Industrial Technologies Bilfinger EMS GmbH Biogas Upgrading Technologies

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Industrial Technologies Bilfinger EMS GmbH Biogas Upgrading Technologies Massimo Pardocchi Consorzio Italiano Biogas Bologna 16.12.2013

Content 2 Bilfinger Group Bilfinger EMS GmbH Amine upgrading Membrane upgrading

Bilfinger Group A strong Group at work around the world for our clients 3 Engineering, construction and services 125 years experience 70.000 employees Around 200 companies and subsidiaries Turnover 2012: > 8.6b Output volume by region 2012 Market leader for industrial services in EU Full range of services from a single source Individual trades to full-service solutions 44% Europe outside Germany 39% Germany 8% America 5% Africa 4% Asia

Bilfinger EMS GmbH Your german partner for the renewables technologies 4 > 35 years in gas processing (NG + BG) > 100 references > 530 employees > Turnover 2013: > 72 m EPC for the biogas upgrading unit EPCM for the full biogas plant Concept and feasibility studies Design & Fabrication Implementation of O&M procedures

Bilfinger EMS GmbH OASEgreen Process 5 Simplified process Desulfurisation before or after upgrading No pre-dehydration Long absorbent lifetime H2S < 5 mg/m³ possible operation slightly above atmospheric pressure High biomethane recovery Extremely low methane losses <0,05% Methane enrichment to > 99,0 Vol.% Advantages for grid injection Compression after CO2 removal Smaller compressors required

Bilfinger EMS GmbH Advantages of OASEgreen Process 6 Advantages of OASEgreen : Chemisorption of H2S Developed solvent: BASF SE, Bilfinger EMS, Wingas Methane-loss < 0,05% Oxygen-resistant Low pressure process ( at atmospheric pressure) Minimum loss of solvent < 5% per year) No unmeant reaction with gas-components Low regeneration-temperature Non hazardous solvent (WGK Class 1) High durability of min 24.000 h (up to 48.000h) Advantages of our upgrading unit: Low maintenance cost Low Energy consumption E <0,06 kwh/nm³ raw biogas T < 0,7 kwh/nm³ raw biogas < 0,4 kwh/nm³ if using excess heat Use of different heat-sources possible Upgrading from 600 up to 10.000 Nm³/h Fully automated process (daily inspection <1h) Modular compact skid mounted standarized design

Bilfinger EMS GmbH References OASEgreen BUP s Verbio (2 separate plants Schwedt and Zörbig) 7 Biogas from bioethanol-residuum 6.000 Nm³/h (1. Step) 25 60 Vol% CO 2 100 ppm H 2 S Biomethane max. 4.500 Nm³/h < 0,5 Vol% CO 2 < 4 ppm H 2 S < 0,05 Vol% CH 4 -loss 8.600 h/a availability Range of operation 25 105 % Scope of supply: CO2-Separation Desulphurization of biomethane (without compression and drying of biomethane) Consumption (full load value): 78 KW el 3,0 GJ/toCO2

Bilfinger EMS GmbH References OASEgreen BUP s Verbio ( 2 separate plants Schwedt and Zörbig 8

Bilfinger EMS GmbH References OASEgreen BUP Weltec (Arneburg) 9 Biogas from renewable energy crops 1.450 Nm³/h 44 49 Vol% CO 2 200 ppm H 2 S Modular Construction Biomethane max. 750 Nm³/h < 1,0 Vol% CO 2 < 4 ppm H 2 S < 0,05 Vol% CH 4 -Slip 8.600 h/a availability Range of operation 40 100 % Scope of supply: CO2-Separation Desulphurization biomethane (incl. compression and drying of biomethane) Consumption (full load value): 92 KW el 3,4 GJ/toCO2

Bilfinger EMS GmbH References OASEgreen BUP Weltec (Arneburg) 10

Bilfinger EMS GmbH References OASEgreen BUP Weltec (Arneburg) 11

Bilfinger EMS GmbH Membrane-upgrading process 12 Process Pre desulfurisation Pre dehydration Operation at 10-16 barg 2 or 3 membrane stages High biomethane recovery Extremely low methane losses Methane enrichment to > 99,0 Vol.% Advantages for grid injection Compression in many projects not required Outlet pressure > 10-16 bar g

Bilfinger EMS GmbH Advantages of membrane upgrading process 13 Advantages of membranes Long-time proven hollow fiber polymer membranes on landfill and biogas applications (est.lifetime 15 years) Methane loss < 0,5% High CH4-quantity in the biomethane (CH4 >98%) Reduction of O2 Biomethane quality guarantee Advantages of our plant Low maintenance cost and high energy efficiency fully automated process (daily inspection <1h) only electrical consumption (<0,26 kwh/nm³ raw biogas) heat recovery possible Outlet pressure >16barg, in most cases no need for increasing the pressure for injection Upgrading from 150 up to 2.000 Nm³/h No water consumption Fully automated process (daily inspection <1h) Modular skid mounted standard design

Bilfinger EMS GmbH Other Projects in Renewable Energy Sector 14 Power to Gas Reserarch and Development in Cooperation with Sunfire

Contacts: Bilfinger EMS GmbH Branch Office Italy Ing. Massimo Pardocchi Paola Fibbiani Via dei Mille 10 55049 Viareggio Italy Business Development Sales Assistant Phone +39 0584 38 4751 Mobile +49 172 4595 593 Mobile +39 348 2402749 www.ems.bilfinger.com massimo.pardocchi@bilfinger.com paola.fibbianii@bilfinger.com