SAFETY DATA SHEET. Conforms to EU Directive 91/155/EEC, as amended by 2001/58/EC - United Kingdom (UK) MIKRO CHLOR
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1 SAFETY DATA SHEET Conforms to EU Directive 1/155/EEC, as amended by 2001/58/EC - United Kingdom (UK) MIKRO CHLOR Code E Version 1 Date of revision 31 August Identification of product and company Identification of the substance or preparation Product name Product use Company/undertaking identification Manufacturer/ Distributor/ Importer MIKRO CHLOR Surface Disinfectant Product is for professional use only Ecolab Ltd. David Murray John Building UK-SN1 1NH Swindon, Wiltshire England Tel +44 (0) Fax +44 (0) CCS@ecolab.com Emergency phone anti-poison centre NOT AVAILABLE. 2. Hazards identification 3. The preparation is classified as dangerous according to Directive 1/45/EC and its amendments. Classification Human health hazards Environmental hazards Xi; R36 N; R51/53 Irritating to eyes. Contact with acids liberates toxic gas. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. See section 11 for more detailed information on health effects and symptoms. Composition/information on ingredients Ingredient declaration according to detergent regulation 648/2004/EC 5 - <15% chlorine-based bleaching agents <5% anionic surfactants, phosphates Contains disinfectants. Substance/preparation Preparation Ingredient name EINECS CAS % Classification sodium carbonate Xi; R36 sodium hypochlorite phosphate (na13(clo)(po4)4) Xi; R36/38 troclosene sodium, dihydrate Xn; R22 Xi; R36/37 N; R50/53 ABS-Na Xn; R22 Xi; R41, R38 Date of issue 31 August 2007 Page 1/5
2 See section 16 for the full text of the R-phrases declared above Occupational exposure limits, if available, are listed in section First-aid measures 5. First-aid measures Inhalation Ingestion Skin contact Eye contact Specific treatments If inhaled, remove to fresh air. Do not induce vomiting unless directed to do so by medical personnel. If swallowed, rinse mouth with water (only if the person is conscious). Flush contaminated skin with plenty of water. In case of contact with eyes, rinse immediately with plenty of water. Get medical attention if irritation occurs. See section 11 for more detailed information on health effects and symptoms. Fire-fighting measures Extinguishing media Special exposure hazards Special protective equipment for fire-fighters Use foam or all-purpose dry chemical to extinguish. This material is toxic to aquatic organisms. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. This material is toxic to aquatic organisms. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Fire-fighters should wear proper protective equipment. 6. Accidental release measures 7. Personal precautions Environmental precautions and clean-up methods Large spill and leak Immediately contact safety personnel. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Small spill Rinse with plenty of running water. For large spills, dyke spilt material or otherwise contain material to ensure runoff does not reach a waterway. Place spilt material in an appropriate container for disposal. Note see section 8 for personal protective equipment and section 13 for waste disposal. Handling and storage Handling Storage Packaging materials Recommended Do not breathe dust. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid release to the environment. Keep away from acids. After handling, always wash hands thoroughly with soap and water. Keep container tightly closed. Keep container in a cool, well-ventilated area. Store between the following temperatures 0 and 35 C Use original container. 8. Exposure controls/personal protection Exposure limit values Exposure controls Occupational exposure controls Respiratory protection (EN 143, 141) Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. If user operations generate dust, fumes or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. Use appropriate respiratory protection if there is a risk of exceeding any exposure limits. Date of issue 31 August 2007 Page 2/5
3 Hand protection (EN 374) Eye protection (EN 166) Skin protection (EN 467) 1-4 hour(s) (breakthrough time) butyl rubber, nitrile rubber Safety glasses. No special recommendations.. Physical and chemical properties General information Appearance Physical state Colour Odour ph Boiling point Melting point Vapour pressure Relative density Solubility Vapour density Evaporation rate (butyl acetate = 1) Solid. [Powder.] pink chlorine Important health, safety and environmental information Flash point > 100 C Flammability (solid, gas) Explosive properties Explosion limits Oxidising properties Octanol/water partition coefficient Viscosity 10 to 11 (1%) 1.1 to 1.2 g/cm 3 (20 C) Easily soluble in cold water, hot water. 10. Stability and reactivity Stability Materials to avoid Stable under normal conditions. Extremely reactive or incompatible with the following materials acids. Do not mix with other products. 11. Toxicological information Potential acute health effects Inhalation Harmful by inhalation. Ingestion No known significant effects or critical hazards. Skin contact No known significant effects or critical hazards. Eye contact Irritating to eyes. Carcinogenicity No known significant effects or critical hazards. Reproductive toxicity No known significant effects or critical hazards. Date of issue 31 August 2007 Page 3/5
4 12. Ecological information Ecotoxicity R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Persistence and degradability The total of the organic components contained in the product achieve > 60% BOD/COD or CO2 liberation, or > 70% DOC reduction in tests for ease of degradability - threshold values for 'readily degradable' (e.g. to OECD method 301). 13. Disposal considerations Methods of disposal European waste catalogue (EWC) Waste must be disposed of according to applicable regulations. Use as much of the contents as possible, according to instructions. Can be added to general waste collection after completely emptying. Use packages for recycling only when totally empty Transport information International transport regulations Regulatory information UN number Proper shipping name Class Packing group Label ADR/RID Class III ADN Class III IMDG Class III Follow special pack instructions for air transport. 15. Regulatory information EU regulations Hazard symbol/symbols Risk phrases Safety phrases National regulations Irritant, Dangerous for the environment R36- Irritating to eyes. - Contact with acids liberates toxic gas. R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S2- Keep out of the reach of children. S7- Keep container tightly closed. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. The Chemicals (Hazard Information and Packaging for Supply) Regulations. Date of issue 31 August 2007 Page 4/5
5 The Control of Substances Hazardous to Health Regulations. Health and Safety at Work Act. 16. Other information Full text of R-phrases referred to in sections 2 and 3 - United Kingdom (UK) History Date of printing Date of revision Version Prepared by Notice to reader R22- Harmful if swallowed. R41- Risk of serious damage to eyes. R36- Irritating to eyes. R38- Irritating to skin. R36/37- Irritating to eyes and respiratory system. R36/38- Irritating to eyes and skin. - Contact with acids liberates toxic gas. R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 31 August August Ecolab Regulatory Department Europe The above information is believed to be correct with respect to the formula used to manufacture the product in the country of origin. As data, standards, and regulations change, and conditions of use and handling are beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR CONTINUING ACCURACY OF THIS INFORMATION. Version 1 Page 5/5
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