Safety Data Sheet 1,4-Butanediol Revision date : 2014/12/16 Page: 1/8

Transcription

1 Revision date : 2014/12/16 Page: 1/8 1. Product and Company Identification Company BASF Canada Inc. 100 Milverton Drive Mississauga, ON L5R 4H1, CANADA 24 Hour Emergency Response Information CANUTEC (reverse charges): (613) BASF HOTLINE: (800) 454-COPE (2673) Molecular formula: Synonyms: HOCH(2)CH(2)CH(2)CH(2)OH 2. Hazards Identification Emergency overview NO PARTICULAR HAZARDS KNOWN. State of matter: liquid Colour: colourless Odour: almost odourless Potential health effects Acute toxicity: Of moderate toxicity after single ingestion. Virtually nontoxic after a single skin contact. Virtually nontoxic by inhalation. Irritation / corrosion: Not irritating to the skin. Not irritating to the eyes. Assessment other acute effects: Possible narcotic effects (drowsiness or dizziness). Sensitization: Skin sensitizing effects were not observed in animal studies. The substance did not cause skin sensitization in humans. Chronic toxicity: Carcinogenicity: The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. In long-term animal studies in which the substance was given by gavage in high doses, a carcinogenic effect was not observed.

2 Revision date : 2014/12/16 Page: 2/8 Repeated dose toxicity: The substance may cause damage to the liver after repeated ingestion of high doses, as shown in animal studies. Reproductive toxicity: The results of animal studies gave no indication of a fertility impairing effect. The results were determined in a Screening test (OECD 421/422). Teratogenicity: Animal studies gave no indication of a developmental toxic effect at doses that were not toxic to the parental animals. The product has not been fully tested. The statements have been derived in parts from products of a similar structure or composition. Genotoxicity: The substance was not mutagenic in bacteria. The substance was not mutagenic in mammalian cell culture. Medical conditions aggravated by overexposure: Data available do not indicate that there are medical conditions that are generally recognized as being aggravated by exposure to this substance/product. See MSDS section 11 - Toxicological information. Signs and symptoms of overexposure: Overexposure may cause:, unconsciousness, lethargy Potential environmental effects Aquatic toxicity: There is a high probability that the product is not acutely harmful to aquatic organisms. The inhibition of the degradation activity of activated sludge is not anticipated when introduced to biological treatment plants in appropriate low concentrations. Terrestrial toxicity: Study scientifically not justified. 3. Composition / Information on Ingredients Not WHMIS controlled. 4. First-Aid Measures General advice: Remove contaminated clothing. If inhaled: Keep patient calm, remove to fresh air. Assist in breathing if necessary. Consult a physician. If on skin: Wash affected areas thoroughly with soap and water. Remove contaminated clothing. If irritation develops, seek medical attention. If in eyes: In case of contact with the eyes, rinse immediately for at least 15 minutes with plenty of water. If irritation develops, seek medical attention. If swallowed: If person is conscious and can swallow, give two glasses of water. Induce vomiting. Immediate medical attention required. Note to physician Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.

3 Revision date : 2014/12/16 Page: 3/8 5. Fire-Fighting Measures Flash point: 115 C (DIN 51758, closed cup) Autoignition: 385 C (DIN 51794) Lower explosion limit: For liquids not relevant for classification and labelling. The lower explosion point may be 5-15 C below the flash point. Upper explosion limit: For liquids not relevant for classification and labelling. Flammability: not flammable Self-ignition temperature: not self-igniting Suitable extinguishing media: water spray, dry powder, foam, carbon dioxide Hazards during fire-fighting: carbon oxides, nitrogen oxides The substances/groups of substances mentioned can be released in case of fire. Under certain conditions in case of fire other hazardous combustion products may be generated. Protective equipment for fire-fighting: Wear a self-contained breathing apparatus. Further information: Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems. Impact Sensitivity: Remarks: Based on the chemical structure there is no shock-sensitivity. 6. Accidental release measures Personal precautions: Handle in accordance with good industrial hygiene and safety practice. Environmental precautions: Discharge into the environment must be avoided. Cleanup: For large amounts: Pump off product. For residues: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr). Dispose of absorbed material in accordance with regulations. 7. Handling and Storage Handling General advice: Ensure thorough ventilation of stores and work areas. Handle in accordance with good industrial hygiene and safety practice. Remove contaminated clothing and protective equipment before entering eating areas. Hands and/or face should be washed before breaks and at the end of the shift. When using do not eat, drink or smoke. Protection against fire and explosion: Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy. Storage General advice:

4 Revision date : 2014/12/16 Page: 4/8 Containers should be stored tightly sealed in a dry place. Storage stability: Storage temperature: 20 C Storage duration: 24 Months From the data on storage duration in this safety data sheet no agreed statement regarding the warrantee of application properties can be deduced. 8. Exposure Controls and Personal Protection Personal protective equipment Respiratory protection: Breathing protection if gases/vapours are formed. Respiratory protection required in case of exceeding the occupational exposure limit: Self-contained breathing apparatus. Hand protection: Chemical resistant protective gloves, Suitable materials, rubber, plastic Eye protection: Tightly fitting safety goggles (chemical goggles). Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN in case of splashes or EN ISO in case of dust). General safety and hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment. When using, do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift. Gloves must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks). Take off immediately all contaminated clothing. Wash contaminated clothing before reuse. Store work clothing separately. 9. Physical and Chemical Properties Form: oily, liquid Odour: almost odourless Odour threshold: No data available. Colour: colourless ph value: ( 500 g/l, 20 C) (DIN 19268) Melting point: 20.4 C ( 1,013 hpa) Literature data. boiling temperature: 230 C ( 1,013 hpa) Vapour pressure: hpa ( 25 C) (measured) negligible Density: 1.02 g/cm3 ( 20 C, 1,013 hpa) liquid Relative density: 1.02 ( 20 C, 1,013 hpa) (in liquid state), Literature data. Vapour density: not relevant Partitioning coefficient n- octanol/water (log Pow): ( 25 C) (OECD Guideline 107) The data refers to the undissociated form of the substance. Viscosity, dynamic: 84.9 mpa.s ( 20 C) Particle size: The substance / product is marketed or used in a non solid or granular form. Solubility in water: > 1,000 g/l ( 25 C) miscible Miscibility with water: Solubility (qualitative): Molar mass: miscible in all proportions soluble solvent(s): organic solvents, g/mol

5 Revision date : 2014/12/16 Page: 5/8 10. Stability and Reactivity Conditions to avoid: Avoid all sources of ignition: heat, sparks, open flame. Substances to avoid: strong oxidizing agents Hazardous reactions: No hazardous reactions when stored and handled according to instructions. Decomposition products: Hazardous decomposition products: carbon monoxide, carbon dioxide Possible decomposition products: tetrahydrofuran Thermal decomposition: 115 C (DSC (DIN 51007)) It is not a self-decompositionable substance. Corrosion to metals: Not corrosive to: iron aluminum Stainless steel Oxidizing properties: Based on its structural properties the product is not classified as oxidizing. 11. Toxicological information Acute toxicity Information on: Information on: Oral: Type of value: LD50 Species: rat (male/female) Value: 1,500 mg/kg (BASF-Test) Inhalation: Type of value: LC50 Species: rat (male/female) Value: > 5.1 mg/l (OECD Guideline 403) Exposure time: 4 h An aerosol was tested. No mortality was observed. The value meets the highest applied test concentration. Dermal: Type of value: LD50 Species: rat (male/female) Value: > 2,000 mg/kg (BASF-Test) The value meets the highest applied test concentration. No mortality was observed. Irritation / corrosion Information on: Skin: Species: rabbit Result: non-irritant

6 Revision date : 2014/12/16 Page: 6/8 Method: Draize test Eye: Species: rabbit Result: non-irritant Method: Draize test Sensitization: Guinea pig maximization test Species: guinea pig Result: Non-sensitizing. Aspiration Hazard: not applicable 12. Ecological Information Fish Acute: OECD 203; ISO 7346; 84/449/EEC, C.1 static Pimephales promelas/lc50 (96 h): > 30,000 mg/l The details of the toxic effect relate to the nominal concentration. Chronic: Study scientifically not justified. Aquatic invertebrates Acute: OECD Guideline 202, part 1 static Daphnia magna/ec50 (48 h): 813 mg/l The statement of the toxic effect relates to the analytically determined concentration. Chronic: OECD Guideline 202, part 2 semistatic Daphnia magna (NOEC) 21 d > 85 mg/l Aquatic plants Toxicity to aquatic plants: DIN Part 9 green algae/ec50 (72 h): > 500 mg/l Nominal concentration. Microorganisms Toxicity to microorganisms: other Protozoa/EC50 (40 h): > 15,000 mg/l OECD Guideline 209 activated sludge, industrial/ec20 (30 min): > 788 mg/l Nominal concentration. Degradability / Persistence Biological / Abiological Degradation Test method: OECD 301C; ISO 9408; 92/69/EEC, C.4-F (aerobic), activated sludge Method of analysis: BOD of the ThOD Degree of elimination: approx % (14 d) Test method: OECD Guideline 302 B (aerobic), activated sludge, industrial Method of analysis: DOC reduction Degree of elimination: % (7 d) Evaluation: Readily biodegradable (according to OECD criteria).

7 Revision date : 2014/12/16 Page: 7/8 Hydrolysis Test method: Half-life: OECD Guideline 111 (abiotic) ph7 (25 C) Bioaccumulation Because of the n-octanol/water distribution coefficient (log Pow) accumulation in organisms is not to be expected. 13. Disposal considerations Waste disposal of substance: Incinerate in suitable incineration plant, observing local authority regulations. A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage. The waste code in accordance with the European waste catalog (EWC) must be specified in cooperation with disposal agency/manufacturer/authorities. Container disposal: Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned. 14. Transport Information Land transport TDG Not classified as a dangerous good under transport regulations Sea transport IMDG Not classified as a dangerous good under transport regulations Air transport IATA/ICAO Not classified as a dangerous good under transport regulations 15. Regulatory Information Federal Regulations Registration status: Chemical DSL, CA released / listed Not WHMIS controlled. THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF THE CPR AND THE MSDS CONTAINS ALL THE INFORMATION REQUIRED BY THE CPR.

8 Revision date : 2014/12/16 Page: 8/8 16. Other Information We support worldwide Responsible Care initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products. SDS Prepared by: BASF NA Product Regulations BASF HOTLINE (800) 454 COPE (2673) SDS Prepared on: 2014/12/16 END OF DATA SHEET