ther common bonding patterns are shown below. YDRGE: Usually forms only one bond. F l ARB: Forms four bonds when neutral, but it can also have only th
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1 LEWIS FRMULAS, STRUTURAL ISMERISM, AD RESAE STRUTURES LEARIG BJETIVES: To understand the uses and limitations of Lewis formulas, to introduce structural isomerism, and to learn the basic concept of resonance structures. ARATERISTIS F LEWIS FRMULAS: Lewis formulas are structures that show the connectivity, or bonding sequence of the atoms, indicating single, double, or triple bonds. They should also show any formal charges and unshared electrons that might be present in the molecule. Additional examples of Lewis formulas follow. l l l 3 5 l 3 5 l 3 5 l These examples were deliberately chosen because all three molecules shown have the same molecular formula, but different connectivities, or bonding sequences. Such substances are called structural isomers, or sometimes constitutional isomers. otice that only the first structure shows the unshared electrons of chlorine. In Lewis formulas of organic compounds, it is customary to omit the lone electron pairs on the halogens unless there is a reason to show them explicitly. Lewis formulas are mostly used for covalent substances, but occasionally they also show ionic bonds that might be present in certain compounds. l The bond between nitrogen and chlorine is ionic. All others are covalent. a The bond between oxygen and sodium is ionic. All others are covalent. MM BDIG PATTERS FR FIRST AD SED RW ELEMETS: nce we write enough Lewis formulas containing the elements of interest in organic chemistry, which are mostly the second row elements, we find that certain bonding patterns occur over and over. Learning these patterns is useful when trying to write Lewis formulas because they provide a convenient starting point. For example, in several of the structures given in the previous section, we find that the carbon bonded to three hydrogens is a unit that occurs quite frequently. It is called the methyl group, represented by 3. It is so common that it is valid to write it as such in Lewis formulas, even though it is in fact an abbreviated form, because everybody knows what it stands for. or 3 It is equally valid to represent the acetate ion by either of these formulas.
2 ther common bonding patterns are shown below. YDRGE: Usually forms only one bond. F l ARB: Forms four bonds when neutral, but it can also have only three bonds by bearing a positive or a negative charge. When it bears a negative charge it should also carry a pair of unshared electrons. l eutral carbon A carbocation has a central carbon with an incomplete octet and a formal +1 charge A carbanion has a central carbon with an unshared electron pair and a formal -1 charge. ITRGE: Forms three bonds and carries a lone pair of electrons when neutral. It can also form four bonds by bearing a positive charge, in which case it carries no unshared electrons. Finally, it can also form two bonds as it carries two unshared electron pairs and a negative charge. 3 3 eutral nitrogen 3 3 Positively charged nitrogen egatively charged nitrogen
3 XYGE: Forms two bonds and carries two lone pairs when neutral. It can form three bonds with a positive charge, or one bond with a negative charge. In each case it must carry the appropriate number of unshared electron pairs to complete the octet. water hydronium ion hydroxide ion ALGES: Form one bond and carry three electron pairs when neutral. an carry a negative charge with no bonds. They are rarely seen with positive charges. F l TIRD RW ELEMETS: They behave like their second-row counterparts, except that they can expand their valence shells if needed. S Electron pairs on oxygen S are not shown for clarity. l l l l P l Br P Br Br ELETR DEFIIEY I SED RW ELEMETS: ne thing worth noting is that, in the second row, only boron and carbon can form relatively stable species in which they bond with an incomplete octet. Examples have already been discussed. Boron has no choice but to be electron deficient. arbon can bond with a complete octet or with an incomplete octet. bviously bonding with a complete octet provides higher stability. F F B F Boron has no choice but to have an incomplete octet An electron deficient carbon in a carbocation It is however very rare to observe species where nitrogen or oxygen bond with incomplete octets. Their high electronegativity renders such situation high energy, and therefore very unstable. For all intents and purposes, avoid writing formulas where oxygen or nitrogen are shown with incomplete octets, even if they carry a positive charge To write this structure without the lone pair of electrons on oxygen is unacceptable. This structure is unacceptable and indeed it looks quite awkward This species might exitst in the high energy environment of a mass spectrometer, but it is not frequently observed in common organic reactions.
4 RESAE STRUTURES AD SME LIMITATIS F LEWIS FRMULAS : Lewis formulas are misleading in the sense that atoms and electrons are shown as being static. By being essentially two-dimensional representations they also fail to give an accurate idea of the three-dimensional features of the molecule, such as actual bond angles and topography of the molecular frame. Furthermore, a given compound can have several valid Lewis formulas. For example 3 can be represented by at least three different but valid Lewis structures called resonance forms, or resonance structures, shown below. I II III owever, a stable compound such as the above does not exist in multiple states represented by structures I, or II, or III. The compound exists in a single state called a hybrid of all three structures. That is, it contains contributions of all three resonance forms, much like a person might have physical features inherited from each parent to varying degrees. In the resonance forms shown above the atoms remain in one place. The basic bonding pattern, or connectivity, is the same in all structures, but some electrons have changed locations. This means that there are certain rules for electron mobility that enable us to push electrons around to arrive from one resonance structure to another. These rules will be examined in detail in a later paper. ALL RESAE STRUTURES MUST BE VALID LEWIS FRMULAS: By convention, we use double-headed arrows to indicate that several resonance structures contribute to the same hybrid. ontinuing with the example we ve been using, the resonance structures for 3 should be written in this way if we want to emphasize that they represent the same hybrid I II III Do not confuse double-headed arrows with double arrows. A double arrow indicates that two or more species are in equilibrium with each other and therefore have a separate existence. Double-headed arrows indicate resonance structures that do not exist by themselves. They simply represent features that the actual molecule, the hybrid, possesses to one extent or another. When writing resonance structures keep in mind that TEY ALL MUST BE VALID LEWIS FRMULAS. The factors that make up valid Lewis formulas are as follows. 1. bserve the rules of covalent bonding, including common patterns as discussed previously. Make sure to show all single, double, and triple bonds. 2. Account for the total number of valence electrons being shared (from all the elements), including bonding and nonbonding electrons. Make sure to show these nonbonding electrons. 3. Account for the net charge of the molecule or species, showing formal charges where they belong. 4.bserve the octet rule as much as possible, but also understand that there are instances where some atoms may not fulfill this rule.
5 5. Avoid having unpaired electrons (single electrons with no partners) unless the total number of valence electrons for all elements is an odd number. This is not a very frequent occurrence, but the following example shows a species that could exist as a reaction intermediate in some high energy environments. The total number of valence electrons being shared for all atoms is 4 from carbon and 3 from the three hydrogens, for a total of 7. Because it is an odd number, it is impossible to have all these electrons paired. Therefore the presence of a single electron cannot be avoided. otice that there is no formal charge on carbon, since it has no surplus or deficit of valence electrons. RELATIVE EERGIES F RESAE STRUTURES. From the examples given so far it can be seen that some resonance forms are structurally equivalent and others are not. The potential energy associated with equivalent Lewis structures is the same. If the Lewis structures are not equivalent, then the potential energy associated with them is most likely different. This means that equivalent resonance structures are also equivalent in stability and nonequivalent structures have different stabilities. This in turn means that equivalent structures contribute equally to the hybrid and nonequivalent structures do not contribute equally to the hybrid. In the example below, the two structures are equivalent. Therefore they make equal contributions to the hybrid. 3 3 equivalent in energy It is very difficult to accurately represent the hybrid with drawings because it is a composite of all the resonance contributors. Some representations such as the first one shown below are sometimes given. In this case the broken line represents the electrons and the negative charge which are spread over three atoms (--). Another commonly used representation of the hybrid is given on the right, showing that each oxygen atom shares a -1/2 charge. owever, none of them accurately conveys the true picture. For convenience, the unshared electrons are sometimes omitted from some representations, just like it s done with hydrogen atoms. This must be kept in mind when examining the different structures /2 two commonly used representations for the acetate ion hybrid -1/2 There is a third resonance form that can be drawn for the acetate ion hybrid. The structure shown below is structurally different from the ones shown above. This means that it is of different energy and therefore does not contribute to the hybrid to the same extent as the others. In this case, it happens to be less stable than the other two and therefore does not make a significant contribution to the hybrid. 3
6 What factors dictate the relative stabilities of different resonance structures? harge separation is an important one. In the example just given there are too many charges present in the structure (even though the net charge is still the same). This results in a structure with higher potential energy than others with fewer or no formal charges. This structure is less stable and its contribution to the hybrid is probably minor. Another important factor that increases potential energy (lowers stability) is the presence of atoms with an incomplete octet. In the example below structure I has a carbon atom with a positive charge and therefore an incomplete octet. Based on this criterion, this structure is less stable than structure II and makes a less significant contribution to the hybrid I II Finally, another factor that comes into play when determining the relative energies of resonance structures is the relative electronegativities of atoms that bear charges. More electronegative atoms are more comfortable with negative charges. Less electronegative atoms are more comfortable with positive charges. In the example below, structure I is less stable than II. The negative charge is on carbon, which is less electronegative than oxygen. Therefore structure II makes a larger contribution to the hybrid. 3 3 I II Some texts refer to the different contributors as important or unimportant. This can be misleading, because importance is context-dependent. In the example above, structure I is less important in terms of its contribution to the hybrid, but in terms of reactivity, it is very important. It will be seen later that this structure provides a better indication of how this species reacts with electrophiles in certain types of reactions. Based on the charge separation criterion, structure II below might be labeled unimportant, or less important because it is less stable than I. But if we are trying to assess the polarity of this molecule, structure II becomes very important because it reveals that the carbon atom has positive character and the oxygen has negative character. The hybrid representation on the right then portrays the molecule as a polar molecule, which structure I alone does not give much indication of. δ δ + ybrid representation as a polar structure. I II The following additional examples further illustrate the relative importance of the factors that contribute to structural energy and stability.
7 Major contributor. eutral structure. Minor contributor. harge separation. Minor contributor. Incomplete octet on carbon. Major contributor. All atoms have octets, even though there is a positive charge on nitrogen 3 3 Minor contributor. Incomplete octet on carbon, but more important in tems of reactivity. Major contributor. All atoms have octets, even though there is a positive charge on oxygen.
The elements of the second row fulfill the octet rule by sharing eight electrons, thus acquiring the electronic configuration of neon, the noble gas o
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