Chemical Resistance Guide



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Caveat Note: This chart is for guidance only and is based upon data which has been generated by a laboratory test representing complete immersion of the test sample. In such tests it is not possible to simulate each condition of use. It is the responsibility of the purchaser to establish that the protective gloves are suitable for the particular application in which protection is required. Chemical Resistance Guide

BM Polyco Test Laboratories The state-of-the-art Technical Department laboratories at BM Polyco are equipped to carry out a range of tests on protective gloves. The chemical and physical test laboratories are accredited by UKAS (United Kingdom Accredited Services) to the BSEN ISO / IEC 17025:2000 Standard. 1971 EN374-3 Determination of Resistance to Permeation by Chemicals Resistance to permeation is assessed by measuring the time for a chemical to breakthrough the glove material. Samples, cut from the palms of the gloves, are placed in a permeation cell which enables the chemical to be placed in contact with the outer surface of the gloves. Collection air or water is passed through the cell to collect any chemical that has broken through to the inside surface of the glove sample. Polyco laboratories are equipped with an infra-red spectrometer (to detect solvents), conductivity/ph electrodes (to detect acids, alkalis and salts) and UV/Visible spectrophotometer (to detect high boiling point water soluble chemicals and solvents). Polyco Range Disposable Natural Rubber Unsupported Natural Rubber Finex Optima Jet Finex PF Processor II Chemprotec Puma SuperGrip Maxima (Available in three thicknesses) Finite Nitri Tech II Finite PF N-Dura Indigo Novex Ni-Tone Finesse Pura Finesse PF Vyking Polygen Vyflex Polysol Polychem Polygen Plus Vyclear Long John Isolator / Dry Box Gauntlets and Sleeves A full range of materials including Hypalon, Butyl, Viton and Polyurethane, along with the more standard Latex and Neoprene are available Performance Level 1 2 3 4 5 6 Breakthrough time (min) >10 >30 >60 >120 >240 >480 Degradation E Excellent G Good F Fair P Poor N Not Recommended

Common Names IUPAC Names CAS (Chemical Abstracts Service Registry No) Disposable Natural Rubber Unsup. Natural Rubber Propylene glycol monomethyl ether 1-Methoxy-2-propanol 107-98-2 1 E 4 E 5 P Acetaldehyde Ethanal 25-07-0 0 E 0 N 0 N 0 E Acetic Acid 84% Ethanoic acid 84% 64-19-7 0 P 5 G 6 E Acetone Propanone 67-64-1 1 E 0 N 0 P Acetonitrile Cyanomethane / Methyl cyanide 75-05-8 0 E 0 N 0 N 1 E Acrylamide 50% 2-propenamide 79-06-1 6 E 6 E 6 E Acrylonitrile Propenenitrile 107-13-1 0 N 0 N 0 E Ammonium Fluoride Ammonium Fluoride 40% 12125-01-8 5 6 E E 6 E 5 E 6 E Strong ammonia solution 29% Ammonium Hydroxide 29% 1336-21-6 4 E 4 E 2 E Amyl acetate / Banana oil n-pentyl ethanoate 628-63-7 1 F 0 N 3 P 2 G Amyl Alcohol n-pentanol 71-41-8 1 3 F 6 E 6 E Aniline Aminobenzene / Benzenamine / Phenylamine 62-53-3 0 1 0 P 0N 1 4 Anionic surfactant Potassium aleate 143-18-0 6 E 6 E 5 E Battery Acid 40% Sulphuric acid 7664-93-9 6 E 6 E 6 E 6 6 E Benzoic aldehyde / Benzenecarbanol Benzaldehyde 100-52-7 1 0N 0N 3N Benzene Benzene 71-43-2 0 N 0 N 1 N 1 F Bromoform Tribromomethane 75-25-2 0 N 0 P 2 P alpha - bromopropionic acid Bromopropionic acid 598-72-1 4 4 4 Butyl alcohol Butanol 71-36-3 0 E 2 E 1 E 6 E 0 4 3 E Butyl Acetate Butyl ethanoate 123-86-4 1 P 0 N 2 P 1 Butyl Cellosolve 2-Butoxyethanol 111-76-2 0 2 3 6 E Carbon Tetrachloride Tetrachloromethane 56-23-5 0 N 6 E 1 Cationic Surfactant 6 E 6 E 6 E Cellosolve 2-Ethoxyethanol 110-80-5 0 E 2 E 5 F Chloroform Trichloromethane 67-66-3 0 N 0 N 0 N 0 N Chromic Acid 50% Chromium trioxide solution 1333-82-0 6 E 6 E 6 Citric Acid 2-Hydroxy-1,2,3,-propanetricarboxylic acid 77-92-9 6 E 6 E 6 E 6 E 6 6 Cyclohexane Hexamethylene 110-82-7 3 E 2 E 6 E 2 E Cyclohexyl alcohol / Hexalin Cyclohexanol 108-93-0 3 E 5 E 5 E 6 E 3 Pimelic ketone Cyclohexanone 108-94-1 1 P 0 N 2 P 2 Hexahydroaniline Cyclohexylamine 108-91-8 0 P 1 P 5 P Diacetone Alcohol 4-Hydroxy-4-methyl-2-pentanone 123-42-2 1 E 1 E 1 P Methylene chloride Dichloromethane 75-09-2 0 P 0 N 0 N 0 N Diethanamine Diethylamine 109-89-7 0 N 2 F 0 P Dimethyl Formamide N,N-dimethyl formamide 68-12-2 0 E 1 E 0 N 2 N 0 P Dioctyl phthalate 1,2-Benzene dicarboxylic acid, dioctyl ester 117-81-7 6 G 6 E 5 E Epichlorohydrin 1-Chloro-2,3-epoxypropane 106-89-8 0 E 0 E 0 N Ethyl alcohol Ethanol 67-17-5 0 G 2 E 1 E 4 E 3 Ethanolamine/monoethanolamine 2-Amino ethanol 141-43-5 4 E 6 E 6 E 6 E 4 Ethyl Acetate Ethyl ethanoate 141-78-6 0 0 E 0N 1 P 0 P Ethyl Ether / Diethyl ether Diethyl oxide 60-29-7 0 0 E 2 E Ethyl Lactate Ethyl-2-hydroxypropionate 97-64-3 0 E 2 E 3 P Ethylene Glycol 1,2-Dihydroxyethane / 1,2-Ethanediol 107-21-1 6 E 6 E 6 E 6 E 6 Formaldehyde 37% Methanal 37% 50-00-0 0 E 6 E 6 E 6 E 1 3 6

Common Names IUPAC Names CAS (Chemical Abstracts Service Registry No) Disposable Natural Rubber Unsup. Natural Rubber Formic Acid 90% Methanoic acid 90% 64-18-6 0 F 3 F 2 P 5 Furfural 2-Furancarboxaldehyde 98-01-1 0 E 1 E 0 N 0 N Acetic Acid Glacial Ethanoic acid glacial 64-19-7 0 G 2 G 1 2 P 2 4 Glutaraldehyde 50% 1,5-Pentanedial 50% 111-30-8 6 E Glycerol 1,2,3-Propanetriol / 1,2,3-Trihydroxypropane 56-81-5 6 E 6 E 6 E Hexane Hexane 110-54-3 0 0 P 1 E 6 E 0 E Hydrazine Hydrazine 65% 302-01-2 1 4 0 6 5 6 Muriatic acid 10% Hydrochloric Acid 10% 7647-01-0 6 6 E 6 E 6 Muriatic acid 37% Hydrochloric Acid 37% 7647-01-0 2 G 6 E 6 E 6 E Hydrogen Fluoride, 48% (aqueous) Hydrofluoric Acid 48% 7664-39-3 1 P 4 E 0 F 2 Hydrogen Peroxide 30% Hydrogen Dioxide 7722-84-1 6 E 6 E 6 N 6 G 5 6 Hydroquinone / Quinol 1,4-Benzenediol / 1,4-Dihydroxybenzene 123-31-9 6 E 6 E 6 E 6 Isobutanol 2-Methylpropanol 78-83-1 0 1 0 P 6 E 1 1 Isopropanol Propan-2-ol / 2-Propanol 67-63-0 0 E 3 E 1 E 6 E 0 4 Jeffamine 4,4-Diamino phenyl methane 101-77-9 6 G 6 E 6 E Kerosene Coal Oil 8008-20-6 3 P 6 E 6 E 2 5 Lactic Acid 2-Hydroxypropionic acid 50-21-5 6 6 6 Lauric Acid (30% in Ethanol) Dodecanoic acid (30% in ethanol) 143-07-7 6 6 E 6 E 1 Lubricating Oil 6 F 6 E 6 E Maleic Acid cis-butenedioic acid 110-16-7 6 6 6 5 6 Methyl alcohol Methanol 67-56-1 0 E 1 E 0 G 1 F 2 2 G Methyl Ethyl Ketone Butan-2-one / 2-Butanone 78-93-3 0 0 F 0N 1N Methyl Isobutyl Ketone 4-Methyl-2-pentanone 108-10-1 0 E 1 E 0 N 0 F Methyl Methacrylate 2-Methyl-2-propenoic acid, methyl ester 80-62-6 0 P 1 F 0 N 0 N Methyl Pyrrolidone 1-Methyl-2-pyrrolidone 872-50-4 1 P 2 E 0 N 1 N Methyl t-butyl Ether t-butyl methyl ether 1634-04-4 0 P 4 E 1 E Methylamine 40% Aminomethane 40% 74-89-5 2 6 E 6 E 4 Mineral Spirits (rule 66) 64475-85-0 3 G 6 E 4 Aqua Fortis / Hydrogen nitrate 70% Nitric Acid (70%) 7697-37-2 5 F 0 P 0 P 5 Aqua Fortis / Hydrogen nitrate 10% Nitric Acid 10% 7697-37-2 6 6 6 6 5 6 Nonionic Surfactant 6 E 6 E 6 E Octyl alcohol 1-Octanol 111-87-5 2 5 E 6 E 0 5 Oleic Acid 98% 9-Octadecanoic acid 98% 112-80-1 6 6 E 6 E 3 Oxalic Acid Ethanedioic acid 6153-56-6 6 6 6 Pentachlorophenol / PCP Pentachlorohydroxybenzene 87-86-5 6 E 4 Perchloric Acid 60% Hydronium perchlorate 7601-90-3 6 6 6 Perchloroethylene Tetrachloroethylene 127-18-4 0 E 0 E 4 F 0 F Petroleum Ether Naptha (VM&P) 8032-32-4 0 P 2 G 6 E 4 0 E Carbolic Acid Phenol 108-95-2 3 0N 0N 2 3 Carbolic Acid 7% Phenol 7% 108-95-2 1 E 4 E 4 F Carbolic Acid 80% Phenol 80% 108-95-2 1 F 3 G 2 F Orthophosphoric Acid 85% Phosphoric Acid 85% 7664-38-2 6 E 6 6 E 6 E 5 6 Picric acid 2,4,6-Trinitrophenol 88-89-1 1 E 3 G 4 G 2 Potassium Hydroxide Potassium Hydroxide 45% 1310-58-3 6 E 6 E 6 E 6 E 6

Common Names IUPAC Names CAS (Chemical Abstracts Service Registry No) Disposable Natural Rubber Unsup. Natural Rubber Propanol Propanol 71-23-8 0 E 2 E 1 P 6 G Pyridine Pyridine 110-86-1 0 P 1 F 0 N Soda ash, carbonic acid Sodium Carbonate 497-19-8 6 E 6 E 6 E Table Salt Sodium Chloride 7647-14-5 6 E 6 E 6 E Caustic soda, 10% Sodium Hydroxide 10% 1310-73-2 6 6 5 6 6 Caustic soda, 50% Sodium Hydroxide 50% 1310-73-2 6 E 6 E 6 E 6 E 5 6 5 E Bleach Sodium Hypochlorite 7681-52-9 6 E 6 E 6 E Bleach Sodium Hypochlorite 4-6% 7681-52-9 6 E 6 E 6E Stoddard Solvent / White spirit Naphtha with 10-15% aromatics (bp 150-200ºC) 8002-41-3 0 P 6 E 6 E 2 5 Battery Acid Sulphuric Acid 50% 7664-93-9 6 E 6 E 6 E 6 E 6 E Oleum Sulphuric Acid 98% 8014-96-7 4 F 0 P 3 P 0 4 3 E Tannic Acid 65% Gallotannic acid / Gallotannin 1401-55-4 6 6 6 Tetrahydrofuran 1,4-epoxybutane / butylene oxide 109-99-9 0 N 0 P 0 N Toluene Methylbenzene 108-88-3 0 P 0 N 1 P 0 P Triclene Trichloroethylene 79-01-6 0 N 0 N 0 N Tricresyl Phosphate Phosphoric acid tris (methyl phenyl ester) 1330-78-5 2 1 G 6 E 5 6 TEA / Trolamine / Triethylolamine Triethylolamine 102-71-6 6 6 6 E 6 E 5 6 Turpentine / Gum spirits / Terpene 8006-64-2 0 N 2 N 0 N 2 E Unleaded Petrol 71-43-2 0 P 6 G Xylene Dimethyl benzene 1330-20-7 0 P 0 N 2 P 1 P

VITOCHEM Examples of chemicals for which Vitochem is recommended: Class Chemical DURAPRENE III Examples of chemicals for which Duraprene III is recommended: Class Chemical Aromatic Compounds Chlorinated Solvents Alcohols Mineral / Inorganic Acids Cyclic Compounds Alkalis Fuels Phenols Xylene Perchloroethylene Carbon Tetrachloride Chloroform Dichloromethane Butanol Methanol Isopropanol Hydrochloric Acid Nitric Acid Sulphuric Acid Cyclohexane Ammonium Hydroxide Diesel Alkali Ammonium hydroxide Sodium hydroxide (50%) Sodium hypochlorite Potassium hydroxide Mineral/inorganic acids Sulphuric acid (50%) Hydrochloric acid (37%) Chromic acid (50%) Phosphoric acid (85%) Nitric acid (70%) Perchloric acid Organic acids Lauric acid Acetic acid Maleic acid Citric acid Tannic acid Alcohols Ethylene glycol Isopropanol Isobutanol Octyl alcohol Propanol BUTOCHEM Examples of chemicals for which Butochem is recommended: Class Ketones Nitriles Esters Amides Alcohols Mineral / Inorganic Acids Alkalis Chemical Acetone Methyl Ethyl Ketone Methyl Isobutyl Ketone Acetonitrile Ethyl Acetate Dimethylformamide Ethanol Butanol Hydrochloric Acid Nitric Acid Sulphuric Acid Ammonium Hydroxide Amines Ethanolamine Triethanolamine Others Formaldehyde (37%) Propylene glycol monomethyl ether BM Polyco Ltd, Crown Road, Enfield EN1 1TX, UK Polyco sales enquiries Tel: +44 (0) 20 8443 9000 Fax: +44 (0) 20 8443 9009 email: sales@polyco.co.uk www.polyco.co.uk Technical enquiries Tel: +44 (0) 20 8443 9090 Fax: +44 (0) 20 8443 9009 email: technical@polyco.co.uk 1631-I-CV