Spanish Situation on FBC



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Spanish Situation on FBC Juan Otero Department of Energy 58 Th IEA FBC IA Xi an May 17, 2009

Industrial Facilities Sogama Escatrón La Pereda CLOSED Tirmadrid Vetejar

La Pereda Location: Mieres (Asturias) Fuel: Hard coal 65% ash Boiler: Foster Wheeler Type: CFB Capacity: 50 MW

Location: Madrid Tirmadrid Starting up:1996 Fuel:MSW Type: BFB Capacity: 30 MW

Sogama Location: Cerceda (La Coruña) Starting up: 2002 Fuel:MSW Type: 2 CFB Capacity:50 MW Power Plant

Vetejar Location: Palenciana (Córdoba) Starting up: 1995 Fuel: orujo (65% moisture) Boiler: Foster Wheeler Type: BFB Capacity: 12.5 MW

Centres of Research and Technological Development CIEMAT Madrid/Soria ETSI University of Seville-AICIA-INERCO INCAR-CSIC CIRCE University of Zaragoza

CIEMAT Madrid-Soria (I) R&D Activities Coal and Waste Co-Combustion Processes. Biomass Gasification Processes. Gas Treatment Processes. Clean-up & Component Separation. Kinetics studies and Theoretical Development DNS for Combustion processes.

CIEMAT Madrid-Soria (II) 3.5 MW BFB Demonstration Plant Steam at 40 bar

CIEMAT Madrid-Soria (III) 1 MW BFB Pilot Plant 100kW BFB Pilot Plant

CIEMAT Madrid-Soria (IV) 500 kw CFB PILOT PLANT GASIFIER

CIEMAT Madrid-Soria (V) BFB Pilot Plant Gasifier Gas Cleanup Area Fuel: sewage sludge 7.5% moisture and 12.1 MJ/kg of LHV Gasifier capacity: 2.4 t/day of dried sewage sludge Fluidising agent: AIR Gas Cleaning system: heat exchanger for gas cooling, gas filter (precoated bag house filter) and 3 gas scrubbers

R&D Activities CO 2 -capture Technologies Bioenergy: Biomass thermochemical conversion/gasification Advanced combustion gas clean technologies Modelling of combustion process Optimization of combustion process New concepts on Biomass Gasification

BFB gasification pilot plant (25 kw th ) Technical Data Type of reactor Bedinsidediameter Bed height Freeboard inside diameter Freeboard height BFB 0.15 m 1.40 m 0.25 m 2.15 m Pressure/Temperature 1atm/ 800ºC BFB gasification bench-scale plant (5 kw th )

GASIFICATION DEMOSTRATION PLANT (3 MW th ) Plant Technical Data Type of reactor Thermal Capacity Oxidising agent BFB 3 MW th Air Pressure/Temperature 0.3 bar/ 800ºC Biomass feeding rate 15 t/day Thermal Yield (cold gas) 75 % Used Biomass Wood pellets Olive Stones

PFD Feeding System Gasification Isle Gas Cleaning System

Research area: Energy Processes & Emissions Reduction Utilization of coal and renewables for CO 2 emissions reduction and H 2 generation CO 2 capture in combustion and gasification processes Development of new materials for H 2 storage Fluidised bed combustion NO x emissions reduction CO2 Capture from combustion flue gases using CaO Carbonation/calcination loop

CO 2 Capture from combustion flue gases using CaO Carbonation/calcination loop 30 kw twin CFB test facility at INCAR-CSIC Calciner T~ 900ºC Carbonator T ~ 650ºC CaCO 3 CO 2 + CaO CO 2 + CaO CaCO 3 O 2 + coal Flue gas

CIRCE Center of research on energy resources & consumption Non-profit private organisation, sponsored by Utility Mining Educational Government R&D in energy and thermal and electrical engineering Experience in coal & biomass combustion, plant tests & monitoring in conventional (PF) and advanced (FBC, IGCC, co-firing) concepts, laboratory work, simulation, CFD, CO 2 capture systems (oxyfuel, calcium looping, process integration)

CIRCE Center of research on energy resources & consumption Research interest Oxyfuel combustion. 100 kwt O 2 /CO 2 bubbling fluidized bed 2.7 m height, 23 cm i.d. Recycling ratio: 0% to 80%. O 2 : from 20% to 40% Combustion efficiency BFB temperature distribution Heat transfer Emissions Hydrodynamic Characterization CFB for Calcium Looping Systems. Cold flow Two Plexiglas risers, 4 m height and 160-170 mm i.d Pressure drop along CFB s and loop-seals Solid circulation measurement System performance with design modifications Spanish situation on FBC 58thIEA FBC Xi'an May 17, 2009

Instituto de Carboquímica de Zaragoza - Chemical-Looping Combustion (CLC) for gaseous fuels (syngas, CH 4 ) - Process and materials development - Chemical-Looping Combustion of coal - Development of oxygen carrier materials - Process development - Process modelling and simulation - Oxyfuel combustion in fluidized bed - Reduction of pollutant emissions - Hydrogen generation by Autothermal Chemical-Looping Reforming (CLR) - Development of oxygen carrier materials - Process modelling and simulation

Chemical-Looping Combustion installations 10 kw CLC unit for gaseous fuels 900 W Autothermal CLR unit Contact: Prof. Juan Adánez

New Projects HUNOSA/ENDESA CIUDEN - ENDESA

New Projects HUNOSA/ENDESA/CSIC There is confidence on the technical viability of carbonate looping cycles after successful experiments at conditions close to those expected in the real CFB carbonator reactor. Endesa, Hunosa and CSIC will built and run before the end of 2010 a 1 MW pilot dedicated to carbonate looping, close to a CFB power plant. Contact: Juan Carlos Abanades e-mail: abanades@incar.csic.es Direct phone: 34 985 11 89 80

New Projects CIUDEN- ENDESA

CIUDEN TEST FACILITY FOR ADVANCED ECHNOLOGIES FOR CO 2 CAPTURE IN COAL POWER GENERATION UPDATE AND UPGRADE 58 Th IEA FBC IMPLEMENTING AGREEMENT Prof. Dr. Vicente J. Cortés CO 2 Capture Program Director CIUDEN, SPAIN

Fundación Ciudad de la Energía An initiative of the Spanish Administration MINISTERIO DE CIENCIA E INNOVACION MINISTERIO DE INDUSTRIA MINISTERIO DE MEDIO AMBIENTE Spanish situation on FBC 58thIEA FBC Xi'an May 17, 2009

Simplified process diagram FROM COAL PREPARATION PC BOILER O 2 STORAGE AND VAPORISATION PHASE II ABSORPTION SECTION STACK CH-50 PC BIN DeNOX AIR CO 2 FGR2 FGR1 COMPRESSION TRAIN PREHEATING TRAIN CO 2 CFB BOILER O 2 PREHEATING CFB BIN MIXERS BAG FILTER HIGH EFFICIENCY DeSOX EXPANDER BAG FILTER FGR2 RECIRCULATION

Relevant oxicombustion projects worldwide LARGE SCALE INTEGRATED PILOT PROJECTS PROJECT LOCATION PC MWth CFB START-UP MAIN FUEL REMARKS VATTENFALL GERMANY 30 2008 LIGNITES 1 BURNER TOTAL FRANCE 30 2009 NG/HC 1 BURNER INDUSTRIAL BOILER CIUDEN SPAIN 20 30 2010 ANT./ BIT./ PETCOKE 2+2 BURNERS OXYBURNERS TEST FACILITIES B&W USA. 30 2007 BIT., SUB B, LIGN. 1 BURNER OXY-COAL UK UK 40 2008 1 BURNER BOILERS REFURBISHMENT/RETROFITTING PEARL PLANT USA 66 2009 BIT. JUPITER TECHNOLOGY CALLIDE AUSTRALIA 90 2010 BIT. _

Model of the plant Chemical absorption CO2 compression FGC Combustio n Island Control Room Oxygen supply Fuel preparation Spanish situation on FBC 58thIEA FBC Xi'an May 17, 2009

The site, near COMPOSTILLA II Power Plant Spanish situation on FBC 58thIEA FBC Xi'an May 17, 2009

Time schedule 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 DISEÑO ORIGINAL CIEMAT DISEÑO REVISADO CIUDEN PERMITTING Y CONTRATACION CONSTRUCCION OPERACION PARA I&D&d PROYECTO 7º PROGRAMA MARCO VALIDACION UNIDADES TRANSFERENCIA TECNOLOGICA SERVICIOS A INGENIERIAS, TECNOLOGOS ELECTRICAS 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015

ENDESA Longannet Hatfield Eemshaven Rotterdam Jaenschwalde Tilbury Kingsnorth Huerth Belchatow Compostilla 500 Mwe CFB Oxi-combustion Supercritical Steam EU Coal Power Generation Demonstration Plants (near 500 Mwe) planed Spanish situation on FBC 58thIEA FBC Xi'an May 17, 2009

The R&D programme structure RESEARCH PROGRAMME OF EL BIERZO TEST FACILITY SCIENTIFIC PROGRAMME EXPERIMENTAL PROGRAMME PERFORMED BY RELEVANT RESEARCH INSTITUTIONS PERFORMED AT THE FACILITY IN COOPERATION WITH RESEARCH INSTITUTIONS, TECHNOLOGY PROVIDERS AND TECHNOLOGY USERS

Juan Otero Department of Energy juan.otero@ciemat.es 58 Th IEA FBC IA Xi an May 17, 2009