Chem 11 Practice Questions for Ch. 8

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Chem 11 Practice Questions for Ch. 8 1. Atoms having equal or nearly equal electronegativities are expected to form A) no bonds B) polar covalent bonds C) nonpolar covalent bonds D) ionic bonds E) covalent bonds 2. For the elements Cs, F, and Cl, the order of increasing electronegativity is: A) F < Cl < Cs B) Cs < Cl < F C) Cl < Cs < F D) F < Cs < Cl E) none of these 3. Based on electronegativity differences, which of the following is most likely to be ionic? A) CaF 2 B) Br 2 C) BH 3 D) NO E) CF 4 4. Which of the following bonds would be the most polar without being considered ionic? A) Mg-O B) C-O C) O-O D) Si-O E) N-O 5. Which of these is an isoelectronic series? A) Na +, K +, Rb +, Cs + B) K +, Ca 2+, Ar, S 2 C) Na +, Mg 2+, S 2, Cl D) Li, Be, B, C E) none of these (A-D) 1

6. Using the following bond energies: Bond Bond Energy (kj/mol) C C 839 C H 413 O=O 495 C=O 799 O H 467 estimate the heat of combustion for one mole of acetylene: C 2 H 2 (g) + 5 2 O 2(g) 2CO 2 (g) + H 2 O(g) A) 1228 kj B) 1228 kj C) 447 kj D) +447 kj E) +365 kj 7. In the Lewis structure for elemental nitrogen there is (are) A) a single bond between the nitrogens B) a double bond between the nitrogens C) a triple bond between the nitrogens D) three unpaired electrons E) none of the above Consider the compound crotonaldehyde, whose skeleton is: 8. How many electrons must be shown (as bonding or nonbonding electrons) in the Lewis structure of this molecule? A) 12 B) 18 C) 24 D) 28 E) 32 9. How many nonbonding electrons appear in the Lewis structure of this molecule? A) 2 B) 4 C) 6 D) 8 E) 10 2

10. Which carbon in this molecule has tetrahedral bonding? A) 1 B) 2 C) 3 D) 4 E) all 11. Which of the following Lewis structures best describes BF 3? A) B) C) D) E) 12. Which of the following has an incomplete octet in its Lewis structure? A) SO 2 B) ICl C) CO 2 D) F 2 E) NO 3

13. Which of the following is not a valid resonance structure for N 3? A) B) C) D) E) all are correct 14. Select the molecule from the following that has a dipole moment. A) CO 2 B) SeO 3 C) XeF 4 D) SF 4 E) BeCl 2 15. If a compound has a number of individual dipoles, then: I. It is polar overall. II. There is an electronegativity difference between the bonded atoms. III. it is ionic. IV. It doesn't have resonance. A) II only B) II, IV C) I, II, IV D) I, III E) All of the above statements are correct. 16. The Cl Kr Cl bond angle in KrCl 4 is closest to A) 90 B) 109 C) 120 D) 150 E) 360 4

17. The bond angles about the carbon atom in the formaldehyde molecule, H 2 C=O, are about: A) 120 B) 60 C) 109 D) 180 E) 90 18. Which of the following species has a trigonal bipyramid structure? A) NH 3 B) IF 5 C) I 3 D) PCl 5 E) none of these 19. Which ion is planar? A) NH + 4 B) CO 2 3 C) SO 2 3 D) ClO 3 E) all are planar 20. Which ion is larger in each pair? i) O 2- or S 2- ii) Fe 2+ or Fe 3+ iii) S 2- or K + A) S 2-, Fe 2+, S 2- B) S 2-, Fe 3+, S 2- C) O 2-, Fe 3+, K + D) S 2-, Fe 2+, K + E) O 2-, Fe 2+, S 2-21. Calculate the lattice energy of the ionic compound MCl 2 given the information below: H f MCl 2 (s) = -342 kj/mol IE 1 of M = +600 kj/mol IE 2 of M = +1150 kj/mol Cl 2 (g) => 2 Cl(g) H = +244 kj Cl(g) + 1 e - => Cl - (g) H = -349 kj M(s) => M(g) H = +150 kj A) -2136 kj B) -2015 kj C) -1446 kj D) -1788 kj E) -1666 kj 5

ID: A Chem 11 Practice Questions for Ch. 8 Answer Section 1. ANS: C PTS: 1 DIF: Easy REF: 8.2 KEY: Chemistry general chemistry bonding covalent bonding electronegativity 2. ANS: B PTS: 1 DIF: Easy REF: 8.2 KEY: Chemistry general chemistry bonding covalent bonding electronegativity 3. ANS: A PTS: 1 DIF: Easy REF: 8.2 KEY: Chemistry general chemistry bonding covalent bonding electronegativity 4. ANS: D PTS: 1 DIF: Moderate REF: 8.2 KEY: Chemistry general chemistry bonding covalent bonding electronegativity polar covalent bond 5. ANS: B PTS: 1 DIF: Easy REF: 8.4 KEY: Chemistry general chemistry bonding ionic bonding 6. ANS: B PTS: 1 DIF: Moderate REF: 8.8 KEY: Chemistry general chemistry bonding covalent bonding bond energy MSC: Quantitative 7. ANS: C PTS: 1 DIF: Easy REF: 8.1 KEY: Chemistry general chemistry bonding covalent bonding Lewis dot formula 8. ANS: D PTS: 1 DIF: Easy REF: 8.1 KEY: Chemistry general chemistry bonding covalent bonding Lewis dot formula 9. ANS: B PTS: 1 DIF: Easy REF: 8.1 KEY: Chemistry general chemistry bonding covalent bonding Lewis dot formula 10. ANS: A PTS: 1 DIF: Easy REF: 8.13 KEY: Chemistry general chemistry bonding molecular geometry the valence-shell electron-pair repulsion model 11. ANS: A PTS: 1 DIF: Easy REF: 8.11 KEY: Chemistry general chemistry bonding covalent bonding exceptions to the octet rule 12. ANS: E PTS: 1 DIF: Easy REF: 8.11 KEY: Chemistry general chemistry bonding covalent bonding exceptions to the octet rule 13. ANS: A PTS: 1 DIF: Easy REF: 8.12 KEY: Chemistry general chemistry bonding covalent bonding resonance 1

ID: A 14. ANS: D PTS: 1 DIF: Moderate REF: 8.13 KEY: Chemistry general chemistry bonding molecular geometry dipole moment 15. ANS: A PTS: 1 DIF: Easy REF: 8.13 KEY: Chemistry general chemistry bonding molecular geometry dipole moment 16. ANS: A PTS: 1 DIF: Moderate REF: 8.13 KEY: Chemistry general chemistry bonding molecular geometry bond angle 17. ANS: A PTS: 1 DIF: Moderate REF: 8.13 KEY: Chemistry general chemistry bonding molecular geometry bond angle 18. ANS: D PTS: 1 DIF: Moderate REF: 8.13 KEY: Chemistry general chemistry bonding molecular geometry the valence-shell electron-pair repulsion model trigonal bipyramidal arrangement 19. ANS: B PTS: 1 DIF: Moderate REF: 8.13 KEY: Chemistry general chemistry bonding molecular geometry the valence-shell electron-pair repulsion model 20. ANS: A PTS: 1 DIF: Moderate REF: 8.4 KEY: Chemistry general chemistry bonding ionic bonding ionic radii 21. ANS: D PTS: 1 DIF: Difficult REF: 8.5 KEY: Chemistry general chemistry bonding ionic bonding Born-Haber cycle MSC: Quantitative 22. ANS: A PTS: 1 DIF: Moderate REF: 9.1 KEY: Chemistry general chemistry bonding bonding theories hybridization 23. ANS: C PTS: 1 DIF: Moderate REF: 9.1 KEY: Chemistry general chemistry bonding bonding theories hybridization 24. ANS: D PTS: 1 DIF: Moderate REF: 9.1 KEY: Chemistry general chemistry bonding bonding theories multiple bonding 25. ANS: D PTS: 1 DIF: Easy REF: 9.1 KEY: Chemistry general chemistry bonding bonding theories multiple bonding 2