1 Page 1 / 7 1. Identification of the Product and of the Company. 1.1 Product name: Apiguard Acaricide aqueous gel 1.2 Company name: VITA (EUROPE) LIMITED BASINGSTOKE, HAMPSHIRE, UNITED KINGDOM Telephone: Telefax: Emergency Telephone Numbers: 44 (0) (0) Composition / Information on Ingredients 2.1 Chemical characterisation of the preparation: Chemical Class: Formulation Type: Sector: Phenol Aqueous gel ACARICIDE Active Ingredient (s): 25% (w/w) THYMOL (2-Isopropyl-5-methylphenol) 2.2 Hazardous Component (s): Contains: THYMOL (2-Isopropyl-5-methylphenol) Empirical Formula: C 10 H 14 O Molecular Weight: Content: 25% (w/w) CAS-Reg. No.: EC-No.: EC-label: R22 Harmful if swallowed. R34 Causes burns. S26 In cases of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 S36/37/39 After contact with skin, wash immediately with plenty of soap-suds. Wear suitable protective clothing, gloves and eye/face protection.
2 Page 2 / 7 3. Hazards Identification 3.1 Potential Health Hazards: The active ingredient THYMOL resembles phenol in its systemic actions but it is less toxic. 3.2 Eyes: Irritation of eyes with redness and pain. 3.3 Skin: Irritation of skin with redness and pain. 3.4 Inhalation: May cause severe and permanent damage to the digestive tract. Causes gastrointestinal irritation with nausea, vomiting and diarrhoea. Irritation of respiratory tract. 3.5 Ingestion: Abdominal pain with possible nausea, vomiting and occasional convulsions. Oils and alcohol may promote absorption into the body. 3.6 Chronic Exposure: No data found. 4. First Aid Measures 4.1 Eyes: Flush eyes thoroughly with running water (for at least 15 minutes) lifting upper and lower lids occasionally. Seek medical advice if irritation persist. 4.2 Skin: Rinse the skin immediately with copious amounts of water. Immediately remove contaminated clothing. Seek medical advice if symptoms develop. 4.3 Inhalation: In cases of excessive inhalation of vapour and/or gases, remove the casualty into fresh air. If nausea persists or symptoms of poisoning are apparent, seek medical attention. 4.4 Ingestion : Clean mouth with water and give large amounts of water (although not to unconscious). Do not induce vomiting. Symptoms of poisoning may occur during at least 48 hours following ingestion; therefore, medical advice must be sought. Symptoms include irritation of gastric mucosa, abdominal pain, nausea, vomiting, shortness of breath and circulatory collapse.
3 Page 3 / Chronic Exposure: No data found: 4.6 Note to Physician: No specific antidote, treat symptomatically. 5. Fire Fighting Measures 5.1 Extinguishing media: Suitable agents: Not to be used: alcohol-resistant foam, carbon dioxide dry powder. full water jet. 5.2 Special protective equipment for fire fighters: Wear self-contained breathing apparatus. 6. Accidental Release Measures Use personal protective clothing. Do not contaminate waters or sewers. Collect the product in containers for safe disposal. Collect material in specially marked, tightly closing containers. Spilled product cannot be used further and must be disposed of. If safe disposal is not possible, contact the manufacturer, supplier or the local representative. 7. Handling and Storage 7.1 Handling: Wash after handling. Avoid contact with the eyes, skin and clothing. Avoid digestion and inhalation. 7.2 Storage: Store in a cool, dry place. Maximum storage temperature: 30 C. Shelf life in original, sealed containers in a temperate climate is: - 36 months minimum for the 50g aluminium-foil container (tray), - 36 months minimum for the 3kg polypropylene container (tub). Store in undamaged, properly sealed, original containers protected from light by secondary packaging. Do not open until ready to use. Keep away form incompatible materials. Observe all warnings and precautions for the product.
4 Page 4 / 7 8. Exposure Controls and Personal Protection 8.1 Occupational Toxicity Risk: Low, when used as directed. 8.2 Engineering Controls: Facilities storing or utilising this material should be equipped with eyewash facility and a safety shower. Use adequate ventilation. 8.3 Industrial Hygiene: Keep away from food, drink and animal feedstuffs. When using do not eat, drink or smoke. Change contaminated clothes immediately. After work and before taking breaks, wash your hands. 8.3 Personal protective equipment: Respiratory protection: Not required if the product is handled in the open or properly ventilated in-door places, otherwise respiratory protection is recommended. Eye protection: Hand protection: Others: chemical safety goggles or glasses gloves working clothes 9. Physical and Chemical Properties 9.1 Form: aqueous granular gel (a solid suspended in a liquid) 9.2 Colour: slightly opalescent, colourless to pale pink 9.3 Odour: characteristic, strong aromatic, thyme-like 9.4 Change in physical state: Melting point: 49.5 C for THYMOL (100%) Boiling point: 233 C for THYMOL (100%) 9.5 Flash point: > 100 C 9.6 Ignition temperature: not applicable 9.7 Explosion limits: not applicable 9.8 Density (Specific Gravity): g/cm 3 at 20 C
5 Page 5 / Vapour pressure: 2.25 x 10 3 Pa at 20 C 9.10 Viscosity: 95, ,000 cps at 25 C 9.11 ph value (1% aqueous suspension): at 20 C 9.12 Solubility in / Miscibility with water: 77% (w/w) at 20 C 9.13 Partition coefficient n-octanol/water: Log p O/W: 3.30 at 20 C Method: calculated Test result for THYMOL (100%) 10. Stability and Reactivity 10.1 Stability: Stable, but avoid any application of heat to the product Reactivity: Non-reactive. 11. Toxicological information 11.1 Acute Oral Toxicity LD 50 : > 2000 mg/kg (rat) 11.2 Acute Dermal Toxicity LD 50 : > 2000 mg/kg (rat) 11.3 Irritation: 11.4 Sensitisation Skin: Eyes: Skin: irritant (rabbit) irritant (rabbit) none (guinea pig) 12. Ecological Information 12.1 Data on elimination (persistence and degradability): Information on the active ingredient THYMOL: The product is readily biodegradable to OECD criteria Fish toxicity: Values for the active ingredient THYMOL (100%): LC 0 (96 hours): 4.2 mg/l LC 50 (96 hours): 5.0 mg/l (approximately) (Brachydanio rerio)
6 Page 6 / Daphnia toxicity: Values for the active ingredient THYMOL (100%): LC 50 (48 hours): (water flea, Daphnia magna)) 12.4 Bacterial toxicity (growth inhibition): 3.2 mg/l Values for the active ingredient THYMOL (100%): EC 50 : 40mg/l Method: OECD 209 / ISO 8192 Activated sludge 12.5 Behaviour in sewage plant: Information on the active ingredient THYMOL: When low concentrations are discharged correctly into adapted biological sewage treatment plants, interference with the degradation activity of activated sludge is not likely Further information: Comment regarding the active ingredient THYMOL: Do not discharge the product unmonitored into the environment. 13. Disposal Considerations The product must be disposed of according to the applicable local regulations in force, if no recycling is possible. Packaging that cannot be cleaned should be disposed of as for the product. 14. Transportation Information RID/GGVE: ADR/GGVS: IMDG/GGVSea: not classified as dangerous goods for transportation not classified as dangerous goods for transportation not classified as dangerous goods for transportation 15. Regulatory Information Assessment by in accordance with EC directives and UK legislation on dangerous substances: R36/38 Irritating to eyes and skin. S2 Keep out of the reach of children. S13 Keep away from food, drink, and animal feedstuffs.
7 Page 7 / 7 S26 S28 S36/37/39 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of soap-suds. Wear suitable protective clothing, gloves and eye/face protection. 16. Other Information Product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with legal regulations. The information contained herein is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It should, therefore, not be construed as a warranty with regard to the product specific properties. Notes: The following changes have been made since the last version of 15 November 2001: Chapter 7, Section 7.2 ( Storage ): Shelf life in original containers in a temperate climate has been extended as follows: a) For the 50g aluminium container from 24 months to 36 months; b) For the 3kg polypropylene container (tub) from 18 months to 36 months. Apiguard is a registered trademark of, Basingstoke, Hampshire, UK.
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