Methane to Markets Oil and Natural Gas Technology Transfer Workshop

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Methane to Markets Oil and Natural Gas Technology Transfer Workshop Airborne Differential Absorption Lidar (DIAL) Detection and Measurement of Fugitive Emissions Steven Stearns ANGEL Service ITT Space Systems Division Rochester, New York email: steven.stearns@itt.com phone: (585) 269-5967 www.ssd.itt.com/angel 25 May 2006 ITT Corporate Overview 2 ITT: ~$7.0 Billion (annual revenue) ITT Defense: ~$3.0 Billion (annual revenue) Supplier of sophisticated military defense systems and provider of advanced technical and operational services to government customers. ITT Space Systems Division Over 50 years as a national leader providing innovation and quality in the design, production and development of Remote Sensing, Meteorological, and Navigation satellite systems.

Evolution of Pipeline Leak Survey Technology 3 1970 1980 1990 2000 2001 2002 2003 2004 2005 2006 Flame Ionization Spectroscopy Hand-held device Slow 1 mph Need to come in contact with the plume Difficult terrain and property issues Industry standard equipment Pass-through Optical Sensors Truck mounted sensor Slow 5 mph Need to come in contact with the plume Difficult terrain and property issues Easily damaged Airborne Remote Sensing Airborne DIAL Sensor High sensitivity Detects and quantifies emissions Broad area scan pattern Fast 150 mph Operates over difficult terrain and environmentally sensitive areas GIS-ready results Hydrocarbon Gas Detection: Active Remote Sensing Differential Absorption LIDAR 4 Absorption 15 On-line wavelength is chosen close to peak of the 10 absorption feature 5 The difference in absorption between the two wavelengths can be used to determine the concentration of the chemical responsible for the absorption feature 0 3046.5 3047.0 3047.5 Wave Number (cm-1) Two lasers sent on the same path generate light which is reflected off the surface and back to the sensor passing through the plume twice in a fraction of a second. Gas Plume Location

Emission Measurements: Linear trend between Concentration (PPM) and Concentration-Path-Length (PPM-m) 5 Depending on conditions, a 150ppm-m CPL will have a ground level concentration ranging from 45ppm to 70ppm. ITT Airborne Natural Gas Emission Lidar (ANGEL) Service Aircraft: DIAL Sensor System and Supporting Hardware 6 DIAL Sensor Digital Video Camera High Resolution Mapping Camera

High-Resolution Digital Color Imagery 7 Vehicles and Equipment Digital Color Video System Patrol any right-of-way from your desktop 8 3-chip RGB Digital Video System Allows you to easily patrol any pipeline segment from your desktop computer. Play, pause, fast forward, rewind, and even print video frames from digital files. Encodes video data with GPS information, so precise locations can be identified. Provides permanent record of aerial patrolling, easement conditions, encroachment monitoring, intrusion detection, and problem areas.

ITT Airborne Natural Gas Emission Lidar (ANGEL) Service Aircraft: Computer controlled pointing, scanning and tracking system 9 DIAL Detection and Measurement of Hydrocarbon Gases Example #1: Pipeline Route Texas 10 DIAL Gas Detection and Measurement DIAL Scan Pattern 3,000 laser samples per second 100 foot wide swath

DIAL Detection and Measurement of Hydrocarbon Gases Example #2: Pipeline Route Texas 11 Controlled release of 8 scfm DIAL Detection and Measurement of Hydrocarbon Gases Example #3: Light Crude Tank Farm 12

DIAL Detection and Measurement of Hydrocarbon Gases Less than 3 seconds of collection from 1,000 altitude 13 DIAL Scan Pattern DIAL Detection and Measurement of Hydrocarbon Gases Example #3: Light Crude Tank Farm 14 Hatches CLOSED CPL (PPM-m)

DIAL Detection and Measurement of Hydrocarbon Gases Example #3: Light Crude Tank Farm 15 Hatches OPEN CPL (PPM-m) DIAL Detection and Measurement of Hydrocarbon Gases Example #4: Detection over grass Open field. 16 Release Tank Flow: 30 scfm

DIAL Detection and Measurement of Hydrocarbon Gases Less than 3 seconds of collection from 1,000 altitude 17 DIAL results CPL (PPM-m) DIAL Detection and Measurement of Hydrocarbon Gases Example #5: Detection over snow (3 separate 4 scfm releases) 18

Conclusions Airborne DIAL can detect and measure fugitive gas emissions 19 Airborne DIAL can provide a unique, comprehensive, and unobstructed view of area emissions. Airborne DIAL can detect specific hydrocarbon gases/vapors (i.e. methane, ethane, propane, gasoline, condensates, etc.). Airborne DIAL can quantify area emissions and provide quantitative information on a plume s size and shape. Airborne DIAL can directly measure the various concentrationpath-lengths (ppm-m) within area emissions. Airborne DIAL can operate day or night, and when integrated into a fixed wing aircraft can survey up to 1,000 pipeline miles per day. Acknowledgements Funding, Field Research, Facilities 20 US Department of Energy National Energy Technology Laboratory (DOE/NETL) US Department of Transportation Pipeline and Hazardous Materials Safety Administration (DOT/PHMSA) Texas A&M University Corpus Christi, Pollution Prevention Partnership BP America, Inc. El Paso Production National Fuel Gas Company Northern Natural Gas

Methane to Markets Oil and Natural Gas Technology Transfer Workshop Airborne Differential Absorption Lidar (DIAL) Detection and Measurement of Fugitive Emissions Steven Stearns ANGEL Service ITT Space Systems Division Rochester, New York email: steven.stearns@itt.com phone: (585) 269-5967 www.ssd.itt.com/angel 25 May 2006