Safety Data Sheet according to (EC) No 1907/2006

Transcription

1 Safety Data Sheet according to (EC) No 1907/2006 P3-Saxin Page 1 of 9 sds no. : Revision: printing date: SECTION 1: Identification of the substance/mixture and of the company/undertaking Product identifier: P3-Saxin Relevant identified uses of the substance or mixture and uses advised against: Intended use: Alkaline Cleaner for Industrial Application Details of the supplier of the safety data sheet: Henkel Limited 2 Bishop Square Business Park AL109EY Herfordshire Hatfield Great Britain Phone: Fax-no.: ua-productsafety.uk@uk.henkel.com Emergency telephone number: 24 Hours Emergency Tel: +44 (0) Classification of the substance or mixture: Classification (CLP): No data available. Classification (DPD): C - Corrosive R34 Causes burns. Xi - Irritant R37 Irritating to respiratory system. Label elements (CLP): No data available. SECTION 2: Hazards identification

2 P3-Saxin Page 2 of 9 Label elements (DPD): C - Corrosive Risk phrases: R34 Causes burns. R37 Irritating to respiratory system. Safety phrases: S22 Do not breathe dust. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Contains: Other hazards: None if used properly. SECTION 3: Composition/information on ingredients Declaration of the ingredients according to CLP (EC) No 1272/2008: Fatty alcohol, C12-18, ethoxylate BU ether EC Number REACH-Reg No. content Classification > 25 % Skin corrosion 1B H314 Specific target organ toxicity - single exposure 3 H335 Corrosive to metals 1 H > 25 % Serious eye irritation H % Acute toxicity 4; Oral H302 Serious eye irritation 2 H319 0,1-1 % Skin irritation 2 H315 Acute hazards to the aquatic environment 1 H400 Only dangerous ingredients for which a CLP classification is already available are displayed in this table. For full text of the H - statements and other abbreviations see section 16 "Other information". Substances without classification may have community workplace exposure limits available.

3 P3-Saxin Page 3 of 9 Declaration of ingredients according to DPD (EC) No 1999/45: Fatty alcohol, C12-18, ethoxylate BU ether EC Number content Classification REACH-Reg No > 25 % C - Corrosive; R34, R > 25 % Xi - Irritant; R % Xn - Harmful; R22 Xi - Irritant; R36 0,1-1 % Xi - Irritant; R38 N - Dangerous for the environment; R50 For full text of the R-Phrases indicated by codes see section 16 'Other Information'. Substances without classification may have community workplace exposure limits available. Declaration of ingredients according to Detergent Regulation 648/2004/EC 5-15 % phosphates < 5 % non-ionic surfactants Description of first aid measures: SECTION 4: First aid measures Inhalation: Remove person from dust-contaminated zone, seek medical advice if necessary. Skin contact: Immediately rinse with copious amounts of running water (for 10 minutes). Remove contaminated clothes. Put on a bandage with sterile gauze, seek medical attention in hospital. Eye contact: Immediately flush eyes with soft jet of water or eye rinse solution for at least 15 minutes. Hold eyelid wide-open. Seek a doctor/hospital, eye flushing should continue during transportation to a doctor. Ingestion: Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor. Most important symptoms and effects, both acute and delayed: Causes burns. RESPIRATORY: Irritation, coughing, shortness of breath, chest tightness. Indication of any immediate medical attention and special treatment needed: See section: Description of first aid measures Extinguishing media: Suitable extinguishing media: Carbon dioxide. extinguishing powder SECTION 5: Firefighting measures Extinguishing media which must not be used for safety reasons: Water Special hazards arising from the substance or mixture: Formation of toxic gases is possible during heating or in fires. Advice for firefighters: Wear self-contained breathing apparatus.

4 P3-Saxin Page 4 of 9 Additional information: The product itself does not burn. Any fire extinguishing action should be appropriate to the surroundings. SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures: Avoid dust formation. Avoid contact with skin and eyes. Environmental precautions: Do not empty into drains / surface water / ground water. Methods and material for containment and cleaning up: Remove mechanically. Wash away residue with plenty of water. Dispose of contaminated material as waste according to Chapter 13. Reference to other sections: See advice in chapter 8 SECTION 7: Handling and storage Precautions for safe handling: Avoid dust formation. When diluting, always stir slowly the product into standing water. See advice in chapter 8 Hygiene measures: Keep away from food, beverages and animal feed. Do not eat, drink or smoke while working. Wash hands before work breaks and after finishing work. Conditions for safe storage, including any incompatibilities: Store only in the original container. Keep container tightly sealed. Store in a cool, dry place. Do not store together with strong acids. Specific end use(s): Alkaline Cleaner for Industrial Application SECTION 8: Exposure controls/personal protection Control parameters: Valid for Great Britain Ingredient ppm mg/m 3 Type Category Remarks DUST, INHALABLE DUST 10 Time Weighted Average EH40 WEL (TWA): DUST, RESPIRABLE DUST 4 Time Weighted Average (TWA): EH40 WEL Exposure controls: Engineering controls: Thorough dedusting. Respiratory protection: In case of dust formation, we recommend wearing of appropriate respiratory protection equipment with particle filter P. This recommendation should be matched to local conditions.

5 P3-Saxin Page 5 of 9 Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): Polychloroprene (CR; >= 1 mm thickness) or natural rubber (NR; >=1 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): Polychloroprene (CR; >= 1 mm thickness) or natural rubber (NR; >=1 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Goggles which can be tightly sealed. The workplace should be equipped with an emergency shower and eye-rinsing facility. Skin protection: Protective clothing that covers arms and legs. SECTION 9: Physical and chemical properties Information on basic physical and chemical properties: Appearance solid material powder Milky white Odor no valuation ph (20 C (68 F); Conc.: 1,0 % product; Solvent: Demineralised water) Initial boiling point Flash point Decomposition temperature Vapour pressure Density Bulk density Viscosity Viscosity (kinematic) Explosive properties Solubility (qualitative) (20 C (68 F); Solvent: Water) Solidification temperature Melting point Flammability Auto-ignition temperature Explosive limits Partition coefficient: n-octanol/water Evaporation rate Vapor density Oxidising properties 11,5-12,5 not applicable not applicable fully soluble Other information: SECTION 10: Stability and reactivity Reactivity: None if used for intended purpose. Reaction with acids: production of heat and carbon dioxide. Reacts with water: generation of heat. Chemical stability: Stable under recommended storage conditions.

6 P3-Saxin Page 6 of 9 Possibility of hazardous reactions: See section reactivity Conditions to avoid: No decomposition if used according to specifications. Incompatible materials: None if used properly. Hazardous decomposition products: None if used for intended purpose. In case of fire toxic gases can be released. SECTION 11: Toxicological information General toxicological information: The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Inhalative toxicity: Irritating to respiratory system Dermal toxicity: The product causes corrosion on skin and mucous membranes. Eye irritation: Corrosive Acute toxicity: sodium metasilicate*5 H2O Value Value Route of Exposure Species type application time LD mg/kg oral mouse LD50 LC50 LD50 LD50 LD mg/kg > mg/kg mg/kg mg/kg oral inhalation dermal oral oral 2 h rat rat rabbit rat rat Method OECD Guideline 401 (Acute Oral Toxicity) OECD Guideline 401 (Acute Oral Toxicity) Skin corrosion/irritation: Result Exposure time Species Method not irritating 4 h rabbit OECD Guideline 404 (Acute Dermal Irritation / Corrosion) not irritating 2 h rabbit Germ cell mutagenicity: Result Type of study / Route of administration negative bacterial reverse mutation assay (e.g Ames test) Metabolic activation / Exposure time with Species Method

7 P3-Saxin Page 7 of 9 SECTION 12: Ecological information General ecological information: The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Contains phosphate, may fertilize watercourses. Locally harmful for aquatic and landliving organisms because of high ph and corrosive properties. Ecotoxicity: Do not empty into drains / surface water / ground water. Persistence and degradability: Degradation of surfactants The biodegradability of the surfactants contained in the product is in accordance with the requirements of the EU Detergent Regulation (EC/648/2004). The surfactants contained in the products are primary biodegradable to at least 90% on average. Other adverse effects: If acidic or alkaline products are discharged into wastewater installations care must be taken that the discharged wastewater has a ph in the range ph 6-10, as ph variations could cause disorders in wastewater channels and biological sewage treatment plants. The local discharge regulations take precedence. Toxicity: Value type Value Acute Toxicity Study Exposure time Species NOEC > 86,7 mg/l Fish 30 d Pimephales promelas LC mg/l Fish 96 h Brachydanio rerio (new name: Danio rerio) EC mg/l Daphnia 48 h Daphnia magna Method EC mg/l Algae 72 h Scenedesmus subspicatus (new name: Desmodesmus subspicatus) LC mg/l Fish 96 h Lepomis macrochirus OECD Guideline 203 (Fish, Acute Toxicity Test) EC mg/l Daphnia 48 h Ceriodaphnia sp. OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC mg/l Algae 5 d Nitzschia sp. OECD Guideline 201 (Alga, Growth Inhibition Test) LC50 6,4 mg/l Fish 48 h Leuciscus idus EC50 27 mg/l Daphnia 24 h Daphnia magna Persistence and degradability: Result Route of application Degradability Method readily biodegradable no data > 60 % OECD Guideline 301 B (Ready Biodegradability: CO2 Evolution Test) Bioaccumulative potential / Mobility in soil: LogKow Bioconcentration factor (BCF) Exposure time Species Temperature Method 1,24 OECD Guideline 107 (Partition Coefficient (noctanol / water), Shake Flask Method)

8 P3-Saxin Page 8 of 9 SECTION 13: Disposal considerations Waste treatment methods: Product disposal: Dispose of in accordance with local and national regulations. In consultation with the responsible local authority, must be subjected to special treatment: Neutralisation Waste code The valid EWC waste code numbers are source-related. The manufacturer is therefore unable to specify EWC waste codes for the articles or products used in the various sectors. The EWC codes listed are intended as a recommendation for users. We will be happy to advise you. EWC/EAK Road transport ADR: SECTION 14: Transport information Classification code: C6 Hazard ident. number: 80 Technical name: DISODIUM TRIOXOSILICATE (mixture) Tunnelcode: (E) Railroad transport RID: Classification code: C6 Hazard ident. number: 80 Technical name: DISODIUM TRIOXOSILICATE (mixture) Tunnelcode: Inland water transport ADN: Classification code: C6 Hazard ident. number: Technical name: DISODIUM TRIOXOSILICATE (mixture) Marine transport IMDG: EmS: F-A,S-B Seawater pollutant: - Proper shipping name: DISODIUM TRIOXOSILICATE (mixture)

9 P3-Saxin Page 9 of 9 Air transport IATA: Packaging instructions (passenger) 860 Packaging instructions (cargo) 864 Proper shipping name: Disodium trioxosilicate (mixture) SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture: VOC content 0,00 % (1999/13/EC) National regulations/information (Great Britain): Remarks Control of Substances Hazardous to Health Regulations (COSHH), and related guidance, e.g COSHH Essentials. EH40 Occupational Exposure Limits Chemicals (Hazard Information & Packaging for Supply) Regulations. The Personnel Protective Equipment at Work Regulations. The Carriage of Dangerous Goods by Road Regulations. The Health & Safety at Work Act (Note: Use latest editions/amendments of above referenced documents.) SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: R22 Harmful if swallowed. R34 Causes burns. R36 Irritating to eyes. R37 Irritating to respiratory system. R38 Irritating to skin. R50 Very toxic to aquatic organisms. H290 May be corrosive to metals. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H400 Very toxic to aquatic life. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties.