Meeting the Thermal Management Needs of Evolving Electronics Applications

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Meeting the Thermal Management Needs of Evolving Electronics Applications Dr. Glenn Mitchell / August 2015

Agenda Introduction Thermal Industry Trends TIM Challenges, Needs & Criteria TIM Industry Solutions Summary Questions TIMs A Closer Look 2

Thermal Management Industry Trends 3

Industry Trend: Power Densities Accelerating Market Dynamics - Increasing power consumption for CPU, APU, GPU, and chipsets - Thermal performance & reliability becoming increasingly important across more applications Watts 450 400 350 300 250 200 150 100 50 0 VGA Power Consumption 410 392 340 283 250 216.4 2009 2010 2011 2012 2013 2014 Server and Telecom Heat Load Rising Power Drives More Emphasis on Reliability 4

Merchant Silicon Power in Networking Applications Power Increases more than Seven Times after the year 2000 Power Cycling Trends in Networking Applications 5

TIMs Crucial for Thermal Management Product Performance - Increasing power densities - High density board layout - Higher Device Temperatures - Lower Thermal Impedance - Increased Thermal Stability and Reliability - Harsher Test Conditions Customer Satisfaction - Reliable product performance for demanding users Result of Incorrect TIM - Device failure and performance degradation 6 Real Potential to Impact Customer Satisfaction and Brand

Thermal Management Challenges, Needs & Criteria 7

Key Thermal Properties of TIM Bulk Thermal Conductivity (W/mK) Material property only Does not consider: - Interface contact resistance - Bond line thickness R TIM Thermal Impedance ( C.cm 2 /W) Thermal bulk resistance + interface contact resistance Bond line thickness Heat Spreader Heat Sink R c2 T q = ka x T TI = A q TIM IC BLT R TIM = K TIM BLT R c1 k: thermal conductivity x: thickness of sample T: temperature difference across sample A: cross-sectional area of sample TIM Thermal Impedance: TI T = BLT/K + R C TI T = Total Thermal Impedance BLT = Bond Line Thickness of TIM K = Bulk Thermal Conductivity of TIM = Thermal Contact Resistance at the Interfaces R C Thermal Impedance Most Critical to Thermal Dissipation and Performance 8

TIMs - Thermal Needs and Requirements # Customer Need Measure Test Method 1 Thermal Performance 2 Out-of-Box Performance @ Time 0; Withstand Temp Spikes and Bursts 3 Longevity 4 Performance Under Harsh Operating Conditions 5 Bond Line Thickness 6 Compression & form factor Thermal Conductivity (W/mK) Thermal impedance (TI, o C.cm 2 /W) Thermal impedance (TI, o C.cm 2 /W) <10% Thermal Degradation over ALT Test Severity ; temperature, humidity, shock, etc. <0.2mm; 0.2mm 1.0mm; >1.0 mm Bond line Compression need Thermal Bulk Conductivity TTV, Laser Flash ASTM E1461 Cut Bar TI Test ASTM D5470 TTV, Laser Flash ASTM E1461; Cut Bar TI Test ASTM D5470 High Temperature Storage, Temp Cycling; Highly Accelerated Stress Test (HAST) Arrhenius Modeling High Temperature Storage, Temp Cycling; Highly Accelerated Stress Test (HAST) BLT Measurement Deflection vs. Pressure 7 Economics $/device Cost of Ownership Modeling 9

Segment Landscape Thermal Performance: TI at T0 Reliability First Notebooks,, Tablets, Mobile, VGA Cards, GPU, MPU, CPU Performance & Reliability Auto, Power, Telecom Infrastructures, Servers Good Enough Gaming, Servers, Wireless, Power, Consumer Electronics Understanding and Prioritizing Needs is Critical to TIM Selection 10 2015 Honeywell International Confidential All Rights Reserved Desktop CPUs, HBLED, Consumer Electronics

TIM Industry Solutions 11

TIM Material Choices Thermal Grease silicone-based, greases are non-curing, conformable provide low thermal resistance for applications that do not require long term reliability and thermal shock Metallic all-metal (e.g., solder) or utilize a metal matrix or binder to which metallic or nonmetallic fillers have been added good thermal conductivity but normally contact resistance or surface wetting is not good TIM Solution Gap Pad typically thicker (>1mm) than other TIMs and designed to have good compression properties however, they usually can not deliver the same level of thermal performance as other TIM materials Thermal Gel normally is one-component, crosslinked or pre-cured gel structure good compressibility and dispense process automation Thermal Adhesives one or two-part crosslinkable materials based on epoxies or silicones known for their structural support - this can eliminate the need for mechanical clamps, but cure time is required and they are not reworkable Others thermal compound, tapes, films, epoxy, etc. Phase Change Material (PCM) transforms from a solid state to a liquid or gel state no bleed out, pump out and degradation issues normally found in thermal greases 12

Greases in Power Cycling Applications Greases - Subject to thermal expansion of the heat sink and ASIC lid during power cycling - Can cause pump out and result in dry-out scenarios of the interface between the heat sink and the chip Name of Sensor Grease Application Phase Change Application Chip 1 91.0 92.0 Chip 2 92.0 91.2 Chip 3 98.0 97.5 Chip 4 100.0 99.0 13 PCM Can Provide Equal Thermal Performance as Grease w/o Issue

Illustration of Pump Out Grease pump out and creation of voids Phase change application forming a continuous interface between heat sink and ASIC lid 14

Theoretical Curve: PCM Viscosity vs. Temp. Viscosity Solid Liquid/gel state Optimal Surface wetting Low Contact Resistance Low Thermal Impedance Melt temp 45 C Increasing Temperature 15

PCM Polymer Higher Molecular Weight - Structural integrity Long Chain Polymer Structure PCM Grease vs. Long Chain Stable and Consistent Filler Minimizes Filler Migration / Separation Over Accelerated Life Test (HTB, Temp Cycle) Short Chain Good Flow-ability, Wetting but Potential for Migration, Dry- Out and Pump-Out Issues 16 PCM Polymer Structure Enables Reliable, Long-Term Performance

PCM Technology Fundamentally three primary components in PCM Each are vital to robust polymer matrix integrity and filler optimization Thermal Filler Filler - Thermal Wax/Polymer - Structural integrity Additives TIM Performance and Reliability Wax/ Polymer Additives - Cross linking, ATO, etc PCM Formulation is Critical to Performance 17

PCM vs. Silicone Grease Initial 1000 cycles Thermal Cycle (-55 C to 125 C) vs. Grease Honeywell PCM PCM Silicone Grease Silicone Grease Grease breaks down Grease TI degrades Thermal Cycling Test Condition: -55 Cx10min + 125 Cx10 min, for 500 to 1000 cycles Sandwich PCM & grease between aluminum and glass plates set at 200μm gap TI Test : ASTM D5470 PCM Provides Stable Polymer Structure with No Pump-Out Issue 18

PCM vs. Silicone Grease Honeywell PCM Initial 400 hr 2.00 1.80 1.60 1.40 High Temp Bake at 150 C vs. Grease Honeywell PCM PCM Competitor Silicone Grease grease 1.78 1.20 1.00 0.80 Silicone Grease 0.60 0.40 0.20 0.09 0.12 0.11 0.00 Initial Baking 400 Hr Oil bleeding from grease Grease TI degrades 19 High Temperature Baking (HTB) Test Condition: HTB = 150 C PCM & thermal grease dispensed on smoked glass plates TI Test : ASTM D5470 PCM Does Not Suffer From Silicone Oil Bleed

Thermal Reliability: PCM vs. Silicone Greases 1.20 High Temperature Soak at 150 C TI vs. Hours of Exposure Thermal Impedance ( C-cm2/W) 1.00 0.80 0.60 0.40 0.20 PTM3180 PTM5000 Grease A Grease B 0.00 0 200 400 600 800 1000 Test Condition: 150 C continuous baking Test Method: Laser Flash, ASTM E1461 Hours 20 Significantly Better Reliability Than Silicone Grease

Extended Reliability - PCM Thermal Stability >3000 hrs @ 150 C HAST > 192hrs@ 130 C/85%RH Superior Reliability HAST TI vs. Time ASTM E1461 High Temperature Baking TI vs. Time >10% deviation of thermal impedance indicates end of reliability life ASTM E1461 21 Polymer Chemistry Enables Improved Reliability

Improved Thermal Impedance - PCM Lower Thermal Impedance: <0.06 o Ccm 2 /W As much as 30% Improvement at 20 um Bond Line Wider Process Window for Pre-Load Pressure Range Test Method: Cut bar, ASTM D5470 22 New PCM Material Demonstrates Lower Thermal Impedance

Thermal Test Vehicle (TTV) Study TTV (thermal test vehicle) Results PTM7000 PTM5000 Grease CPU device: = 9.25 mm x 8.29 mm GPU device: 12.36 mm x 9.13 mm 23

Summary Increased device power densities challenge the performance and reliability of Thermal Interface Materials Application needs and requirements as well as accelerated life tests are critical to TIM selection criteria The robust polymer chemistry of Phase Change Materials enables low thermal impedance with proven long term thermal stability and reliability 24

Questions 25

Thermal Impedance Test Method: Laser Flash Netzsch Laser Flash IR Sensor Die TIM Spreader Temperature Laser Pulse Time Determines Thermal Diffusivity Flash Thermal Conductivity/Resistance Calculated k = (α)(cp)(ρ) k = Thermal Conductivity (W/cmK) α = Thermal Diffusivity (cm 2 /s) α =0.13879L 2 /t 1/2 L=specimen thickness, meter t 1/2 =the time required for the temperature rise to reach 50% percent of ΔTmax Cp = Specific Heat Capacity (J/gK) ρ = Density (g/cm 3 ) ASTM E1461 Thermal Impedance Between Si, Ni-plated Cu Surfaces - Includes the CTE mismatch - includes actual surface finish Typical Coupons: - Ni-plate copper, 0.5 X0.5 X0.03 - Si, 0.5 X0.5 X0.02 Suitable for Accelerated Life Test 26

Thermal Impedance Test Method: Cut Bar Heater Block (provide constant heat) Upper Intermediate Block Test Sample Lower Intermediate Block Cooling Block (maintain constant low temp.) T1 T2 T3 T4 T5 T6 Connect to data acquisition set-up Per Fourier s Law of Heat Conduction: T q = ka x T TI = A q q = heat flux K = thermal conductivity x = thickness of sample T = temperature difference across sample A = cross-sectional area of sample ASTM D5470 - Destructive, one time test only - Fast test for immediate results - Most common test method 27