Polymer products for personal care

derypol Polymer products for personal care We make polymers, we care for the environment Last Revision: September 2015

derypol "We make polymers, we care for the environment" "We make polymers" means that derypol works to detect the market needs and to investigate and develop products. Our concern for the environment has become our main objective. For this reason, we only use processes and products that respect the environment. Our range of products for water treatment is the result of our commitment to innovate and to use advanced technologies for the development of specialized and progressive products. All our products are the fruit of extensive investigation and are made in accordance with the most demanding criteria and quality. * * **

Contents Index 4-5 Opacifiers OPM Series OPM504 OPM544 6-11 Conditioners DER Series DER K228 DER K228PF DER K327 DER BCA42PF DER BCA35PF DER K2 DER K2PF DER K6 DER K11 DER K11PF DER K39PF 12-21 Rheology Modifiers Himosap & HYgel Series HIMOSAP GAS100 HYGEL CL1700 HYGEL LE766 HYGEL LE585 HYGEL LE755 HYGEL LE305 HYGEL E375C HYGEL E900 HYGEL E100FD 22-23 Styling Agent HYfix Series HYfix CX414 24-26 Biocides Derycide Series DERYDICE CD100BR DERYDICE CD48 DERYDICE CD42

Opacifiers 4 OPM 504 & OPM 544 The objective of an opacifier is to improve the appearance of the product, even if colouring compounds are used in its formulation. + 0.5% OPM 544 To get the most effective blend of the opacifier we recommend a previous dilution of the OPM product with water in a proportion of 1:5 or 1:10, and to dilute with between 10% and 20% in an intermediary phase of the addition of the products. The recommended doses are usually within the range of 0.2 1% depending on each particular case. Our OPM series are used in a wide range of products in cosmetics and detergency as Sunlight protection products, bath gels, hand soaps, face cleaning creams, shampoos, hair treatment creams and others. Estability Our OPM series guarantees a good opacifying capacity and good stability in a wide range of products formulations; however it is mandatory to check this compatibility at laboratory scale prior to progressing to industrial scale. Derypol has an equipped laboratory and expert staff for this testing in order to check formulation stabilities. These are the conditions to which the opacified formulations are submitted: Stability Test Control: 4 weeks of stove 45 ºC. Centrifugation (special cases).

OPM Series derypol 5 Specifications OPM 504 OPM 544 Appearance White milky White milky Solids 40% 40% ph 2,1 3,5 2. 3.5 Viscosity <100 cps < 100 cps Density 1.04 gr/cc aprox 1.04 gr/cc aprox Surfactants Anionic Nonylphenol free Anionic Nonylphenol free Particle Size 150-350 nm 150-350 nm INCI Styrene / Acrylates copolymer

Conditioners 6 DER K228, DER K228PF & DER K327 INCI: POLYQUATERNIUM 7 Compatible with most components of cosmetic formulations, as well as with most cationic, no ionic, anionic and amphoteric surfactants. Transparent and colourless cosmetic products. Substantively properties to skin and hair. The new DER K228PF does not contain parabens. The preservative used as an alternative is sodium benzoate. In Skin Care products: - Imparts a smooth, velvety feel and reduces tightness after drying skin. - Improves foam for liquid cleansing and liquid soaps. - Provides an excellent moisturization. In Hair Care products: - Provides a luster and a soft silky feel. Reduce static and flyaway. Increase Shine, softness and body. - Excellent lubricity and sang-free wet compatibility. - Imparts excellent dry compatibility when the hair is dried. Improve wet and dry combability. - Helps hold curl without flaking. DER BCA42PF & DER BCA35PF INCI: POLYQUATERNIUM 22 Compatible with most components of cosmetic formulations, as well as with most cationic, no ionic, anionic and amphoteric surfactants. Substantively properties to skin and hair (PQ22 is mainly used in hair care formulations due to its high cationicity). Both products are parabens free. The preservative used as an alternative is sodium benzoate. In Skin Care products: - Imparts a smooth, velvety feel and reduces tightness after drying skin. - Improves foam for liquid cleansing and liquid soaps. - Provides an excellent moisturization. In Hair Care products: - Provides a luster and a soft silky feel. - Excellent lubricity and sang-free wet compatibility. - Imparts excellent dry compatibility when the hair is dried. - Helps hold curl without flaking.

DER Series 7 DER K2, DER K2PF & DER K6 INCI: POLYQUATERNIUM 6 100% cationic. High substantive power. Full compatibility with non-ionic and amphoteric ingredients. It imparts a smooth and velvety touch on the skin contributing greatly to maintain a maximum degree of hydration. Easy to dosage due to its solubility in water. DER K6 is a very high molecular weigh polymer. In Skin Care products: - Provides a luster and a soft silky feel. - Give to the skin a soft, velvety and non greasy after feel. - Improves the spreadability and the application of the final product. In Hair Care products: - Conditioning shampoos, blow-dry lotions, leave on or rinse off conditioners, hair relaxer creams. - Provides a luster and a soft silky feel. - Reduce Static and flyaway effect. - Increase Shine, softness and body. - Improving wet and dry combability. - Improves the spread ability and the application of the final product. - Strong conditioning effect, both products are mainly used in Afro-American products, damaged hair products and tightly curly hair. DER K11 & DER K11PF INCI: POLYQUATERNIUM 11 Easy incorporation in formulations due to complete water solubility. Compatible with a wide range of surfactants, including anionic and amphoteric ones. Compatibility with ethanol for hair formulations (musses and sprays). Acts as an antistatic agent, film former and hair fixative. Conditioner for styling gels. Hair Care; It can be formulated into styling mousses, lotions and gels, conditioners, transparent shampoos and treatment products. Improve wet and dry combability. Increase Shine, softness and body. Good curl retention. Form a non-tacky and continuous film. Suitable for Skin care products; liquid soaps, shower gels, body lotions and shaving products.

Conditioners 8 DER K39PF INCI: POLYQUATERNIUM 39 Amphoteric terpolymer suited for liquid cleansing products. Compatible with anionic and amphoteric surfactants. For hair care products, it provides really good dry and wet combing properties. Preserved with Sodium Benzoate as an alternative to parabens. In Hair care products: - Excellent lubricity and slip, excellent wet combability without too much build-up. - Provides sheen to dry hair. - Excellent dry combability. - Superior conditioning properties for products with extreme ph ranges. In Skin care products: - Contributes lubricity, which makes their application easier. - Reduces tightness of drying skin, and provides a smooth feel. - Excellent moisturization - Helps to reduce irritation resulting from liquid cleansers. - Liquid cleansers obtain a richer, thicker foam with better stability.

DER Series 9 Specifications ph Viscosity Solids Components INCI DER K228 6 7.5 7.500 15.000 8.5 10% DER K228PF 3 4.5 7.500 15.000 8 10% DER K327 6-7.5 7.500 15.000 18.5 20% DER BCA42PF 4-6 3.000 6.000 39 43% DER BCA35PF 2.5 4.000 15.000 39 43% DER K2 5-7 5.000 12.000 39 41% AAM DADMAC AAC DADMAC Polyquaternium - 7 Polyquaternium - 22 DER K2PF 5-7 5.000-12.000 40% DADMAC Polyquaternium - 6 DER K6 4-7 2.000 15.000 19 21% DER K11 5-7 10.000-50000 19 22% DMAEMA Polyquaternium - 11 DER K11PF 3-5 10.000-60.000 19-22% DMAEMA Polyquaternium - 11 DER K39PF 5.5-7 5500-16000 < 15% AAC AAM DADMAC Polyquaternium - 39 DADMAC: Diallyldimethylammonium Chloride AAC: Acrylic Acid AAM: Acrylamide

Rehology Modifiers 10 Classification Water based Aqueous emulsion Emulsion Powder Himosap GAS100 HYgel CL1700 HYgel LE585 HYgel LE755 HYgel LE766 HYgel LE305 HYgel LE375C HYgel E900 HYgelE100FD Himosap Series (Exclusive Derypol s Technology) HIMOSAP GAS 100 INCI: Acrylamide / Sodium acryloyldimethyltaurate / Acrylic acid copolymer in aqueous dispersion with ammonium and sodium sulphate Are well known polymers but in aqueous presentation form. Water dispersion polymers are not known in the cosmetic market thereby Himosap are special products and they work in a different way than others solids, emulsions or latex products. Advantages of Himosap products: Aqueous dispersion free of oils, solvents and surfactants. Water based polymers that permits a very easy preparation. Immediately dissolutions. Excellent salt tolerant, even better than other products in the market. Provides aqueous transparent solutions. Viscosity recovered after boiling it. Stable with polar solvents (glycolic acid, sorbitol, glycerine, propylenglicol ). ph independent.

Viscosidad (cps), 4@0.6 rpm Himosap Series (Exclusive Deryol s Technology) 11 HIMOSAP GAS 100 Cross-linked copolymer with anionic content at 20% of actives. ph independent. Doesn t need neutralization before using it. High molecular weight. The polymer thickens in all the ph range, even acid ph. Compatible with non-ionic surfactants. GAS100 is recommended for transparent gel formulations as: Aloe Vera, anti-cellulite gels, hot and cold effect gels, depilatories, peelings, water hairstyle, etc Thickening ability at different ph Thickening ability at different concentrations of NaCl 1000000 1000000 100000 10000 1000 100 0 2 4 6 8 10 ph T 100000 L V ld m 10000 k fie rp o.5 ro 1 B ) @ 1000 s 4 p (c le d ity in 100 s p s o c Emulsion product, 4,4% is commercial product V 10 HIMOSAP GAS 100, 10% commercial product 1 0 0,2 0,4 0,6 0,8 1 1,2 % NaCl

Rehology Modifiers 12 Specifications GAS 100 Appearance White milky Liquid Actives 20% Density 1.2 Product Viscosity Ionic character < 3.000 cps Anionic INCI Acrylamide/sodium acryloyl-dimethyltaurate/acrylic acid copolymer Compatibilities and Incompatibilities Compatibilities Water Sorbitol 50% : Water 50% Glycerine 50% : Water 50% Sodium Lauryl ether sulfate Hydrogen peroxide Incompatibilities Propylene glycol 50% : Water 50% Ethanol 10% : Water 90% Sodium Chloride Non-ionic surfactants Glicolic acid Ionic surfactants

HYgel Series 13 Hygel Series Aqueous Emulsion HYgel CL1700 INCI: ACRYLATES COPOLYMER Polymer of acrylic monomers in aqueous emulsion with a high suspending ability. Anionic rheology modifier which provides clear formulations which contains high level of surfactants Compatible with electrolytes and surfactants (non-ionic, anionic and amphoteric surfactants). Solutions are pseudoplastic and non thixotropic. Neutralization at ph7. Wide ph range, ph can be reduced with Citric Acid. It is compatible with most of the more common surfactants used in personal care: - Sodium Lauryl Sulfate - Sodium Laureth Sulfate - Cocamidopropyl Betaine - Sodium lauroyl sarcosinate - Disodium Laureth Sulfosuccinate It is usually used on clear shampoos, bath gels and 2 in 1 conditioning shampoos. Antidandruff shampoos. Baby shampoos. Facial Cleanesers. Conditioning body washes. Sanitizing gels. Low ph formulations. Pearlized Cleanising Products.

Rehology Modifiers 14 Specifications Nature HYgel CL 1700 White milky Liquid Viscosity (in solution) 1%: 300-400 Viscosity (commercial product) < 100 cps Acitve Content 30% Shelf Life 6 months ph 2 5* (Solution 1%) INCI Acrylates Copolymer Factor When factor is Suspending and viscosity properties Polymer concentration Added/Increased Increase Surfactant concentration: Sodium Lauryl Sulfate Sodium Laureth Sulfate Cocamidopropyl Betaine Sodium lauroyl sarcosinate Disodium Laureth Sulfosuccinate Increased Increase Salt Added / Increased Increase

HYgel Series 15 Emulsion HYgel LE766 INCI: Sodium Polyacrylate, Hydrogenate Polydecene, Trideceth - 6 It is an anionic acrylic copolymer dispersed in Hidrogenated Polydecene as an alternative to mineral oil, and does not contain acrylamide. It is normally used to thicken aqueous solutions and to stabilize O/W emulsions. It is pseudoplastic and non thixotropic. Its solutions do not show significant changes in viscosity and stability at high temperature. LE766 helps to stabilise suspensions. It is supplied in ready to use form, so it is no necessary neutralization. The addition can be made at any stage of the manufacturing process (at room temperature). Compatible with surfactants. HYgel LE585 & LE755 INCI LE585: Acrylamide/Sodium Acrylate Copolymer Mineral Oil, Trideceth - 6 INCI LE755: Sodium Polyacrylate Mineral Oil, Trideceth - 6 Anionic acrylic copolymer dispersed in medicinal grade white oil. Those polymers are tipically used to thicken aqueous solutions and to formulate stable O/W emulsions. The polymers swell immediately in water without any neutralisation, and at room temperature. Solutions are pseudoplastic and non thixotropic. Suspension of solid particles (only the LE585) Compatible with surfactants. Make up and sun screen formulations with a non greasy and non sticky after feel. Rub-in and spreadability of highly thick and compact creams are easier and more uniform. Cream-like gels (light textures white glossy products) Serums. Sensitive creams and baby care. Cleansing lotions and creams (compatibility with surfactants) Nail varnish remover. High ph formulations: depilatory creams, perm lotions Hydroalcoholic gels.

Rehology Modifiers 16 HYgel LE305 INCI: Polyacrilamide & C13-14 Isoparaffin & Laureth-7 LE305 is An anionic thickening and stabilizing agent ready to use as a fluid inverse emulsion. It has emulsifying properties with oil phases, providing gel-cream texture. HYGEL LE305 thickens extreme media (highly acidic, highly alkaline or oxidizing) and stabilizes mineral additives. This is a ready to use polymer which swells immediately in water at room temperature and without any neutralization. LE305 allows allows the formulation of highly stable suspensions under a wide range of ph (from 2 to 11). In Hair care products: - Creams, lotions, - Sun Care (sunscreens, self-tanning creams, ) - Hair Care - Make up HYgel LE375C INCI: Polyquaternium 37 Mineral Oil, Trideceth - 6 It is a cationic acrylic copolymer dispersed in medicinal grade white oil. Normally used to thicken cationic aqueous solutions and to stabilize O/W emulsions. It is supplied in ready to use form, so neutralization is no necessary. It swells immediately in water at room temperature. Solutions are pseudoplastic and non thixotropic. LE375C helps to stabilise suspensions. Formulations that contain cationic ingredients. Make up and sun screen formulations with a non greasy and non sticky after feel. Self-tanning emulsions. Sunscreen. Skin care with AHA, acid fruits, DHA Hair care: after-shampoos (conditioning effect)

HYgel Series 17 Specifications HYgel LE 766 HYgel LE305 HYgel LE 585 HYgel LE 755 HYgel LE 375C Character Anionic Anionic Anionic Anionic Cationic Nature White milky Translucent Emulsion White milky White milky White milky Odor Slightly acetic Slyghtly acrylic Slightly acetic Slightly acetic Slightly acetic Viscosity (in solution) Viscosity (prod. Cial.) Acitve Content 1%: 15000-25000 cps 2%: 18000 32000 cps 1%: 20000-32000 cps 1%: 15000-25000 cps 2%: 25000-45000 cps 400 2000 cps 1500 5500 cps <1500 cps 400-2000 cps 200-3000 cps 57.5%* 45 55 % 57.5%* 57.5%* 53 %* Shelf Life 12 months 12 months 12 months 12 months 12 months ph INCI 5-7 (Solution 1%) Sodium Polyacrylate, Hydrogenate Polydecene, Trideceth - 6 4 5.5 (Solution 1%) Polyacrilamide & C13-14 Isoparaffin & Laureth-7 5 7 (Solution 1%) Acrylamide/Sodium Acrylate Copolymer 5 7 (Solution 2%) Sodium Polyacrylate 3.5 5 (Solution 2%) Polyquaternium 37 Mineral Oil (Paraffinum Liquidum), Trideceth - 6

Rehology Modifiers 18 HYgel E900 INCI: Carbomer Powder Acrylic-based polymer in powder form, typically used to formulate transparent gels. Thickening agent for aqueous solutions. Solutions are pseudoplastic and non thixotropic. The polymer does not show significant changes in viscosity and stability at high temperature. It has a high yield value. So it is an effective agent for emulsion stabilization and stable suspension of solid particles. Has a very high yield value, so it is an effective agent for emulsion stabilization and stable. It used in hair care and skin care products, for gel, lotion and cream formulation. Hydro-alcoholic gels.

HYgel Series 19 HYgel E100FD (Fast Dispersion Version) INCI: Carbomer Acrylic-based polymer in powder form, typically used to formulate transparent gels. HYgel E100FD is an optimized grade of Carbomer with better clarity, handling and less foam. Thickening agent for aqueous solutions. Solutions are pseudoplastic and non thixotropic. It has a high yield value. So it is an effective agent for emulsion stabilization and stable suspension of solid particles. Has a very high yield value, so it is an effective agent for emulsion stabilization and stable. It used in hair care and skin care products, for gel, lotion and cream formulation. Hidro-alcoholic gels. Specifications HYgel E900 Hygel E100 FD Nature White granulated powder White granulated powder Odor Slightly acetic Slightly acetic Size of particle 5 µm 5 µm Water content 5 % max 5 % max Viscosity (in solution) 0.2%: 20000-30000 cps 0.5%: 45000-65000 cps 0.2%: 20000-30000 cps 0.5%: 50000-65000 cps Solvent residual 1000 ppm max 1000 ppm max Shelf Life 24 months 24 months ph 2,7 3,5 (0,5% solution) 2,7 3,5 (0,5% solution) INCI Carbomer Carbomer

Styling Agents 20 HYfix CX414 INCI: Methacrylic Acid/Sodium Acrylamidomethyl Propane Sulfonate Copolymer Anionic copolymers in aqueous solution for applications in hair and skin products. Easy incorporation into formulations without heating and without neutralization. Is recommended a previous dilution to obtain better results. It provides transparent forumlations. In Hair Care Products: - Adapted for styling gels, waxes, Creams,.. - Helps to provide high curl retention in a high humidity environment. - Contributes to a silky, dry hair feel. - Washes out easily. - Curl retantion. - It does not leave White particles once dryed - Suggested strarting concentration in Styling: 5% as supplied. - Suggested strarting concentration in Shampoos: 1.5% as supplied. In skin Care Products: - Lotions, Liquid cleanising Products, Shaving, moisturing creams. - Enhances skin smoothness. - Improve spreadibility of lotions and creams. - Suggested strarting concentration in Skin Care: 1.5% as supplied.

HYfix Series 21 Specifications HYfix CX414 Appearance Odor Liquid, viscous, colorless, hazy Without scent Colour, APHA 50 Ionic character Anionic Solids % 10.5 13.1 ph 5-7 Viscosity 5000 15.000 cps Intrinsec Viscosity 3,5 4,5 INCI Methacrylic Acid/Sodium Acrylamidomethyl Propane Sulfonate Copolymer

Biocides 22 Derycide CD100BR INCI: 2-Bromo-2-Nitropropane-1,3-Diol It is a biocide resulting from the active brominated in solid form. It possesses a high activity against gram-positive and gram-negative bacteria, fungi and yeast. Biocide with a wide range of effectiveness against bacteria and fungi. It may be used as it is or previously diluted in water. The dosage will vary depending on the characteristics and requirements of the composition to preserve. Usually, though, it is within the range 0.01 0.02%. CD100BR is mainly used as a preserving agent in formulations of liquid detergents, softeners, home-cleaning detergents and cosmetic products as shampoos. In general it may be useful in almost any kind of aqueous emulsion. Derycide CD48 INCI: phenoxyethanol + methylisotiazolona + propylene glycol Biocide compatible with most of the ingredients used in cosmetic formulations including surfactants, emulsifiers and zinc piritione. Is recommended a Challenge Test before its homologation. CD48 is mainly used as a preserving agent in formulations of liquid detergents, softeners, home-cleaning detergents and cosmetic products as shampoos. In general it may be useful in almost any kind of aqueous emulsion. Derycide CD42 INCI: Methylchloroisothiazolinone Methylisothiazolinone Biocide Blend of chloride and methyl isothiazolones (CMI/MI) stabilised in aqueous solution. It has a high activity against gram-positive and gram-negative bacteria, fungi and yeast. It may be added at any time during the manufacturing process. A high level of agitation and mixing is required to allow the product to homogenise within the composition. The ph of the formulation should not be higher than ph 8. CD42 is mainly used as a preserving agent in formulations of liquid detergents, softeners, home-cleaning detergents and cosmetic products as shampoos. In general it may be useful in almost any kind of aqueous emulsion.

Derycide Series 23 Specifications Derycide CD100BR Derycide CD48 Derycide CD42 Appearance White Powder Transpratent Yellowish Liquid Transparent liquid Actives (%, p/p) 99 mín. - 1.5 Moisture (%, p/p) 0.5 max. - - Density (20ºC) Aprox. 1.2 gr/cc 1,10 ±0,02 g/cc 1.07 1.11 gr/cc ph (20ºC) 5.7 (sol.1%) 3 5 2 4 Ashes sulphates) (%, p/p) 0.5 max. - n.a. Solubility Soluble in water Soluble in water, glicerine and propylene glycol Soluble in water and glycol at 20 ºC Odor Characteristic - Smooth, slightly spicy INCI 2-Bromo-2-Nitropropane-1,3- Diol phenoxyethanol + methylisotiazolona + propylene glycol Methylchloroisothiazolinone Methylisothiazolinone

PRODUCT APPLICATIONS / INCI NAME Product Type Product Name INCI Opacifier Opacifier Conditioner Conditioner Conditioner Conditioner Conditioner Conditioner Conditioner Conditioner OPM504 OPM544 DER K228 DER K228PF DER K327 DER BCA42PF DER BCA35PF DER K2 DER K2PF DER K6 Styrene / acrylates copolymer Polyquaternium - 7 Polyquaternium - 22 Polyquaternium - 6 Conditioner DER K11 Polyquaternium - 11 Conditioner DER K11PF Polyquaternium - 11 Conditioner DER K39PF Polyquaternium - 39 Rheology modifier GAS100 Copolymer of acrylic acid, 2-propenamide and sodium acryloyldimethyltaurate in aqueous dispersion with ammonium and sodium sulfate. Rheology modifier HYgel CL1700 Acrylates Copolymer Rheology modifier Rheology modifier Rheology modifier Rheology modifier Rheology modifier Rheology modifier Rheology modifier Styling Agent HYgel LE766 HYgel LE585 HYgel LE755 HYgel LE305 HYgel LE375 C HYgel E900 HYgel E100FD HYfix CX414 Sodium Polyacrylate / Hydrogenate Polydecene / Trideceth-6 Acrylamide / Sodium Acrylate Copolymer / Mineral Oil (Paraffinum Liquidum), Trideceth - 6 Sodium Polyacrylate /Mineral Oil (Paraffinum Liquidum), Trideceth - 6 Polyacrylamide & C13-14 Isoparaffin & Laureth-7 Polyquaternium 37/ Mineral Oil (Paraffinum Liquidum), Trideceth - 6 Carbomer Methacrylic Acid/Sodium Acrylamidomethyl Propane Sulfonate Copolymer. Biocide Derycide CD100BR 2-Bromo-2-Nitropropane- 1,3-Diol Biocide Derycide CD48 phenoxyethanol + methylisotiazolona + propylene glycol Biocide Derycide CD42 Methylchloroisothiazolinone Methylisothiazolinone

derypol We are working hard everyday to be able to offer new discoveries so that may: - Improve our customers water quality. - Reach more profitable and sustainable treatments. - Adapt ourselves to the new government demands. - Contribute to the effort of keeping our planet blue. Our range of products, reflective of our beliefs, is continuously evolving, because we focus our efforts specially on finding new chemicals. Our success is due to our partners, colleagues and customers, and to their spirit of innovation. We understand that our strength is in our research and development of practical application, as well as our focus on meeting the needs of our clients. To discover means that we have a great ability to adapt to the needs of the market and customers, thanks to an organization that works with dynamism, creativity, effort, and overall with illusion. We make polymers, we care for the environment.

Derypol, S.A. Offices: C/ Plató, Nº 6 Entlo. 5º Tel. +34 93 238 90 90, Fax +34 93238 90 91 08021 Barcelona (Spain) mail: info@derypol.com Factory and Laboratories: C/de Cal Gabatx, s/n. Tel. +34 93 849 61 88 Fax +34 93 846 41 93 08520 Les Franqueses del Vallès Barcelona - Spain www.derypol.com derypol