Report WCCAP Calibration Workshop Condensation Particle Counters November 2002

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Report WCCAP Calibration Workshop Condensation Particle Counters November 22 Dr. Thomas Tuch Dr. Alfred Wiedensohler The intercomparison and calibration workshop for Condensation Particle Counters (CPC) was held at the World Calibration Center for Aerosol Physics in Leipzig in October 22. The workshop was jointly coordinated with the GAWTEC IV course at Schneefernerhaus, Zugspitze, also held in October 23. Three people attending the GAWTEC course participated also with their instruments in the intercomparison and calibration workshop. The entire time for preparing and conduction the workshop covered approximately three man month. Calibration procedure: A tube furnace generator in combination with a Differential Mobility Analyzer (DMA) was used produce silver particles. Calibration of the aerosol electrometer using several TSI 31 CPCs and a 4 nm monodisperse aerosol. The uncertainty of the TSI 31 have been in the range of few percent. Calibration of two CPCs of the WCCAP as comparison counters using an aerosol electrometer as reference instrument. CPCs were tested for functioning using a monodisperse 4 nm aerosol and comparing the number concentration with the comparison counters. A TSI technician attended the workshop to electronically check the CPCs and if possible to repair them. The DWD and Izana UCPCs were repaired. The low flow modus of the UCPC from Izana could however not be fixed within the frame of the workshop. The 761 and 376 from DWD and NOAA, respectively, could also not be repaired. TSI is not able to support these counters any longer. Determination of the counting efficiency curve of the TSI 31, 761, and 376 CPCs in the size range from 7-4 nm using monodisperse aerosols. Determination of the counting efficiency curve of the TSI 325 UCPC in the size range from 3-4 nm using monodisperse aerosols. Calibration of the Pollak Counter

Particle Counters in the workshop: Organization CPC SN Status Action Result Calibration IFT 31 26 ok Ok IFT 31 2114 ok Ok IFT 325 137 ok Ok IFT 325 119 ok Ok IFT 31 2337 ok Ok INM 325 116 high TSI service High Flow Ok Ok Finnland 31 2366 ok Ok CSIRO 376 638 ok Ok DWD 761 n.a. low TSI service defect No DWD 325 116 high TSI service Ok Ok Mace Head 31 2296 ok Ok Mace Head 31 2275 ok defect NOAA 31 31 228 ok Ok NOAA 376 376 597 low TSI service defect No PSI 31 2154 ok Ok Mace Head Pollak Counter ok Ok The final counting efficiencies were sent to the participating institutes. Because of the different applications of the CPCs, no individual Standard Operation Procedures (SOP) were developed during the workshop. The participant received a general SOP for CPCs used to measure total number concentrations.

Participant list: Treffert, Ulrich Name Institution Country Federal Environmental Agency Germany Kelly, Brendan Galway, (Mace Head) Ireland Pedro Miguel Ramero Campos Kaminski, Uwe I.N.M, (Izana) German Weather Service (DWD), Hohenpeissenberg Spain Canary Islands Germany Paulsen, Dwane PSI Switzerland Andrews, Betsy NOAA/CMDL USA Komppula, Mika FMI Finland Graham, Bim CSIRO Australia Ouchene, Bouziane ONM Algeria German Weather Service Wilhelm, Reinhard T. (DWD), Hohenpeissenberg Germany Birgit Wehner IfT Germany Thomas Tuch IfT Germany Alfred Wiedensohler IfT Germany Wolfgang Völker TSI Germany

Calibration Curves CPC Calibration 22.1.22 WCC Institute for Tropospheric Research, Leipzig, Germany 1.1 1 counting efficiency.7.6.5.4.3 Eff 31 #2337 Eff 31 #2117.2 Eff 31 #2296 Eff 31 #2366.1 Eff 376 #638 @1l/min Eff 31 #228 5 1 15 2 25 3 35 4 45 UCPC Calibration 23.1.22 WCC Institute for Tropospheric Research, Leipzig, Germany 1.2 1.1 1 efficiency.7.6.5.4.3.2.1 Eff 325 #137 Eff 325 #116 1 1 1

UCPC Calibration 24.1.22 WCC Institute for Tropospheric Research, Leipzig, Germany 1.3 1.2 1.1 Eff 31 #2154 Eff 325 #119 Eff 325 #116 1 efficiency.7.6.5.4.3.2.1 1 1 1 Average Efficiency of Nolan Pollak Counter.7.6 Efficiency.5.4.3.2.1 Reference: TSI CPC 325 A Serial Number 137 1 1 Average Efficiency 1

Comparison Laser OPC MetOne (Tamanrasset/Assekrem) Aerodynamic Particle Sizer: The people ask to calibrate of the Laser OPC MetOne during the workshop. However, this was not possible within the time period of the workshop. Instead, the OPC was intercompared with an Aerodynamic Particle Sizer (APS). The final result of the intercomparison will be send to Tamanrasset in April 23.