Electrokinetics Across Disciplines and Continents

Transcription

1 Electrokinetics Across Disciplines and Continents

2

3 Alexandra B. Ribeiro Eduardo P. Mateus Nazaré Couto Editors Electrokinetics Across Disciplines and Continents New Strategies for Sustainable Development

4 Editors Alexandra B. Ribeiro CENSE, Departamento de Ciências e Engenharia do Ambiente Faculdade de Ciências e Tecnologia Universidade Nova de Lisboa Caparica, Eduardo P. Mateus CENSE, Departamento de Ciências e Engenharia do Ambiente Faculdade de Ciências e Tecnologia Universidade Nova de Lisboa Caparica, Nazaré Couto CENSE, Departamento de Ciências e Engenharia do Ambiente Faculdade de Ciências e Tecnologia Universidade Nova de Lisboa Caparica, ISBN ISBN (ebook) DOI / Library of Congress Control Number: Springer Cham Heidelberg New York Dordrecht London Springer International Publishing Switzerland 2016 This work is subject to copyright. All rights are reserved by the Publisher, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission or information storage and retrieval, electronic adaptation, computer software, or by similar or dissimilar methodology now known or hereafter developed. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. The publisher, the authors and the editors are safe to assume that the advice and information in this book are believed to be true and accurate at the date of publication. Neither the publisher nor the authors or the editors give a warranty, express or implied, with respect to the material contained herein or for any errors or omissions that may have been made. Printed on acid-free paper Springer International Publishing AG Switzerland is part of Springer Science+Business Media (

5 Preface The book Electrokinetics Across Disciplines and Continents New Strategies for Sustainable Development aims to discuss and deepen the knowledge about electrokinetic (EK) process. The EK process could be used as an integrated approach for new strategies aiming at sustainable development and for supporting waste strategies worldwide. The conciliation of the EK process in the recovery of secondary resources, remediation, and conservation is a multidisciplinary, novel approach that opens new technical possibilities for waste minimization, through the upgradation of particulate waste products and recovery of secondary resources for industrial, agricultural, or social use. The EK process can also be coupled with phytoremediation and integrated with nanotechnology, enlarging the scope of its application. This was the basis and the motivation for this work. The insights provided in this book are mainly based on a compilation of the works developed in the scope of ELECTROACROSS (electrokinetics across disciplines and continents: an integrated approach to finding new strategies to sustainable development), an FP7 People International Research Staff Exchange Scheme (IRSES) project. The book is divided into five main parts: (I) Introduction and Overview of the Process; (II) Remediation of Contaminants and Recovery of Secondary Resources with Socio-Economical Value; (III) Conservation of Cultural Heritage and Use in Construction Material; (IV) Modeling of the Electrokinetic Process; and (V) Coupling Electrokinetic Process with Other Technologies to Enhance Performance and Sustainability (analytical, nano-, and phytotechnologies). The book starts with an overview of EK soil remediation followed by influence of soil structure on EK dewatering process, EK enabled de-swelling of clay and soil stabilization, sustainable power generation from salinity gradient energy, and adsorption processes. The issue of phosphorus recovery in water and wastewater treatment plants by EK is discussed, together with remediation of copper mine tailings or as an alternative for soil and compost characterization. Life cycle assessment of EK remediation, electro-desalination of buildings damaged by salt weathering and incorporation of fly ashes as substitute for cement in mortar are also v

6 vi Preface presented. A coupled reactive-transport model for EK remediation is discussed as well as the modeling of the transport of EK and zero valent iron nanoparticles and EK remediation of a mercury-polluted soil. The coupling of electrokinetics with phytotechnologies for arsenic removal or with nanoremediation for organic removal is also discussed, together with a broader range of topics regarding phytoremediation of pharmaceuticals and personal care products or inorganic compounds. The last part is devoted to analytical methodologies that allow detection and monitoring of contaminants in specific matrices. We do hope you will find this book of interest, and we would like to thank all those who contributed to it. Caparica, 30 March 2015 Alexandra B. Ribeiro Eduardo P. Mateus Nazaré Couto

7 Contents Part I Introduction and Overview of the Process 1 Electrokinetic Soil Remediation: An Overview... 3 Henrik K. Hansen, Lisbeth M. Ottosen, and Alexandra B. Ribeiro 2 Soil Structure Influence on Electrokinetic Dewatering Process Vikas Gingine and Rafaela Cardoso 3 Electrokinetically Enabled De-swelling of Clay Reena A. Shrestha, Angela P. Zhang, Eduardo P. Mateus, Alexandra B. Ribeiro, and Sibel Pamukcu 4 Sustainable Power Generation from Salinity Gradient Energy by Reverse Electrodialysis Sylwin Pawlowski, João Crespo, and Svetlozar Velizarov 5 The Kinetic Parameters Evaluation for the Adsorption Processes at Liquid Solid Interface Svetlana Lyubchik, Elena Lygina, Andriy Lyubchyk, Sergiy Lyubchik, José M. Loureiro, Isabel M. Fonseca, Alexandra B. Ribeiro, Margarida M. Pinto, and Agnes M. Sá Figueiredo Part II Remediation of Contaminants and Recovery of Secondary Resources with Socio-Economical Value 6 Electrochemical Process for Phosphorus Recovery from Water Treatment Plants Nazaré Couto, Margarida Ribau Teixeira, Paula R. Guedes, Eduardo P. Mateus, and Alexandra B. Ribeiro vii

8 viii Contents 7 Electrochemical Process for Phosphorus Recovery from Wastewater Treatment Plants Paula R. Guedes, Nazaré Couto, Eduardo P. Mateus, and Alexandra B. Ribeiro 8 Electrokinetic Remediation of Copper Mine Tailings: Evaluating Different Alternatives for the Electric Field Henrik K. Hansen, Adrián Rojo, Claudia Gutiérrez, Pernille E. Jensen, and Lisbeth M. Ottosen 9 Electrokinetics as an Alternative for Soil and Compost Characterization Alejandro Serna González, Lucas Bland on Naranjo, Jorge Andrés Hoyos, and Mario Víctor Vázquez 10 Life Cycle Assessment of Soil and Groundwater Remediation: Groundwater Impacts of Electrokinetic Remediation Luís M. Nunes, Helena I. Gomes, Margarida Ribau Teixeira, Celia Dias-Ferreira, and Alexandra B. Ribeiro Part III Conservation of Cultural Heritage and Use in Construction Material 11 Electro-desalination of Buildings Suffering from Salt Weathering Lisbeth M. Ottosen and Henrik K. Hansen 12 Incorporation of Different Fly Ashes from MSWI as Substitute for Cement in Mortar: An Overview of the Suitability of Electrodialytic Pre-treatment Cátia C. Magro, Paula R. Guedes, Gunvor M. Kirkelund, Pernille E. Jensen, Lisbeth M. Ottosen, and Alexandra B. Ribeiro Part IV Modeling of the Electrokinetic Process 13 A Coupled Reactive-Transport Model for Electrokinetic Remediation Juan Manuel Paz-García, María Villén-Guzmán, Ana García-Rubio, Stephen Hall, Matti Ristinmaa, and César G omez-lahoz 14 Electrokinetics and Zero Valent Iron Nanoparticles: Experimental and Modeling of the Transport in Different Porous Media Helena I. Gomes, José M. Rodríguez-Maroto, Alexandra B. Ribeiro, Sibel Pamukcu, and Celia Dias-Ferreira

9 Contents ix 15 Feasibility Study of the Electrokinetic Remediation of a Mercury-Polluted Soil Ana García-Rubio, María Villén-Guzmán, Francisco García-Herruzo, José M. Rodríguez-Maroto, Carlos Vereda-Alonso, César G omez-lahoz, and Juan Manuel Paz-García Part V Coupling Electrokinetic Process with Other Technologies to Enhance Performance and Sustainability 16 Phytoremediation Coupled to Electrochemical Process for Arsenic Removal from Soil Paula R. Guedes, Nazaré Couto, Alexandra B. Ribeiro, and Dong-Mei Zhou 17 Nanoremediation Coupled to Electrokinetics for PCB Removal from Soil Helena I. Gomes, Guangping Fan, Lisbeth M. Ottosen, Celia Dias-Ferreira, and Alexandra B. Ribeiro 18 Removal of Pharmaceutical and Personal Care Products in Aquatic Plant-Based Systems Ana R. Ferreira, Nazaré Couto, Paula R. Guedes, Eduardo P. Mateus, and Alexandra B. Ribeiro 19 Phytoremediation of Inorganic Compounds Bruno Barbosa, Jorge Costa, Sara Boléo, Maria Paula Duarte, and Ana Luisa Fernando 20 Sensing of Component Traces in Complex Systems Maria Raposo, Paulo A. Ribeiro, Nezha El Bari, and Benachir Bouchikhi 21 Analysis of Endocrine Disrupting Chemicals in Food Samples Miriany A. Moreira, Leiliane C. André, Marco D.R. Gomes da Silva, and Zenilda L. Cardeal 22 Multidimensional Chromatographic Techniques for Monitoring and Characterization of Environmental Samples Eduardo P. Mateus, Marco D.R. Gomes da Silva, Alexandra B. Ribeiro, and Philip Marriott Index

10

11 Contributors Leiliane C. André Departamento de Análises Clínicas e Toxicol ogicas, Faculdade de Farmácia (FaFar), Universidade Federal de Minas Gerais, Belo Horizonte, MG, Brazil Bruno Barbosa MEtRiCS, Departamento de Ciências e Tecnologia da Biomassa, Sara Boléo MEtRiCS, Departamento de Ciências e Tecnologia da Biomassa, Benachir Bouchikhi Sensor Electronic & Instrumentation Group, Department of Physics, Faculty of Sciences, Moulay Ismaïl University, Meknes, Morocco Lucas Bland on Naranjo Interdisciplinary Group of Molecular Studies (GIEM), Chemistry Institute, Faculty of Exact and Natural Sciences, University of Antioquia, Medellín, Colombia Zenilda L. Cardeal Departamento de Química, Instituto de Ciências Exatas (ICEx) Universidade Federal de Minas Gerais, Belo Horizonte, MG, Brazil Rafaela Cardoso ICIST, Instituto Superior Técnico, University of Lisbon, Lisbon, Jorge Costa MEtRiCS, Departamento de Ciências e Tecnologia da Biomassa, Nazaré Couto CENSE, Departamento de Ciências e Engenharia do Ambiente, Key Laboratory of Soil Environment and Pollution Remediation, Institute of Soil Science, Chinese Academy of Sciences, Nanjing, China xi

12 xii Contributors João Crespo LAQV-REQUIMTE, Departamento de Química, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, Caparica, Nezha El Bari Biotechnology Agroalimentary and Biomedical Analysis Group, Department of Biology, Faculty of Sciences, Moulay Ismaïl University, Meknes, Morocco Celia Dias-Ferreira CERNAS Research Center for Natural Resources, Environment and Society, Escola Superior Agraria de Coimbra, Instituto Politecnico de Coimbra, Coimbra, Maria Paula Duarte MEtRiCS, Departamento de Ciências e Tecnologia da Biomassa, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, Caparica, Guangping Fan Key Laboratory of Soil Environment and Pollution Remediation, Institute of Soil Science, Chinese Academy of Sciences (ISSCAS), Nanjing, China Ana Luisa Fernando MEtRiCS, Departamento de Ciências e Tecnologia da Biomassa, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, Caparica, Ana R. Ferreira CENSE, Departamento de Ciências e Engenharia do Ambiente, Agnes M. Sá Figueiredo Instituto de Microbiologia Paulo de G oes, Universidade Federal do Rio de Janeiro, Rio de Janeiro, Brazil Isabel M. Fonseca REQUIMTE, Departamento de Química, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, Caparica, Francisco García-Herruzo Department of Chemical Engineering, University of Málaga, Málaga, Spain Ana García-Rubio Department of Chemical Engineering, University of Málaga, Málaga, Spain Vikas Gingine ICIST, Instituto Superior Técnico, University of Lisbon, Lisbon, Helena I. Gomes CENSE, Departamento de Ciências e Engenharia do Ambiente, CERNAS Research Center for Natural Resources, Environment and Society, Escola Superior Agraria de Coimbra, Instituto Politecnico de Coimbra, Coimbra, Department of Civil Engineering, Technical University of Denmark, Lyngby, Denmark

13 Contributors xiii Marco D.R. Gomes da Silva LAQV, REQUIMTE, Departamento de Química, César G omez-lahoz Department of Chemical Engineering, University of Málaga, Málaga, Spain Paula R. Guedes CENSE, Departamento de Ciências e Engenharia do Ambiente, Key Laboratory of Soil Environment and Pollution Remediation, Institute of Soil Science, Chinese Academy of Sciences, Nanjing, China Claudia Gutiérrez Departamento de Ingeniería Química y Ambiental, Universidad Técnica Federico Santa Maria, Valparaíso, Chile Stephen Hall Division of Solid Mechanics, University of Lund, Lund, Sweden Henrik K. Hansen Departamento de Ingeniería Química y Ambiental, Universidad Técnica Federico Santa María, Valparaíso, Chile Jorge Andrés Hoyos Interdisciplinary Group of Molecular Studies (GIEM), Chemistry Institute, Faculty of Exact and Natural Sciences, University of Antioquia, Medellín, Colombia Pernille E. Jensen Department of Civil Engineering, Technical University of Denmark, Lyngby, Denmark Gunvor M. Kirkelund Department of Civil Engineering, Technical University of Denmark, Lyngby, Denmark José M. Loureiro Faculdade de Engenharia, Universidade do Porto, Porto, Elena Lygina REQUIMTE, Departamento de Química, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, Caparica, Sergiy Lyubchik CQE, Departamento de Engenharia Química, Instituto Superior Técnico de Lisboa, Lisbon, Svetlana Lyubchik REQUIMTE, Departamento de Química, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, Caparica, Andriy Lyubchyk CENIMAT, Departamento de Engenharia de Materiais e Cer^amica, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, Caparica, Cátia C. Magro CENSE, Departamento de Ciências e Engenharia do Ambiente, Department of Civil Engineering, Technical University of Denmark, Lyngby, Denmark

14 xiv Contributors Philip Marriott Australian Centre for Research on Separation Science, School of Chemistry, Monash University, Clayton, VIC, Australia Eduardo P. Mateus CENSE, Departamento de Ciências e Engenharia do Ambiente, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, Caparica, Miriany A. Moreira Departamento de Química, Instituto de Ciências Exatas (ICEx) Universidade Federal de Minas Gerais, Belo Horizonte, MG, Brazil Luís M. Nunes CERIS Civil Engineering Research and Innovation for Sustainability, Faculdade de Ciências e Tecnologia, Universidade do Algarve, Faro, Lisbeth M. Ottosen Department of Civil Engineering, Technical University of Denmark, Lyngby, Denmark Sibel Pamukcu Department of Civil and Environmental Engineering, Lehigh University, Bethlehem, PA, USA Sylwin Pawlowski LAQV-REQUIMTE, Departamento de Química, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, Caparica, Juan Manuel Paz-García Division of Solid Mechanics, University of Lund, Lund, Sweden Margarida M. Pinto ISQ-R&D Department, Instituto de Soldadura e Qualidade, Porto Salvo, Maria Raposo CEFITEC, Departamento de Física, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, Caparica, José M. Rodríguez-Maroto Department of Chemical Engineering, University of Málaga, Málaga, Spain Alexandra B. Ribeiro CENSE, Departamento de Ciências e Engenharia do Ambiente, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, Caparica, Paulo A. Ribeiro CEFITEC, Departamento de Física, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, Caparica, Matti Ristinmaa Division of Solid Mechanics, University of Lund, Lund, Sweden Adrián Rojo Departamento de Ingeniería Química y Ambiental, Universidad Técnica Federico Santa Maria, Valparaíso, Chile Alejandro Serna González Interdisciplinary Group of Molecular Studies (GIEM), Chemistry Institute, Faculty of Exact and Natural Sciences, University of Antioquia, Medellín, Colombia

15 Contributors xv Reena A. Shrestha Department of Civil and Environmental Engineering, Lehigh University, Bethlehem, PA, USA Department of Petroleum Engineering, The Petroleum Institute, Abhu Dhabi, UAE Margarida Ribau Teixeira CENSE, Faculdade de Ciências e Tecnologia, Universidade do Algarve, Faro, Mario Víctor Vázquez Interdisciplinary Group of Molecular Studies (GIEM), Chemistry Institute, Faculty of Exact and Natural Sciences, University of Antioquia, Medellín, Colombia Svetlozar Velizarov LAQV-REQUIMTE, Departamento de Química, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, Caparica, Carlos Vereda-Alonso Department of Chemical Engineering, University of Málaga, Málaga, Spain María Villén-Guzmán Department of Chemical Engineering, University of Málaga, Málaga, Spain Angela P. Zhang Department of Civil and Environmental Engineering, Lehigh University, Bethlehem, PA, USA Dong-Mei Zhou Key Laboratory of Soil Environment and Pollution Remediation, Institute of Soil Science, Chinese Academy of Sciences, Nanjing, China