TECHNICAL REPORT HOLLOW POLYCARBONATE



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Transcription:

TECHNICAL REPORT HOLLOW POLYCARBONATE

A Brief Introduction Polycarbonate is a very well-known engineering thermoplastic, as clear as glass and as resistant as steel, it is a carbon derivative that gathers a high level of mechanical resistance quality, as well as optical, thermal and electric. It useful in many different engineering applications, because of its high versatility, either on flat or curved situations. It was discovered in Europe in the early 50 s and its commercial production started in the late 50 s.

CHEMICAL COMPABILITY Normally do not cause problems at low concentrations and room Alkalis Acids Alcohols Amines Ketones Detergents and Cleaning materials temperature. High temperatures and/or higher concentration will harm the material. Do not attack the material at normal temperatures and concentrations. Normally do not cause problems at low concentrations and room temperature. High temperatures and/or higher concentration will harm the material. Chemical attack will occur. Avoid this material. They are solvents. Avoid solvents. Neutral solutions of soap and detergents are applicable. Avoid too high ph material. Esthers Hydrocarbons Aliphatic Hydrocarbons Alifáticos Halogenated Hydrocarbons Silicon oil and grease Avoid. Partially solvents to Polycarbonate. Can cause blisters to the surface. Can be partially solvent to the material causing stress cracking. Avoid. Usually compatible with the product. They are solvents. Avoid. Normally compatible up to 85 o C. Some may contain aromatic hydrocarbons and therefore one should avoid them. Oil and greases Oil and greases coming from petroleum are generally compatible. Some additives they contain are not compatible.

Hollow Polycarbonate It is a flat sheet with an internal hollow cavity, between two external walls, that restrains the heat exchange from one side to the other, preserving the temperature of the internal area. The impact resistance is far better than glass, about 30 times bigger, and the sheet can be bent without heating being able to stand a bending radio of minimum 175 times its thickness. Hollow Polycarbonate sheets have good performance in temperatures ranging from minus 40 C up to 120 C. In one of its side, a treatment prevents the damage to the material by the ultra-violet rays, especially from the sun. The material is self-extinguishing and do not propagate fire. By selecting the correct thickness, one can regulate the structure to be used. By using colored sheets, one can regulate the quantity of light and heat coming into the ambient. Special length dimension makes it easier to use less emendation, what avoids easier points for infiltration. Hollow Polycarbonate is used in general coverage, side closing and sheds, fair booths, winter gardens, metro stations, sports stadiums, industrial covering, domes, footbridge, etc. enhancing the natural lightning of the ambient. Comparison of weight of Polycarbonate with other material Material Thickness (mm) Weight (kgf/m²) Solid Acrylic Sheet 6 7,2 GRP sheet (Polyester) 1,5 2,3 Solid PVC Sheet 6 8 Hollow Polycarbonate 6 1,3 Wired Glass 6 16

Hollow Polycarbonate Thickness Weight 4 mm 0,8 kg/m² 6 mm 1,3 kg/m² 8 mm 1,5 kg/m² 10 mm 1,7 kg/m² 16 mm 2,7 kg/m²

OPTICAL AND THERMAL CHARACTERISTICS Thick Light Trans. Solar Direct Solar Total Solar (mm) Trans Solar Reflect. Color Solar Shadow Transm. Reflect. Adsorpt. Coefic. SC DST (%) RST (%) AS (%) TL (%) TST (%) RS (%) Blue 6 27 55 40 45 30 30 0,63 8 10 27 55 40 45 20 30 0,63 16 27 55 Bronze 6 35 55 40 45 30 30 0,63 8 35 55 40 45 30 30 0,63 10 35 55 40 45 20 30 0,63 16 35 55 Gray 6 20 50 33 50 4 63 0,58 8 10 20 50 33 50 4 63 0,58 16 20 50 Clear 6 82 86 79 14 7 14 0,98 8 82 86 79 14 7 14 0,96 10 81 85 79 15 9 12 0,89 16 79 82 Smoky 6 40 76 65 24 13 22 0,66 8 40 75 65 25 15 0 0,66 10 40 71 65 29 23 12 0,66 16 40 71 Green 6 62 60 40 40 30 30 0,69 8 65 60 40 40 30 30 0,69 10 68 60 40 40 20 30 0,69 16 68 60

TRANSMISSION OF LIGHT AND ENERGY Thicknesses Transmission values % Visible light Solar energy 6 mm 83 88 8 mm 82 86 10 mm 80 85 CHARACTERISTICS 74 82

GENERAL CHARACTERISTICS Thermal 6 mm 8 mm 10 mm 16 mm K Factor (w/m². O k) 3,5 3,3 3 2,4 Heat gain in summer (BTU/H-m². C) 0,62 0,59 0,57 0,52 Heat loss in winter (BTU/H-m². C) 0,65 0,62 0,6 0,55 Temperature of application ( C) De -40 C a 100 C Deformation temperature ( C) 140 C Tensile strength as a function of temperature 80 Mpa = -2,5 C 70 Mpa = 0 C 65 Mpa = 25 C 59 Mpa = 50 C Flexural modulus as a function of temperature 26 Mpa = -2,5 C 25,5 Mpa = 0 C 25 Mpa = 25 C 23 Mpa = 50 C Breaking Temperature '-110 Thermal conductivity 0,21 W/m. C Thermal expansion coef-ficient 7 x 10 -⁵ m/m. C Oxygen Index 25% FLAMABILITY 6 mm 8 mm 10 mm 16 mm Horizontal burn (flame propagation speed) AEB (mm) ASTM D 635 CC-2 Ignition Temperature - spark Self-Ignition Temperature ASTM D-1929B ASTM D1929B 471 C - - 585 C 582 C

Direct Resistance to Chemicals CHEMICAL RESISTANCE Acetylene Butane Hexane Good Resistance Chromic Acid Potassium carbonate Calcium Hypochlorite Acetic Acid Sodium Carbonate Sodium Hypochlorite Arsenic Acid Aluminum Chloride Mercurium Citric Acid Ammonium Chloride Methane Hydrochloric Acid, 20% Antimony Chloride Carbon Monoxide Hydrochloric Acid, 5% Calcium Chloride Ammonium Nitrate Sulfuric Acid, 50% Calcium Chloride Calcium Nitrate Lactic Acid Cupric Chloride Aluminum Oxalate Nitric Acid, 10% Cuprous Chloride Phosphorous Oxide Oleic Acid Ferric Chloride Oxygen Oxalic Acid Magnesium Chloride Ozone Per chloric Acid Mercurium Chloride Pentane Per chloric Acid, 20% Potassium Chloride Calcium soap Tartaric Acid, 20% Sodium Chlorate Sodium Hydroxide Water Sodium Chloride Resorcinol, 1% Butyl Alcohol Zinc Chloride Calcium Chloride sol. Ethanol 96% Hydrogen Peroxide Sulfates Propyl Alcohol Sulfur Aluminum Sulfate Chrome Alum Ethanol Ammonium Sulfate Alum Dinonyl Phthalate Copper Sulfate Sodium Bicarbonate Formaldehyde, 10% Magnesium Sulfate Potassium dichromate Coal Gas Manganese Sulfate Carbon Dioxide Propane Potassium Sulfate Sodium bisulfate Glycol Sodium Sulfate Sodium Bisulfite Butylene Glycol Ferrous Sulfate Borax Ethylene Glycol Hydrogen Sulfite Boric Acid Diethylene Glycol Potassium Bromide Heptane Urea Allylic Acid Dinonyl Phthalate

Isoamyl Alcohol Trichloric Acid Dry Chlorine Isopropyl Alcohol Sulfuric Acid, 70% Glycerin Limited Resistance Not Resistant Nitric Acid, 10-20% Cyclo hexyl alcohol Calcium Hydroxide 30% Perchloric Acid Tetraethyl lead Kerosene Formic Acid Petroleum Ether Acetone Potassium Cyanide Iodine Amyl Acetate Cyclohexanone Methanol Butyl Acetate Benzyl Chloride Methylamine Nitric Acid,20% Chloroform Methyl Methacrylate Chemical Resistance Resistência Química Butyric Acid Ethyl Chloride Nitrobenzene Hydrochloric Acid, conc. Ethylene Chlorohydrin Perchloretylene Phenilyc Acid Methylene Chloride Pyridine Phenyl Ethyl Alcohol Cresol Sodium Hydrox. sol. Propionic Acid Carbon Disulfide Potassium solution Not Resistant Sulfuric Acid concent. Dimethyl naphthenic Caustic Soda Sulfurous Acid, 10% Dibutyl phthalate Ammonium Sulfate Benzilic Acid Dioxane Phenyl ethyl alcohol Diethyl ether Ethane Tetrachloride Ammonium Ether Tetrahydrofuran Aniline Ethyl amide Tetrahydronaftalen Benzaldehyde Styren Thiofuran Benzene Dimethyl formamide Toluene Benzoic Acid Tricresyl phosphate Trichlorethylene Ethyl Bromide Ammonium Fluoride Phosphor Trichloride Brome Brome Chlorine gas umid Nitrous vapor Brome Benzene Ammonium Hydroxide Xylene Cyano Ethylene Potassium Hydroxide

Cleaning Agents Ethanol Pure Lysoform, 2 % Resorcinol solution Baktol, 5% Maktol Sublimed Good Resistance Limited Resistance Chloramine Mefen, 2% Trosilin G extra, 1,5% Delegol, 5% Oktozon, 1% Hydrogen Peroxide Dimamin T, 5% Iodine Tincture Zephirol Sagrotan, 5% Not Resistant Carbolic Acid DDT TB-Lysorform Pharmaceutical/ Cosmetics Delial Sun Milk Periston blood substit. Vaseline Good Resistance Lanoline Blood Plasma Vick's vapor rub Odol mouthwash Limited Resistant Tincture of Iodine Menthol, 90% in alcohol

Big care was taken in the compilation of the information herein contained. The recommendations about the use of the products are made without guarantee as the using conditions are not controlled by Bérkel. It is responsibility of the customer provide assurance that the product will be appropriate for each situation and that the conditions of its application be adequate. Every information of this publication are reliable and issued on good faith. They were though not intended to be a guarantee and therefore we take no legal responsibilities. The users of polycarbonate sheets should run enough experiments as to establish that the material is appropriate of their real particular cases.