproductive system STOT - single exposure Folpet : Not available STOT - repeated exposure Folpet : Not available Aspiration hazard Folpet : Not available Section 12: ECOLOGICAL INFORMATION Toxicity Acute toxicity Aquatic toxicity Values Species Method Remarks Fish 96-hour LC50 mg/l : Rainbow trout OECD 204 Crustacea 48-hour EC50 mg/l : 3.9 Daphnia magna OECD 202 Algae 72-hour EC50 mg/l : 48.4 Scenedesmus OECD 201 subspicatus Other plants EC50 mg/l : OECD 221 Not available Terrestrial toxicity Birds oral LD50 mg/kg Folpet : >2510 Bobwhite quail EPA 71-1 Bees oral LD50 μg/ee Folpet : >236 EPPO 170 (1992) Oral

10 12.2. Persistence and degradability Abiotic degradation Values Method Remarks Water DT50 days Folpet : <0.05 OECD 111 ph 7 Soil DT50 days Folpet : 4.3 SETAC 25 C Biodegradation Folpet : Readily biodegradable OECD 301 B Bioaccumulative potential Partition coefficient Values Method Remarks (n-octanol/water) Log Pow Folpet : C Bioconcentration factor (BCF) Folpet : 56 OECD 305E Mobility in soil Adsorption/desorption Values Method Remarks Folpet : 304 Koc Results of PBT and vpvb assessment The components in this formulation do not meet the criteria for classification as PBT or vpvb Other adverse effects No information available. Section 13: DISPOSAL CONSIDERATIONS Waste treatment methods Waste from residues/unused products Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Improper disposal or reuse of this container may be dangerous and illegal. Other information Waste codes should be assigned by the user based on the application for which the product was used. Section 14: TRANSPORTATION INFORMATION IMDG/IMO 14.1 UN/ID No Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Folpet) 14.3 Hazard class Packing group III 14.5 Marine pollutant Yes 14.6 Special precautions for user RID/ADR 14.1 UN/ID No Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Folpet) 14.3 Hazard class Packing group III 14.5 Environmental hazard Yes 14.6 Special precautions for user

11 ICAO/IATA 14.1 UN/ID No Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Folpet) 14.3 Hazard class Packing group III 14.5 Environmental hazard Yes 14.6 Special precautions for user 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable Section 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Chemical safety assessment A chemical safety assessment according to regulation (EC) No. 1907/2006 is not required. A risk assessment was performed according to directive (EC) No. 91/414 or according to regulation (EC) No. 1107/2009. Section 16: OTHER INFORMATION Full text of R-phrases referred to under Sections 2 and 3 R40 - Limited evidence of a carcinogenic effect R50 - Very toxic to aquatic organisms R43 - May cause sensitisation by skin contact R36 - Irritating to eyes R20 - Harmful by inhalation R11 - Highly flammable R36/38 - Irritating to eyes and skin Full text of H-Statements referred to under Sections 2 and 3 H228 - Flammable solid H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H332 - Harmful if inhaled H351 - Suspected of causing cancer if inhaled H400 - Very toxic to aquatic life H315 - Causes skin irritation This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006 Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet

12 Phoenix MAPP PCS A suspension concentrate formulation containing 500 g/l (39.5% w/w) folpet. Contains folpet and hexamethylene tetramine: may produce an allergic reaction. UK only - The (COSHH) Control of Substances Hazardous to Health Regulations may apply to the use of this product at work. SAFETY PRECAUTIONS Operator Protection Engineering control of operator exposure must be used where reasonably practicable in addition to the following personal protective equipment. WEAR SUITABLE PROTECTIVE GLOVES when handling the concentrate or handling contaminated surfaces. UK only: However, engineering controls may replace personal protective equipment if a COSHH assessment shows they provide an equal or higher standard of protection. WASH CONCENTRATE from skin or eyes immediately. WASH HANDS AND EXPOSED SKIN before eating or drinking and after work. IF YOU FEEL UNWELL, seek medical advice immediately (show the label where possible). Crop Winter wheat, spring wheat, winter barley, spring barley and triticale Environmental Protection Do not contaminate water with the product or its container. Do not clean application equipment near surface water. Avoid contamination via drains from farmyards and roads. UK only: To protect aquatic organisms respect an unsprayed buffer zone distance to surface water bodies in line with LERAP requirements. Ireland only: To protect aquatic organisms respect an unsprayed buffer of 5 metres to surface water bodies. UK only: DO NOT ALLOW DIRECT SPRAY from horizontal boom sprayers to fall within 5m of the top of the bank of a static or flowing water body unless a Local Environmental Risk Assessment for Pesticides (LERAP) permits a narrower buffer zone, or within 1m of the IMPORTANT INFORMATION FOR PROFESSIONAL USE ONLY AS AN AGRICULTURAL FUNGICIDE Maximum individual dose (litres of product/ha) Adama Agricultural Solutions UK Ltd Unit 15, Thatcham Business Village, Colthrop Way, Thatcham, Berkshire RG19 4LW Telephone: +44 (0) Technical Helpline: +44 (0) UK: Ireland: For advice on medical emergencies, fires or major spills telephone the UK National Chemical Emergency Centre on +44 (0) Batch No.: see packaging SHAKE WELL BEFORE USE PROTECT FROM FROST Maximum total dose (litres of product/ha/crop) top of a ditch which is dry at the time of application. Aim spray away from water. UK only: This product qualifies for inclusion within the Local Environmental Risk Assessment for Pesticides (LERAP) scheme. Before each spraying operation from a horizontal boom sprayer, either a LERAP must be carried out in accordance with HSE s published guidance or the statutory buffer zone must be maintained. The results of the LERAP must be recorded and kept available for three years. Storage and Disposal KEEP IN ORIGINAL CONTAINER, tightly closed, in a safe place. DO NOT RE-USE CONTAINER FOR ANY PURPOSE. Latest time of application Before end of heading/ inflorescence fully emerged (GS 59) READ THE LABEL BEFORE USE. USING THIS PRODUCT IN A MANNER THAT IS INCONSISTENT WITH THE LABEL MAY BE AN OFFENCE. FOLLOW THE CODE OF PRACTICE FOR USING PLANT PROTECTION PRODUCTS. BK C/ R3.2.4AUG14

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