Formulation Examples. with Self-Tanning Compositions for Modulated Skin Toning

Transcription

1 Formulation Examples with Self-Tanning Compositions for Modulated Skin Toning

2 7 th revision dd. July 2007 SELF TANNING FORMULATIONS EMULSIONS, GEL, SPRAY, WIPES Name Type Comments page SE O/W Cream basic cream formulation 3 ST O/W Cream basic cream formulation 4 SK O/W Cream with empty liposomes for a very even tan 5 SL Clear W/O Lotion transparent; for light skin 6 ST W/O Lotion for light skin 7 SF Aqueous Gel transparent 8 SF Aqueous-alcoholic Spray for pump applications 9 SU Gel transparent W/Si 10 SK O/W Cream 3 % Eusolex 2292 & 0.5 % Eusolex NEW! 18SA014 Solution for Sprays or Wipes opaque solution 12 NEW! SK O/W Cream with DHA Plus 13 ST Colored W/O Lotion Shimmering with pearlescent pigments 14 DAY CARE Name Type page NEW! ST Cream with a twinkling touch of sun with Ronastar Silver 15 NEW! SK Cream providing a holiday tan (O/W) with DHA Plus 16 SK Cream providing a summer like complexion (O/W) in vivo SPF 7 17 SK Skin care cream providing a light summer tan (O/W) 18 ST Velvety body lotion for a natural glow (W/O) 19 SK Rapid Summer glow Day Care Cream with DHA Rapid 20 2

3 SE Self tanning cream (O/W) A Marlipal 1618/11 (1) CETEARETH Lanette O (2) CETEARYL ALCOHOL 7.00 Luvitol EHO (3) CETEARYL OCTANOATE 5.00 Tegosoft TN (4) C12-15 ALKYL BENZOATE 2.50 Miglyol 812 N (1) CAPRYLIC/CAPRIC TRIGLYCERIDE 2.50 Propyl-4-hydroxybenzoate (5) PROPYLPARABEN 0.05 B 1,2-Propanediol (5) PROPYLENE GLYCOL 4.00 Methyl-4-hydroxybenzoate (5) METHYLPARABEN 0.15 Water, demineralized AQUA (WATER) C Dihydroxyacetone (5) DIHYDROXYACETONE 5.00 Water, demineralized AQUA (WATER) Heat phase A to 75 C, phase B to 80 C. Add phase B slowly to phase A while stirring. Homogenize. Cool down while stirring and add phase C at 40 C. ph 26 C = 4.6 Viscosity 60,300 mpas (Brookfield RVT, Sp. C, 10 rpm) at 26 C Samples contain as preservatives 0.05 % Propyl-4-hydroxybenzoate (Merck-Art.-No ) 0.15 % Methyl-4-hydroxybenzoate (Merck-Art.-No ) (1) Sasol Germany GmbH (2) Cognis GmbH (3) BASF AG (4) Degussa-Goldschmidt AG (5) Merck KGaA/Rona 3

4 ST Self tanning cream (O/W) A Tego Care 150 (1) GLYCERYL STEARATE, STEARETH-25, CETETH-20, 8.00 STEARYL ALCOHOL Miglyol 812 N (2) CAPRYLIC/CAPRIC TRIGLYCERIDE 3.00 Isopropyl myristate (3) ISOPROPYL MYRISTATE 2.00 Paraffin liquid (4) PARAFFINUM LIQUIDUM (MINERAL OIL) Paraffin (4) PARAFFIN 2.00 Propyl-4-hydroxybenzoate (4) PROPYLPARABEN 0.15 B 1,2-Propanediol (4) PROPYLENE GLYCOL 4.00 Sorbitol F liquid (4) SORBITOL 2.00 Methyl-4-hydroxybenzoate (4) METHYLPARABEN 0.05 Water, demineralized AQUA (WATER) C Dihydroxyacetone (4) DIHYDROXYACETONE 5.00 Water, demineralized AQUA (WATER) D Fragrance (q.s.) PARFUM 0.50 Heat phase A and B separately to 75 C. Add phase A slowly to phase B while gently stirring. Homogenize at 65 C for one minute. Cool down to 40 C while stirring and add phase C. Cool down to 35 C and add phase D while stirring, cool down. ph 23 C = 4.6 Viscosity 42,500 mpas (Brookfield RVT, Sp. C, 10 rpm) at 23 C (1) Degussa-Goldschmidt AG (2) Sasol Germany GmbH (3) Cognis GmbH (4) Merck KGaA/Rona 4

5 SK Self Tanning Cream O/W cream providing a very even tan A Tego Care 150 (1) GLYCERYL STEARATE, STEARETH-25, CETETH-20, 8.00 STEARYL ALCOHOL Lanette O (2) CETEARYL ALCOHOL 1.50 Luvitol EHO (3) CETEARYL OCTANOATE 5.00 Miglyol 812 N (4) CAPRYLIC/CAPRIC TRIGLYCERIDE 5.00 Paraffin liquid (5) PARAFFINUM LIQUIDUM (MINERAL OIL) 3.00 Abil-Wax 2434 (1) STEAROXY DIMETHICONE 1.60 Dow Corning 200 Fluid (350 cs) (6) DIMETHICONE 0.50 Propyl-4-hydroxybenzoate (5) PROPYLPARABEN 0.05 B 1,2-Propanediol (5) PROPYLENE GLYCOL 3.00 Methyl-4-hydroxybenzoate (5) METHYLPARABEN 0.15 Water, demineralized AQUA (WATER) C Dihydroxyacetone (5) DIHYDROXYACETONE 5.00 Probiol L (Empty liposomes) (7) AQUA, ALCOHOL DENAT., LECITHIN, GLYCERIN, 5.00 DISODIUM PHOSPHATE Water, demineralized AQUA (WATER) Heat phase A and phase B to 80 C. Add phase B slowly to phase A while stirring. Homogenize. Cool down while stirring and add phase C at 40 C Viscosity 68,000 mpas (Brookfield RVT, sp. C, 10 rpm) at 26 C (1) Degussa-Goldschmidt AG (2) Cognis GmbH (3) BASF AG (4) Sasol Germany GmbH (5) Merck KGaA/Rona (6) Dow Corning (7) Kuhs GmbH & Co. KG 5

6 SL Smooth Self-Tanning Lotion Transparent W/O A Dow Corning 3225 C (1) CYCLOMETHICONE, DIMETHICONE COPOLYOL Propyl-4-hydroxybenzoate (2) PROPYLPARABEN 0.05 B Dihydroxyacetone (2) DIHYDROXYACETONE 5.00 Methyl-4-hydroxybenzoate (2) METHYLPARABEN ,2-Propanediol (2) PROPYLENE GLYCOL Water, demineralized AQUA (WATER) Dissolve phase B and add it to phase A. Transparent lotion, oil-free. Adjust transparency by means of variation of ratio water/propanediol-1,2. Viscosity 12,000 mpas (Brookfield RVT, sp. 4, 10 rpm) at 24 C. (1) Dow Corning (2) Merck KGaA/Rona 6

7 ST Self Tanning Lotion (W/O) A Abil EM 97 (1) BIS-PEG/PPG-14/14 DIMETHICONE, CYCLOPENTASILOXANE 1.50 Abil EM 90 (1) CETYL PEG/PPG-10/1 DIMETHICONE 1.30 Ceraphyl 368 (2) ETHYLHEXYL PALMITATE 2.00 Tegosoft DEC (1) DIETHYLHEXYL CARBONATE 5.00 Dow Corning 345 (3) CYCLOMETHICONE Dow Corning 9041 Silicone Elastomer Blend (3) DIMETHICONE CROSSPOLYMER, DIMETHICONE 3.00 Fragrance Babylon (4) PARFUM 0.30 B Dihydroxyacetone (5) DIHYDROXYACETONE ,2-Propanediol (5) PROPYLENE GLYCOL Glycerol, anhydrous (5) GLYCERIN 3.00 Magnesium sulfate heptahydrate (5) MAGNESIUM SULFATE 2.00 Phenonip (6) PHENOXYETHANOL, BUTYLPARABEN, ETHYLPARABEN, 1.00 PROPYLPARABEN, METHYLPARABEN Ethanol 96% (5) ALCOHOL 8.00 Water, demineralized AQUA (WATER) First dissolve the Magnesium sulfate heptahydrate in the water of phase B. Add the remaining ingredients of phase B. Add phase B slowly to phase A while stirring. Continue stirring stir for 2 minutes with high agitation and homogenize. Viscosity: 18,300 cps (Brookfield model RVT DV-II, Helipath Spindle C, 10 rpm) at 23 C (1) Degussa-Goldschmidt AG (2) ISP Global Technologies (3) Dow Corning (4) Drom (5) Merck KGaA/Rona (6) Nipa Laboratorien GmbH 7

8 SF Self Tanning Gel (aqueous) A Diyhdroxyacetone (1) DIHYDROXYACETONE ,2-Propanediol (1) PROPYLENE GLYCOL 2.50 Sorbitol F liquid (1) SORBITOL 2.50 Methyl-4-hydroxybenzoate (1) METHYLPARABEN 0.20 Water, demineralized AQUA (WATER) B Natrosol 250 HHR (2) HYDROXYETHYLCELLULOSE 1.50 Water, demineralized AQUA (WATER) Add Natrosol to the vortex of the vigorously agitated water of phase B. The rate of addition must be slow enough to permit the particles to separate and their surfaces to become individually wetted, but it should be fast enough to minimize viscosity build up of the aqueous phase while the polymer is being added. Dissolve Dihydroxyacetone in the water of phase A and add remaining ingredients while stirring. Combine phase A and B and homogenize. Transparent gel. Storage at room temperature is recommended to avoid a decrease of viscosity at about 40 C. (1) Merck KGaA/Rona (2) Aqualon GmbH 8

9 SF Self Tanning Lotion for Pump-Spray Aqueous-alcoholic Dihydroxyacetone (1) DIHYDROXYACETONE 5.00 Ethanol 96% (1) ALCOHOL Tagat L 2 (2) PEG-20 GLYCERYL LAURATE ,2-Propanediol (1) PROPYLENE GLYCOL 5.00 Water, demineralized AQUA (WATER) Dissolve dihydroxyacetone in water, add remaining ingredients while stirring. ph 22 C = 5.4 (immediately after production) (1) Merck KGaA/Rona (2) Degussa-Goldschmidt AG 9

10 SU Self Tanning Gel (W/Si) A Dow Corning 5225 C (1) CYCLOPENTASILOXANE, PEG/PPG-18/18 DIMETHICONE DM-Fluid-A-6cs (2) DIMETHICONE 4.00 Soybean Oil (3) GLYCINE SOJA (SOYBEAN OIL) 2.00 RonaCare Tocopherol Acetate (4) TOCOPHERYL ACETATE 0.50 B RonaCare Ectoin (4) ECTOIN ,2-Propanediol (4) PROPYLENE GLYCOL Dipropylenglycol (5) DIPROPYLENE GLYCOL Sodium chloride (4) SODIUM CHLORIDE 1.00 Ethanol 96% (4) ALCOHOL % Caramel in water (6) CARAMEL % FD&C Yelllow No. 6 in water (5) AQUA (WATER), CI (FD&C YELLOW NO. 6) 0.25 Water, demineralized AQUA (WATER) 9.25 C Dihydroxyacetone (4) DIHYDROXYACETONE 5.00 Water, demineralized AQUA (WATER) D Fragrance Melopeach (7) PARFUM 0.20 Dissolve phase B and incorporate it into phase A. Add phases C and D successively while stirring. Homogenize. Viscosity: 9,400 cps (Brookfield model RVT DV-II, Helipath Spindle C, 10 rpm) at 23 C (1) Dow Corning (2) S. Black GmbH (3) Gustav Heess GmbH (4) Merck KGaA/Rona (5) BASF AG (6) D.D.Williamson (7) Drom 10

11 SK Self Tanning Cream (O/W) with UVA/B-protection A Eusolex (1) ETHYLHEXYL METHOXYCINNAMATE, BHT 3.00 Eusolex (1) BENZOPHENONE Tego Care 150 (2) GLYCERYL STEARATE, STEARETH-25, CETETH-20, 8.00 STEARYL ALCOHOL Lanette O (3) CETEARYL ALCOHOL 1.50 Luvitol EHO (4) CETEARYL OCTANOATE 5.00 Miglyol 812 N (5) CAPRYLIC/CAPRIC TRIGLYCERIDE 5.00 Paraffin liquid (1) PARAFFINUM LIQUIDUM (MINERAL OIL) 3.00 Abil-Wax 2434 (2) STEAROXY DIMETHICONE 1.60 Dow Corning 200 Fluid (350 cs) (6) DIMETHICONE 0.50 Propyl-4-hydroxybenzoate (1) PROPYLPARABEN 0.05 B 1,2-Propanediol (1) PROPYLENE GLYCOL 3.00 Methyl-4-hydroxybenzoate sodium salt (1) SODIUM METHYLPARABEN 0.17 Water, demineralized AQUA (WATER) C Dihydroxyacetone (1) DIHYDROXYACETONE 5.00 Water, demineralized AQUA (WATER) Combine phases A and B separately and to 80 C. Add phase B slowly to phase A while stirring. Homogenize. Cool down while stirring and add phase C at 40 C (1) Merck KGaA/Rona (2) Degussa-Goldschmidt AG (3) Cognis GmbH (4) BASF AG (5) Sasol Germany GmbH (6) Dow Corning 11

12 18SA014 Self Tanning Solution for Sprays or Wipes A Arlamol E (1) PPG-15 STEARYL ETHER, BHT 3.50 Prisorine 2021 (2) ISOPROPYL ISOSTEARATE 8.00 Prisorine 2034 (2) PROPYLENE GLYCOL ISOSTEARATE 1.00 Arlasolve 200 (2) ISOCETETH Arlacel 987 (1) SORBITAN ISOSTEARATE 1.12 Atlas G-2330 (1) SORBETH B Dihydroxyacetone (3) DIHYDROXYACETONE 5.00 Water, demineralized AQUA (WATER) ad 100 Arlasolve DMI (1) DIMETHYL ISOSORBIDE 3.00 C Preservative q.s. 1,2-Propanediol (3) PROPYLENE GLYCOL 0.56 D Fragrance Pearl FC10599 (4) PARFUM 0.08 Mix phase A to obtain a homogeneous solution. Mix phase B to a transparent solution. Stir phase A into phase B. Homogenize for 5 minutes. Adjust ph value to 4.0 if necessary. Add phase C and the fragrance while stirring. ph value: 4.0 Appearance: opaque Samples contain as preservatives Propyl-4-hydroxybenzoate (1) PROPYLPARABEN 0.03 Methyl-4-hydroxybenzoate (1) METHYLPARABEN 0.11 Germall 115 (5) IMIDAZOLIDINYL UREA 0.30 (1) Uniqema (2) Uniqema Chemie GmbH (3) Merck KGaA/Rona (4) Parfex (5) ISP Global Technologies 12

13 SK Self Tanning Cream with DHA Plus (o/w) A Tego Care 150 (1) GLYCERYL STEARATE, STEARETH-25, CETETH-20, 8.00 STEARYL ALCOHOL Lanette O (2) CETEARYL ALCOHOL 1.50 Tegosoft liquid (1) CETEARYL ETHYLHEXANOATE 6.50 Miglyol 812 N (3) CAPRYLIC/CAPRIC TRIGLYCERIDE 6.50 Abil Wax 2434 (1) STEAROXY DIMETHICONE 1.20 Dow Corning 200 (100cs) (4) DIMETHICONE 0.50 RonaCare Tocopherol Acetate (5) TOCOPHERYL ACETATE 0.50 Propyl-4-hydroxybenzoate (5) PROPYLPARABEN 0.05 B RonaCare Ectoin (5) ECTOIN ,2-Propanediol (5) PROPYLENE GLYCOL 3.00 Methyl-4-hydroxybenzoate (5) METHYLPARABEN 0.15 Water, demineralized AQUA (WATER) C DHA Plus (5) DIHYDROXYACETONE, SODIUM METABISULFITE, 5.60 Water, demineralized MAGNESIUM STEARATE AQUA (WATER) D Fragrance "Sunshine for cream D" (6) PARFUM 0.10 Heat phase A and phase B to 80 C. Add phase B slowly to phase A while stirring. Homogenize. Cool down while stirring and add phase C at 40 C ph (23 C) = 3.8 Viscosity 62,000 mpas (Brookfield model RVT DV-II, Helipath spindle C, 10 rpm) at 23 C Formulation is restricted to face applications. The presence of sodium disulfite determines the maximum concentrations of DHA Plus. Recommended concentrations in formulations for the body maximum 5.4 % DHA Plus Recommended concentrations in formulations for the face maximum 6.0 % DHA Plus (1) Degussa-Goldschmidt AG (2) Cognis GmbH (3) Sasol Germany GmbH (4) Dow Corning (5) Merck KGaA/Rona (6) Bell Flavors & Fragrances 13

14 ST Shimmering Self Tanning Lotion (W/O) Clear lotion of walnut brownish color A Abil EM 97 (1) BIS-PEG/PPG-14/14 DIMETHICONE, 1.20 CYCLOPENTASILOXANE Abil EM 90 (1) CETYL PEG/PPG-10/1 DIMETHICONE 1.00 Mirasil CM 5 (2) CYCLOMETHICONE Ceraphyl 368 (3) ETHYLHEXYL PALMITATE 2.00 Dow Corning 9041 Silicone Elastomer Blend (4) DIMETHICONE CROSSPOLYMER, DIMETHICONE 1.60 Tegosoft DEC (1) DIETHYLHEXYL CARBONATE 5.00 Fragrance Babylon (5) PARFUM 0.30 B Dihydroxyacetone (6) DIHYDROXYACETONE 5.00 RonaCare Ectoin (6) ECTOIN 0.50 Caramel 250 (7) CARAMEL 0.60 Timiron Starluster MP (6) MICA, CI (TITANIUM DIOXIDE) 1.00 FD&C Yellow No6 W082 (8) CI ,2-Propanediol (6) PROPYLENE GLYCOL Glycerol, anhydrous (6) GLYCERIN 3.00 Magnesium sulfate heptahydrate (6) MAGNESIUM SULFATE 2.00 Ethanol 96% (6) ALCOHOL 8.00 Phenonip (9) PHENOXYETHANOL, BUTYLPARABEN, ETHYL PARABEN, PROPYLPARABEN, METHYLPARABEN Water, demineralized AQUA (WATER) Dissolve Magnesium sulfate heptahydrate in the water of phase B. Add the remaining ingredients. Add phase B slowly to phase A while stirring. Continue stirring for 2 minutes with high agitation and homogenize. Viscosity: 16,800 cps (Brookfield RVT DV-II, Helipath Spindle C, 10 rpm) at 23 C (1) Degussa-Goldschmidt AG (2) Rhodia GmbH (3) ISP Global Technologies (4) Dow Corning (5) Drom (6) Merck KGaA/Rona (7) D.D.Williamson (8) Les Colorants Wackherr SA (9) Nipa Laboratorien GmbH 14

15 ST Day Care Cream Twinkling Touch of Sun 2 % DHA & 1 % Ronastar Silver A Tego Care 150 (1) GLYCERYL STEARATE, STEARETH-25, CETETH-20, 8.00 STEARYL ALCOHOL Lanette O (2) CETEARYL ALCOHOL 1.50 Tegosoft liquid (1) CETEARYL ETHYLHEXANOATE 5.00 Miglyol 812 N (3) CAPRYLIC/CAPRIC TRIGLYCERIDE 5.00 Abil Wax 2434 (1) STEAROXY DIMETHICONE 1.00 Dow Corning 200 (100cs) (4) DIMETHICONE 0.50 Propyl-4-hydroxybenzoate (5) PROPYLPARABEN 0.05 B Ronastar Silver (5) CALCIUM ALUMINUM BOROSILICATE, SILICA, CI (TITANIUM DIOXIDE), TIN OXIDE 1,2-Propanediol (5) PROPYLENE GLYCOL 3.00 Methyl-4-hydroxybenzoate (5) METHYLPARABEN 0.15 Water, demineralized AQUA (WATER) C Dihydroxyacetone (5) DIHYDROXYACETONE 2.00 Water, demineralized AQUA (WATER) D Fragrance "Sultan Fantasy" (6) PARFUM 0.10 Heat phase A and phase B to 80 C. Add phase B slowly to phase A while stirring. Homogenize. Cool down while stirring and add phase C at 40 C ph (23 C) = 4.5 Viscosity 77,800 mpas (Brookfield model RVT DV-II, Helipath spindle D, 10 rpm) at 23 C (1) Degussa-Goldschmidt AG (2) Cognis GmbH (3) Sasol Germany GmbH (4) Dow Corning (5) Merck KGaA/Rona (6) Drom 15

16 SK Cream providing a Holiday Tan with DHA Plus A Tego Care 150 (1) GLYCERYL STEARATE, STEARETH-25, CETETH-20, 8.00 STEARYL ALCOHOL Lanette O (2) CETEARYL ALCOHOL 1.50 Tegosoft liquid (1) CETEARYL ETHYLHEXANOATE 6.50 Miglyol 812 N (3) CAPRYLIC/CAPRIC TRIGLYCERIDE 6.50 Abil Wax 2434 (1) STEAROXY DIMETHICONE 1.20 Dow Corning 200 (100cs) (4) DIMETHICONE 0.50 RonaCare Tocopherol Acetate (5) TOCOPHERYL ACETATE 0.50 Propyl-4-hydroxybenzoate (5) PROPYLPARABEN 0.05 B RonaCare Ectoin (5) ECTOIN ,2-Propanediol (5) PROPYLENE GLYCOL 3.00 Methyl-4-hydroxybenzoate (5) METHYLPARABEN 0.15 Water, demineralized AQUA (WATER) C DHA Plus (5) DIHYDROXYACETONE, SODIUM METABISULFITE, 2.20 Water, demineralized MAGNESIUM STEARATE AQUA (WATER) D Fragrance "Sunshine for cream D" (6) PARFUM 0.10 Heat phase A and phase B to 80 C. Add phase B slowly to phase A while stirring. Homogenize. Cool down while stirring and add phase C at 40 C ph (23 C) = 4.0 Viscosity 66,000 mpas (Brookfield model RVT DV-II, Helipath spindle C, 10 rpm) at 23 C (1) Degussa-Goldschmidt AG (2) Cognis GmbH (3) Sasol Germany GmbH (4) Dow Corning (5) Merck KGaA/Rona (6) Bell Flavors & Fragrances 16

17 SK Skin care cream providing a summer like complexion in vivo SPF 7 (International method with 10 volunteers) A Eusolex OCR (1) OCTOCRYLENE 5.00 Eusolex (1) BUTYL METHOXYDIBENZOYLMETHANE 1.00 Tego Care 150 (2) GLYCERYL STEARATE, STEARETH-25, CETETH-20, 8.00 STEARYL ALCOHOL Lanette O (3) CETEARYL ALCOHOL 1.50 Tegosoft liquid (2) CETEARYL ETHYLHEXANOATE 3.50 Miglyol 812 N (4) CAPRYLIC/CAPRIC TRIGLYCERIDE 3.50 Abil-Wax 2434 (2) STEAROXY DIMETHICONE 1.20 Dow Corning 200 (100cs) (5) DIMETHICONE 0.50 Propyl-4-hydroxybenzoate (1) PROPYLPARABEN 0.05 B 1,2-Propanediol (1) PROPYLENE GLYCOL 3.00 RonaCare Ectoin (1) ECTOIN 0.30 Methyl-4-hydroxybenzoate (1) METHYLPARABEN 0.15 Water, demineralized AQUA (WATER) C Dihydroxyacetone (1) DIHYDROXYACETONE 2.00 Water, demineralized AQUA (WATER) D Fragrance "Sunshine for cream D" (6) PARFUM 0.10 Heat phases A and B to 80 C separately. Add phase B slowly to phase A while stirring. Homogenize. Cool down while stirring and add phase C and D at 40 C. ph (23 C) = 4.4 Viscosity 73,600 mpas (Brookfield model RVT DV-II, spindle D, 10 rpm) at 23 C SPF to be labelled = 6 (Colipa recommendation) Recommended product category designation (PCD) = low SPF (1) Merck KGaA/Rona (2) Degussa-Goldschmidt AG (3) Cognis GmbH (4) Sasol Germany GmbH (5) Dow Corning (6) Bell Flavors & Fragrances 17

18 SK Skin care cream providing a light summer tan A Tego Care 150 (1) GLYCERYL STEARATE, STEARETH-25, CETETH-20, 8.00 STEARYL ALCOHOL Lanette O (2) CETEARYL ALCOHOL 1.50 Tegosoft liquid (1) CETEARYL ETHYLHEXANOATE 6.50 Miglyol 812 N (3) CAPRYLIC/CAPRIC TRIGLYCERIDE 6.50 Abil-Wax 2434 (1) STEAROXY DIMETHICONE 1.20 Dow Corning 200 (100cs) (4) DIMETHICONE 0.50 Propyl-4-hydroxybenzoate (5) PROPYLPARABEN 0.05 B 1,2-Propanediol (5) PROPYLENE GLYCOL 3.00 Ectoin (5) ECTOIN 0.30 Methyl-4-hydroxybenzoate (5) METHYLPARABEN 0.15 Water, demineralized AQUA (WATER) C Dihydroxyacetone (5) DIHYDROXYACETONE 0.75 Water, demineralized AQUA (WATER) D Fragrance "Sunshine for cream D" (6) PARFUM 0.10 Heat phases A and B to 80 C separately. Add phase B slowly to phase A while stirring. Homogenize. Cool down while stirring and add phase C and D at 40 C. ph (23 C) = 4.4 Viscosity 73,600 mpas (Brookfield model RVT DV-II, spindle D, 10 rpm) at 23 C Daily use ensures a light summer tan all year long. (1) Degussa-Goldschmidt AG (2) Cognis GmbH (3) Sasol Germany GmbH (4) Dow Corning (5) Merck KGaA/Rona (6) Bell Flavors & Fragrances 18

19 ST Velvety body lotion for a natural glow (W/O) A Abil EM 97 (1) BIS-PEG/PPG-14/14 DIMETHICONE, CYCLOPENTASILOXANE 1.50 Abil EM 90 (1) CETYL PEG/PPG-10/1 DIMETHICONE 1.30 Ceraphyl 368 (2) ETHYLHEXYL PALMITATE 2.00 Tegosoft DEC (1) DIETHYLHEXYL CARBONATE 5.00 Dow Corning 345 (3) CYCLOMETHICONE Dow Corning 9041 Silicone Elastomer Blend (3) DIMETHICONE CROSSPOLYMER, DIMETHICONE 3.00 Fragrance Babylon (4) PARFUM 0.30 B Dihydroxyacetone (5) DIHYDROXYACETONE 2.00 RonaCare Ectoin (5) ECTOIN ,2-Propanediol (5) PROPYLENE GLYCOL Glycerol, anhydrous (5) GLYCERIN 3.00 Magnesium sulphate heptahydrate (5) MAGNESIUM SULFATE 2.00 Ethanol 96% (5) ALCOHOL 8.00 Phenonip (6) PHENOXYETHANOL, BUTYLPARABEN, ETHYLPARABEN, 1.00 PROPYLPARABEN, METHYLPARABEN Water, demineralized AQUA (WATER) Dissolve the magnesium sulphate heptahydrate in the water of phase B. Add the remaining ingredients of phase B. Add phase B slowly to phase A while stirring an homogenize. (1) Degussa-Goldschmidt AG (2) ISP Global Technologies (3) Dow Corning (4) Drom (5) Merck KGaA/Rona (6) Nipa Laboratorien GmbH 19

20 SK Rapid Summer Glow' Day Care Cream with DHA-Rapid A Tego Care 150 (1) GLYCERYL STEARATE, STEARETH-25, CETETH-20, 8.00 STEARYL ALCOHOL Lanette O (2) CETEARYL ALCOHOL 1.50 Tegosoft liquid (1) CETEARYL ETHYLHEXANOATE 6.50 Miglyol 812 N (3) CAPRYLIC/CAPRIC TRIGLYCERIDE 6.50 Abil-Wax 2434 (1) STEAROXY DIMETHICONE 1.20 Dow Corning 200 (100cs) (4) DIMETHICONE 0.50 RonaCare Tocopherol Acetate (5) TOCOPHERYL ACETATE 0.50 Propyl-4-hydroxybenzoate (5) PROPYLPARABEN 0.05 B 1,2-Propanediol (5) PROPYLENE GLYCOL 3.00 Methyl-4-hydroxybenzoate (5) METHYLPARABEN 0.15 Water, demineralized AQUA (WATER) C DHA-Rapid (5) DIHYDROXYACETONE, TROXERUTIN 3.00 Water, demineralized AQUA (WATER) D Fragrance "Sunshine for cream D" (6) PARFUM 0.10 Heat phases A and B to 80 C separately. Add phase B slowly to phase A while stirring. Homogenize. Cool down while stirring and add phase C at 40 C. Incorporate phase D. Yellowish cream. (1) Degussa-Goldschmidt AG (2) Cognis GmbH (3) Sasol Germany GmbH (4) Dow Corning (5) Merck KGaA/Rona (6) Bell Flavors & Fragrances 20