CLASSIFICATION AND LABELLING
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1 CLASSIFICATION AND LABELLING. and labelling according to CLP / GHS Name: cadmium (non-pyrophoric) Implementation: EU State/form of the substance: powder Remarks: cadmium is usually manufactured as massive solid; small quantities produced as non-pyrophoric powder and labelling according to CLP / GHS for physicochemical properties Not classified for physico-chemical properties and labelling according to CLP / GHS for health hazards Acute toxicity - inhalation: Hazard Acute Tox. 2 Reproductive Toxicity: Repr. 2 Germ cell mutagenicity: Muta. 2 Hazard statement H330: Fatal if inhaled. H36: Suspected of damaging fertility or the unborn child <state specific effect if known> <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>. H34: Suspected of causing genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>. Carcinogenicity: Carc. B H350: May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>. Specific target organ toxicity - repeated: STOT Rep. Exp. Affected organs: kidney, lung, bone Route of exposure: Inhalation H372: Causes damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>. and labelling according to CLP / GHS for environmental hazards Hazards to the aquatic environment (acute/short-term): Hazards to the aquatic environment (longterm): M-Factor acute: 0 M-Factor chronic: 0 Hazard Hazard statement Aquatic Acute H400: Very toxic to aquatic life. Aquatic Chronic H40: Very toxic to aquatic life with long lasting effects.
2 Signal word: Danger Hazard pictogram: GHS06: skull and crossbones GHS08: health hazard GHS09: environment Hazard statements: H350: May cause cancer H34: Suspected of causing genetic defects H36: Suspected of damaging fertility or the unborn child (H36fd is exact statement) H330: Fatal if inhaled. H372: Causes damage to Lung, kidney, bone through prolonged or repeated exposure by inhalation. H400: Very toxic to aquatic life. H40: Very toxic to aquatic life with long lasting effects. Precautionary statements: P270: Do not eat, drink or smoke when using this product. P273: Avoid release to the environment. P39: Collect spillage. P28: Use personal protective equipment as required. P405: Store locked up. P308+P33: IF exposed or concerned: Get medical advice/attention. P50: Dispose of contents/container to... (According to local/national waste legislation) Name: cadmium (pyrophoric) Implementation: EU State/form of the substance: powder and labelling according to CLP / GHS for physicochemical properties Hazard Hazard statement Pyrophoric solids: Pyr. Solid H250: Catches fire spontaneously if exposed to air.
3 and labelling according to CLP / GHS for health hazards Acute toxicity - inhalation: Hazard Acute Tox. 2 Reproductive Toxicity: Repr. 2 Germ cell mutagenicity: Muta. 2 Hazard statement H330: Fatal if inhaled. H36: Suspected of damaging fertility or the unborn child <state specific effect if known> <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>. H34: Suspected of causing genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>. Carcinogenicity: Carc. B H350: May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>. Specific target organ toxicity - repeated: STOT Rep. Exp. Affected organs: kidney, lung, bone Route of exposure: Inhalation H372: Causes damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>. and labelling according to CLP / GHS for environmental hazards Hazards to the aquatic environment (acute/short-term): Hazards to the aquatic environment (longterm): M-Factor acute: 0 M-Factor chronic: 0 Hazard Hazard statement Aquatic Acute H400: Very toxic to aquatic life. Aquatic Chronic H40: Very toxic to aquatic life with long lasting effects. Signal word: Danger Hazard pictogram: GHS02: flame GHS06: skull and crossbones GHS08: health hazard
4 GHS09: environment Hazard statements: H250: Catches fire spontaneously if exposed to air. H350: May cause cancer. H34: Suspected of causing genetic defects. H36: Suspected of damaging fertility or the unborn child (exact statement is H36fd) H330: Fatal if inhaled. H372: Causes damage to lung, kidney, bone through prolonged or repeated exposure by inhalation. H400: Very toxic to aquatic life. H40: Very toxic to aquatic life with long lasting effects. Precautionary statements: P273: Avoid release to the environment. P39: Collect spillage. P20: Keep away from heat/sparks/open flames/... /hot surfaces... No smoking. P260: Do not breathe dust/fume/gas/mist/vapours/spray. P28: Use personal protective equipment as required. P308+P33: IF exposed or concerned: Get medical advice/attention. P405: Store locked up. P50: Dispose of contents/container to... (according to local/national waste legislation) Name: cadmium (massive) Implementation: EU State/form of the substance: solid The substance is classified as follows: and labelling according to CLP / GHS for physicochemical properties Not classified for physic-chemical properties and labelling according to CLP / GHS for health hazards Hazard Hazard statement Reason for no classification Reproductive Toxicity: Germ cell mutagenicity: Carcinogenicity: Specific target organ toxicity - repeated:
5 and labelling according to CLP / GHS for environmental hazards Hazards to the aquatic environment (acute/short-term): Hazards to the aquatic environment (longterm): M-Factor acute: M-Factor chronic: 0 Hazard Hazard statement Aquatic Acute H400: Very toxic to aquatic life. Aquatic Chronic H40: Very toxic to aquatic life with long lasting effects. Signal word: Warning Hazard pictogram: GHS09: environment Hazard statements: H400: Very toxic to aquatic life. H40: Very toxic to aquatic life with long lasting effects. Precautionary statements: P273: Avoid release to the environment. P39: Collect spillage. P50: Dispose of contents/container to and labelling according to DSD / DPD 2.. and labelling in Annex I of Directive 67/548/EEC Chemical name: cadmium (non-pyrophoric) and labelling in Annex I of Directive 67/548/EEC for physicochemical properties Not classified for physic-chemical properties and labelling in Annex I of Directive 67/548/EEC for health hazards Acute toxicity: Repeated dose toxicity: Carcinogenicity: Mutagenicity - Genetic Toxicity: Toxicity to reproduction - fertility: Toxicity to reproduction - T+; R26 Very toxic by inhalation. T; R48/23/25 Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed. Carc. Cat. 2; R45 May cause cancer. Muta. Cat. 3; R68 Possible risk of irreversible effects. Repr. Cat. 3; R62 Possible risk of impaired fertility Repr. Cat. 3; R63 Possible risk of harm to the unborn child.
6 development: and labelling in Annex I of Directive 67/548/EEC for the environment Environment: N; R50/53 Dangerous for the environment; Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Indication of danger: T+ - very toxic N - dangerous for the environment R-phrases: R45 - May cause cancer R26 - Very toxic by inhalation R48/23/25 - Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed R62 - Possible risk of impaired fertility R63 - Possible risk of harm to the unborn child R68 - Possible risk of irreversible effects R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment S-phrases: S53 - avoid exposure - obtain special instructions before use S45 - in case of accident or if you feel unwell, seek medical advice immediately (show the label where possible) S60 - this material and its container must be disposed of as hazardous waste S6 - avoid release to the environment. Refer to special instructions/safety data sheets Notes: Note E Chemical name: cadmium (pyrophoric) and labelling in Annex I of Directive 67/548/EEC for physicochemical properties Flammability: F; R7 Spontaneously flammable in air. and labelling in Annex I of Directive 67/548/EEC for health hazards Acute toxicity: Repeated dose toxicity: Carcinogenicity: Mutagenicity - Genetic Toxicity: Toxicity to reproduction - fertility: T+; R26 Very toxic by inhalation. T; R48/23/25 Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed. Carc. Cat. 2; R45 May cause cancer. Muta. Cat. 3; R68 Possible risk of irreversible effects. Repr. Cat. 3; R62 Possible risk of impaired fertility
7 Toxicity to reproduction - development: Repr. Cat. 3; R63 Possible risk of harm to the unborn child. and labelling in Annex I of Directive 67/548/EEC for the environment Environment: N; R50/53 Dangerous for the environment; Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Indication of danger: F - Highly flammable T+ - very toxic N - dangerous for the environment R-phrases: R45 - May cause cancer R7 - Spontaneously flammable in air R26 - Very toxic by inhalation R48/23/25 - Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed R62 - Possible risk of impaired fertility R63 - Possible risk of harm to the unborn child R68 - Possible risk of irreversible effects R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment S-phrases: S53 - avoid exposure - obtain special instructions before use S45 - in case of accident or if you feel unwell, seek medical advice immediately (show the label where possible) S7/8 - keep container tightly closed and dry S43 - in case of fire, use... (Indicate in the space the precise type of fire-fighting equipment. if water increases risk, add 'never use water') S60 - this material and its container must be disposed of as hazardous waste S6 - avoid release to the environment. Refer to special instructions/safety data sheets Notes: Note E 2.2. Self classification(s) Chemical name: cadmium (massive) Self classification according to Directive 67/548/EEC criteria s Reason for no classification Acute toxicity Repeated dose toxicity Carcinogenicity Mutagenicity - Genetic
8 s Reason for no classification Toxicity Toxicity to reproduction- fertility Toxicity to reproductiondevelopment Environment Indication of danger: N - dangerous for the environment R-phrases: N; R50/53 Dangerous for the environment; Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment S-phrases: S60 - this material and its container must be disposed of as hazardous waste S6 - avoid release to the environment. refer to special instructions/safety data sheets
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