Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) revision (GB) Version 1.5 Schnellbrünierung

Transcription

1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Name of product 1.2. Relevant identified uses of the substance or mixture and uses advised against Recommended intended purpose(s) Black finishing of metal surfaces 1.3. Details of the supplier of the safety data sheet Manufacturer Advice 1.4. Emergency telephone number Emergency advice F.W.Klever Hauptstraße 20, D Aham Phone +49 (0) , Fax + 49 (0) info@ballistol.de Internet Qualitätssicherung Phone +49 (0) (competent person): info@ballistol.de Dr.Zettler (Werktags von 8.00 Uhr bis Uhr) Phone +49 (0) This number is only available at office times. SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to 67/548/EEC or 1999/45/EC Xn; R20/22 R33 N; R51/53 R-phrases 20/22 Harmful by inhalation and if swallowed. 33 Danger of cumulative effects. 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Classification according to Regulation (EC) No 1272/2008 [CLP/GHS] Hazard classes and Hazard categories Acute Tox. 4 Skin Irrit. 2 Eye Irrit. 2 STOT RE 2 Hazard Statements H302 H315 H319 Classification procedure Page 1/7

2 Classification according to Regulation (EC) No 1272/2008 [CLP/GHS] Hazard classes and Hazard categories Aquatic Chronic 2 Hazard Statements H411 Classification procedure Hazard statements for health hazards H302 Harmful if swallowed. H315 Causes skin irritation. H319 Causes serious eye irritation. Hazard statements for environmental hazards H411 Toxic to aquatic life with long lasting effects Label elements Labelling according to Regulation (EC) No 1272/2008 [CLP/GHS] GHS07 GHS08 GHS09 Signal word Warning Hazard statements for health hazards H302 Harmful if swallowed. H315 Causes skin irritation. H319 Causes serious eye irritation. Hazard statements for environmental hazards H411 Toxic to aquatic life with long lasting effects. Precautionary Statements Prevention P260 P270 P273 P280 Response P301 + P312 P302 + P352 P305 + P351 + P338 P314 P332 + P313 P337 + P313 P362 P391! Disposal P Other hazards Do not breathe dust/fume/gas/mist/vapours/spray. Do no eat, drink or smoke when using this product. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minuts. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Collect spillage. Dispose of contents/container to recycling Page 2/7

3 SECTION 3: Composition/ information on ingredients 3.1. Substances not applicable 3.2. Mixtures Hazardous ingredients CAS No EC No Name [% weight] Classification according to 67/548/EEC nitric acid... % < 10 O R8; C R35 div. Schwermetallverbindungen < 15 T R23/25; R33; N R50-53 CAS No EC No Name [% weight] Classification according to Regulation (EC) No 1272/2008 [CLP/ GHS] nitric acid... % < 10 Ox. Liq. 3, H272 / Skin Corr. 1A, H314 Schwermetallverbindungen < 15 Acute Tox. 3, H331 / Acute Tox. 3, H301 / STOT RE 2, H373 / Aquatic Acute 1, H400 / Aquatic Chronic 1, H410 SECTION 4: First aid measures 4.1. Description of first aid measures In case of skin contact In case of contact with skin wash off immediately with plenty of water. Seek medical treatment immediately. In case of eye contact In case of contact with eyes rinse with plenty of water carefully. In the event of persistent symptoms seek medical treatment. In case of ingestion Give activated charcoal. If swallowed seek medical advice immediately and show the doctor packing or label. Give plenty of water to drink in small sips Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed Treatment (Advice to doctor) Treat symptoms. SECTION 5: Firefighting measures 5.1. Extinguishing media 5.2. Special hazards arising from the substance or mixture Page 3/7

4 5.3. Advice for firefighters Additional information Product is incombustible SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Use personal protective clothing Environmental precautions Do not discharge into the drains/surface waters/groundwater Methods and material for containment and cleaning up Dilute with water. Neutralize with sodium carbonate or slaked lime Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling General protective measures Avoid contact with eyes and skin Hygiene measures At work do not eat, drink, smoke or take drugs. Wash soiled clothing immediately. Keep away from food and drink Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels Keep only in original container. Further information on storage conditions Recommended storage temperature: 20 C Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters Indicative occupational exposure limit values (91/322/EEC, 2000/39/EC, 2006/15/EC or 2009/161/EU) CAS No Name Code [mg/m3] [ppm] Remark nitric acid Short-term 2, Exposure controls Respiratory protection Short term: filter apparatus, Filter A/P2 Hand protection If contact is possible use gloves of latex, coat thickness 0,6 mm, time < 120 min Gloves (acid-resistant) The material of the gloves has to be impermeable and consistent for the substance. Observe glove manufactor s instructions concerning penetrability and breakthrough time. Page 4/7

5 Eye protection safety goggles SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Form Colour liquid dark green Important health, safety and environmental information ph value in delivery state Odour odourless Value Temperature at Method Remark ca. 0,4 Vapour pressure ca. 23 hpa 20 C Relative density 1,08-1,081 g/cm3 20 C Solubility in water multimiscible Viscosity kinematic ca. 1,1 mm2/s 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Heating over 110 C Incompatible materials Materials to avoid Reactions with reducing agents. Reactions with alkalies Hazardous decomposition products < 100 C splitting off smoke of nitric acid Page 5/7

6 SECTION 11: Toxicological information Information on toxicological effects Acute toxicity/irritability/sensitization Value/Validation Species Method Remark LD50 acute oral 7-13 mg/kg rat (male / female) Angabe bezieht sich auf das Selendioxid. Irritability skin Irritability eye reizend/ätzend reizend/ätzend SECTION 12: Ecological information Toxicity Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Waste code No. Name of waste wastes not otherwise specified Recommendations for packaging Barrel: return by DSD ( Dualistic System Germany ) Recommended cleansing agent Water SECTION 14: Transport information Land and inland navigation transport ADR/RID UN 2031nitric acid, 8, II, ADR including 1 liter: limited quantity LQ22 (max.to 4L / parcel) more than 1liter: dangerous goods Marine transport IMDG UN 2031 nitric acid, class 8, packinging group II, EmS F-A, S-B including 1 liter: "limited quantity" (max. 30 kg / parcel, more than 1 liter: dangerous goods Page 6/7

7 Air transport ICAO/IATA-DGR UN 2031 nitric acid, class8, packaging group II, packaging order 807 (passanger) 813 (cargo) Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture National regulations Water hazard class Chemical Safety Assessment Chemical safety assessments for substances in this mixture were not carried out. SECTION 16: Other information Recommended uses and restrictions National and local regulations concerning chemicals shall be observed. The information in this data sheet has been established to our best knowledge and was up-to-date at time of revision. It does not represent a guarantee for the properties of the product described in terms of the legal warranty regulations. Wording of the R/H-phrases specified in chapter 3 (not the classification of the mixture!) R 23/25 Toxic by inhalation and if swallowed. R 33 Danger of cumulative effects. R 35 Causes severe burns. R 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R 8 Contact with combustible material may cause fire. H272 May intensify fire; oxidiser. H301 Toxic if swallowed. H314 Causes severe skin burns and eye damage. H331 Toxic if inhaled. H373 May cause damage to organs (or state all organs affected, if known) through prolonged or repeated exposure (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard). H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. Page 7/7