Product Safety Data Sheet

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1 Product Safety Data Sheet Document Code: D Version: 5.0 Description: HARPIC POWER PLUS GEL Status: Published Revision Reason: Formula change Issue Date: 19 May 2011 PSDS PSDS PAGE 1 OF TOTAL 6 1. PRODUCT and COMPANY IDENTIFICATION Product Name Other Names Variants Recommended Use Harpic Power Plus Harpic Power Plus Toilet Cleaner Spring Power 5X Power Action Citrus Force 5X Power Action Surface cleaner Supplier AUSTRALIA COMPANY: Reckitt Benckiser (Australia) Pty Limited ABN: ADDRESS: 44 Wharf Road West Ryde NSW 2114 TELEPHONE: (02) AFTER HOURS EMERGENCY TELEPHONE (5pm to 8am EST Australia): (02) NEW ZEALAND COMPANY: Reckitt Benckiser (New Zealand) Limited ADDRESS: Lincoln Manor 289 Lincoln Road Henderson Auckland 1231 TELEPHONE: (09) Poisons Centre Information AUSTRALIA NEW ZEALAND or 0800 POISON 2. HAZARD(S) IDENTIFICATION 19/05/ :21:53 GMT Page 1 Product Safety Data Sheet D

2 HAZARDOUS ACCORDING TO NOHSC CRITERIA NONDANGEROUS GOODS ACCORDING TO ADG CODE (See Section 14) RISK PHRASE(S) R36/38 Irritating to eyes and skin (See Section 15) SAFETY PHRASE(S) S2 Keep out of the reach of children S24/25 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 After contact with skin, wash immediately with plenty of water. S35 This material and its container must be disposed of in a safe way S46 If swallowed, seek medical advice immediately and show this container or label. S50 Do not mix with drain cleaners and bleach products. S51 Use only in well ventilated areas 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS No Proportion (%w/w) Surfactants <10 Formic acid <5 Fragrance Mixture <1 Sodium hydroxide * <1 Other ingredients classified as not hazardous according to NOHSC to 100 * Neutralised in the reaction 4. FIRST AID MEASURES Eye Contact Skin Contact Inhalation Ingestion Advice to Doctor If in eyes, hold eyelids apart and flush the eye continuously with running water. Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes. If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Remove to fresh air. If breathing difficulties are experienced, seek medical attention. If swallowed do NOT induce vomiting. Give 2 glasses of water to drink. Contact a doctor or a Poisons Centre Information. Treat symptomatically. 5. FIREFIGHTING MEASURES Specific Dangers Flammability Extinguisher Type Hazchem code None known. Not flammable. Water, foam, carbon dioxide, dry chemical. 19/05/ :21:53 GMT Page 2 Product Safety Data Sheet D

3 6. ACCIDENTAL RELEASE MEASURES Emergency and Evacuation Avoid contact with skin and eyes. Procedures Avoid breathing vapour. Ensure adequate ventilation. Area may become slippery. Use personal protective equipment. See section 8. Minor Spills Major Spills Mop up spill and wash area with detergent and water. Contain spill. collect product using a suitable absorbent material such as vermiculite. Shovel material into a clean, dry, labelled container and close lid tightly. Do not allow product to enter waterways. 7. HANDLING AND STORAGE Handling Storage Avoid contact with skin and eyes. Avoid breathing vapour. Store in a cool dry area out of direct sunlight. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Standards Australia ingredients: Exposure Standards (1) have been set for the following Ingredient CAS No. (a) TWA ppm (b) mg/m 3(c) STEL ppm (b) mg/m 3(c) Carcinogen Category Notices Sodium hydroxide peak limitation Formic acid Exposure Standards New Zealand following ingredients: Exposure Standards (3) have been set for the Ingredient CAS No. (a) TWA STEL ppm (b) mg/m 3(c) ppm (b) mg/m 3(c) Sodium hydroxide Ceiling 2 Formic acid TWA = Time Weighted Average STEL= Short Term Exposure Limit (1) Worksafe Australia Exposure Standards for Atmospheric Contaminants in the Occupational Environment [NOHSC: )] (2) Workplace Exposure Standards endorsed by the Occupational Safety and Health Service (OSH) of the Department of Labour; Revised: January 2002 (a) CAS #, Chemical Abstracts Service Registry. A unique numbering identifier is assigned to each individual chemical. (b) Parts of vapour or gas per million of contaminated air by volume at 25 C and 760 torr. (c) Milligrams of substance per cubic metre of air. Ceiling = (WES Ceiling) = A concentration that should not be exceeded during any part of the working day. Engineering Controls Use in well ventilated areas. Maintain air concentrations below exposure standards. 19/05/ :21:53 GMT Page 3 Product Safety Data Sheet D

4 Local exhaust ventilation should be used where aerosols/vapours are generated. Personal Protection When handling bulk quantities, wear suitable gloves, safety glasses and protective clothing. If ventilation is insufficient, a suitable respirator should be worn. Work/Hygienic Practices Wash thoroughly with soap and water after handling. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Appearance Colour Liquid Clear, viscous Blue ph (neat) at 25 C Vapour Pressure Vapour Density Boiling Point Solubility in Water 2.3 kpa (water) Not available 100 C (water) Soluble Specific Gravity at 25 C Flashpoint Viscosity Not flammable Centipoise at 25 C (Brookfield sp2, 50rpm) 10. STABILITY AND REACTIVITY Stability Dangerous Reactions Stable under normal conditions. Avoid alkalis, oxidizing and reducing agents. Decomposition Products Products may include oxides of carbon and nitrogen. 11. TOXICOLOGICAL INFORMATION Acute Effect(s) Eye Skin Inhaled Swallowed Sensitisation Chronic Effect(s) Toxicity Information Will cause irritation to the eyes. Will cause irritation to the skin. Vapours/mists may cause irritation to the upper respiratory tract. May cause irritation to the upper gastrointestinal tract. Not expected to be a skin sensitiser. The chronic toxicity of this product has not been determined. Information is based on available component data and their concentrations in 19/05/ :21:53 GMT Page 4 Product Safety Data Sheet D

5 the product. 12. ECOLOGICAL INFORMATION Ecotoxicity Based on component ecotoxicity data the product is not an environmental hazard. 13. DISPOSAL CONSIDERATIONS Disposal Method Product should be treated according to the instructions given under sections 6,7 and 8 above. Dispose of according to Local, State and Federal regulations. Contact relevant authority for details. 14. TRANSPORT INFORMATION Road Transport Regulations (ADG 7) UN number: Proper shipping name: DG class: Not a DG Subsidiary risk: Packing group: Hazchem code: Maritime Transport Regulations (IMDG) UN number: Proper shipping name: DG class: Not a DG Subsidiary risk: Packing group: Marine Pollutant: Not a Marine Pollutant Air Transport Regulations (IATA) UN number: Proper shipping name: DG class: Not a DG Subsidiary risk: Packing group: 15. REGULATORY INFORMATION AUSTRALIA Regulatory Status This product has been approved by TGA Australia, AUST L Hazardous Substances Regulation Hazardous Risk Phrase(s) R36/38 Irritating to eyes and skin Safety Phrase(s) S2 Keep out of the reach of children S24/25 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 After contact with skin, wash immediately with plenty of water. S35 This material and its container must be disposed of in a safe way S46 If swallowed, seek medical advice immediately and show this container or label. S50 Do not mix with drain cleaners and bleach products. 19/05/ :21:53 GMT Page 5 Product Safety Data Sheet D

6 S51 Use only in well ventilated area SUSMP NEW ZEALAND Regulatory Status Approved Handler Tracking S5 (Formic acid) This product has been approved under HSNO covered by Cleaning Products (Subsidiary Hazard) Group Standard 2006 HSR Not required Not required 16. OTHER INFORMATION CONTACT POINT AUSTRALIA and NEW ZEALAND Regulatory, Safety & Environmental Services From outside Australia Ph: (61) (2) From within Australia Ph: (02) The information contained in this MSDS was compiled using the latest and most reliable information available to Reckitt Benckiser. The information is provided without any warranty, expressed or implied regarding its correctness or accuracy. Similarly no warranty expressed or implied regarding the product described herein shall be created by or inferred from any statement or omission from this MSDS nor will Reckitt Benckiser assume any liability for any loss or damage arising out of the use of this information. It is solely the responsibility of the user to determine safe conditions for use of this product and to assume liability for any loss, damage or expense whatsoever arising out of the product's improper use. KEY/LEGEND ADG = Australian Code for the Transport of Dangerous Goods by Road and Rail DG = Dangerous Goods HSNO = Hazardous Substances and New Organisms Act 1996 (New Zealand) IATA = International Air Transport Association IMDG = International Maritime Dangerous Goods NOHSC = National Occupational Health and Safety Commission (Australia) SUSMP = Standard for the Uniform Scheduling of Medicines and Poisons (Australia) This document is only current on the day of viewing. Printed copies are UNCONTROLLED unless they are a part of a Quality/ Technical Manual or attached to a letter referring to Purchase Order Number. END OF DOCUMENT. 19/05/ :21:53 GMT Page 6 Product Safety Data Sheet D

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