SAFETY DATA SHEET. 1. Identification. 2. Hazard(s) identification. 3. Composition/information on ingredients. 4. First-aid measures

Transcription

1 SAFETY DATA SHEET 1. Identification Product identifier Other means of identification Product code 7212 Recommended use Recommended restrictions STEPAN PTC Surfactant For industrial use only. Manufacturer/Importer/Supplier/Distributor information Manufacturer Company name Stepan Company Address 22 West Frontage Road rthfield, IL Telephone USA General Emergency phone number Medical Chemtrec Chemtrec Int'l Hazard(s) identification Physical hazards Health hazards Environmental hazards OSHA defined hazards t classified. Serious eye damage/eye irritation t classified. t classified. Category 2B Label elements Hazard symbol Signal word Hazard statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Supplemental information ne. Warning Causes eye irritation. Wash thoroughly after handling. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Store away from incompatible materials. Dispose of waste and residues in accordance with local authority requirements. ne known. t applicable. 3. Composition/information on ingredients Mixtures Chemical name _Pentaerythrityl Tetracaprylate/Caprate Common name and synonyms CAS number % First-aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Move to fresh air. Call a physician if symptoms develop or persist. Wash off with soap and water. Get medical attention if irritation develops and persists. Hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if irritation develops and persists. Rinse mouth. Get medical attention if symptoms occur. Do not induce vomiting. Direct contact with eyes may cause temporary irritation. 1 / 6

2 Indication of immediate medical attention and special treatment needed General information Treat symptomatically. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions Specific methods General fire hazards 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Do not use water jet as an extinguisher, as this will spread the fire. During fire, gases hazardous to health may be formed. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Move containers from fire area if you can do so without risk. Use standard firefighting procedures and consider the hazards of other involved materials. unusual fire or explosion hazards noted. Keep unnecessary personnel away. For personal protection, see section 8 of the SDS. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Environmental precautions Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Avoid contact with skin. Observe good industrial hygiene practices. Wear appropriate personal protective equipment. Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Store in original tightly closed container. Store away from incompatible materials (see Section 10 of the SDS). Occupational exposure limits exposure limits noted for ingredient(s). Biological limit values Appropriate engineering controls biological exposure limits noted for the ingredient(s). Ensure adequate ventilation, especially in confined areas. Eye wash facilities and emergency shower must be available when handling this product. Individual protection measures, such as personal protective equipment Eye/face protection If contact is likely, safety glasses with side shields are recommended. Hand protection Skin protection Other Skin protection Respiratory protection Thermal hazards General hygiene considerations 9. Physical and chemical properties Appearance Odor Physical state Form Color For prolonged or repeated skin contact use suitable protective gloves. Wear suitable protective clothing. Wear protective gloves. In case of insufficient ventilation, wear suitable respiratory equipment. Wear appropriate thermal protective clothing, when necessary. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Liquid. Liquid. Light yellow. 2 / 6

3 Odor threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) > 300 F (> C) > 201 F (> 93.9 C) PMCC Estimated slower than ethyl ether. Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) NOT DETERMINED. Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Vapor density Relative density Solubility(ies) Solubility (water) Auto-ignition temperature Decomposition temperature Viscosity Other information Density t Applicable Estimated heavier than air C C 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. dangerous reaction known under conditions of normal use. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Strong oxidizing agents. Alkalies. Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. 11. Toxicological information Information on likely routes of exposure Ingestion Expected to be a low ingestion hazard. Inhalation Skin contact Eye contact Symptoms related to the physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Product STEPAN PTC Acute Oral LD50 Skin corrosion/irritation Serious eye damage/eye irritation adverse effects due to inhalation are expected. Causes mild skin irritation. Causes eye irritation. Direct contact with eyes may cause temporary irritation. Mild skin irritation. Expected to be a low hazard for usual industrial or commercial handling by trained personnel. Species Rat Causes mild skin irritation. Causes eye irritation. Test Results > 5000 mg/kg 3 / 6

4 Respiratory or skin sensitization Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity This product is not expected to cause skin sensitization. data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. US. OSHA Specifically Regulated Substances (29 CFR ) t listed. Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard 12. Ecological information Ecotoxicity This product is not expected to cause reproductive or developmental effects. t applicable. t applicable. t applicable. ecotoxicity data noted for the ingredient(s). Persistence and degradability Expected to be readily biodegradable. Bioaccumulative potential Mobility in soil Other adverse effects 13. Disposal considerations Disposal instructions Hazardous waste code Waste from residues / unused products Contaminated packaging 14. Transport information DOT t regulated as dangerous goods. IATA t regulated as dangerous goods. IMDG t regulated as dangerous goods. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information US federal regulations data available. data available. other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. Dispose of contents/container in accordance with local/regional/national/international regulations. The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. CERCLA Hazardous Substance List (40 CFR 302.4) t listed. US. OSHA Specifically Regulated Substances (29 CFR ) t listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Delayed Hazard - Fire Hazard - Pressure Hazard - Reactivity Hazard - SARA 302 Extremely hazardous substance SARA 311/312 Hazardous chemical 4 / 6

5 SARA 313 (TRI reporting) Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ) Safe Drinking Water Act (SDWA) US state regulations US. Massachusetts RTK - Substance List US. Rhode Island RTK US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Canada China Europe Europe Japan Korea New Zealand Philippines Domestic Substances List (DSL) n-domestic Substances List (NDSL) Inventory of Existing Chemical Substances in China (IECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of tified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date Revision date Version # 01 NFPA ratings / 6

6 Disclaimer Revision Information Terms and Conditions. This SDS is designed only as guidance for the products to which it applies. To the greatest extent permitted by applicable law, nothing contained herein creates any legal obligation including contractual obligations, expressed or implied warranties, including any warranties of merchantibility or fitness for particular purpose; or confers any intellectual property rights, including rights to use trademarks or a license to use patents, issued or pending. The information contained herein is based on the manufacturer's own study and the work of others, and is subject to change at any time without further notice. There is no warranty, expressed or implied, as to the accuracy, completeness or adequacy of the information contained herein, and neither the provider nor the manufacturer (nor the agents, directors, officers, contractors or employees of either) are liable to any party for any damages of any nature, including direct, special or consequential damages arising out of or in connection with the accuracy, completeness, adequacy or furnishing of any information in this SDS, or in any other way related (directly or indirectly) to this SDS. The receipt and use of this information constitutes consent to these terms and conditions. Product and Company Identification: Product and Company Identification Composition / Information on Ingredients: Disclosure Overrides Physical & Chemical Properties: Multiple Properties Toxicological Information: Toxicological Data Index: United States GHS: Classification 6 / 6