MSDS - Version: 1.2 Product name : RAL7040 PE-PARLAK Product code : KC80907040 Product date : 26.07.2013 Section 1 - Product and company identification MANUFACTURER'S NAME KC Kimya Ticaret ve San.A.Ş Beylikbağı Mah.E 5 Güney Yanyol Cad.No:50 Gebze Kocaeli/Türkiye PRODUCT CLASS Powder coating. Applied by electrostatic spray PRODUCT CODE & TRADE NAME KC80907040 RAL7040 PE- PARLAK Section 2 - Composition of ingredients MATERIAL SAFETY DATA SHEET EMERGENCY TELEPHONE NO +90 262 653 05 52 INFORMATION TELEPHONE NO +90 262 653 12 52 DATE OF PREPARATION 26.07.2013 INGREDIENT NAME 1,3,5-Triglycidyl Isocyanurate BARIUM SULFATE TITANIUM DIOXIDE NUISANCE DUST Section 3 - Hazards Identification CAS Number 002451-62-9 007727-43-7 013463-67-7 PERCENT BY WEIGHT 1~5 7 ~ 13 3~7 As generated ROUTES OF EXPOSURE Exposure may be by inhalation, skin, eye contact. To minimize exposure, ventilation and personal protective equipment is recommended. Avoid breathing vapor or mist. Avoid contact with eyes, skin, and clothing. SHORT TERM & LONG TERM EFFECTS - Short term effects - Cause respiratory tract, skin and eye irritation. Additional effects may include lack of sense of smell, nausea, headache, drowsiness, drunkenness, tingling sensation, liver and kidney and nerve damage. - Long term effects - In addition to effects from short term exposure, ringing in the ears, stomach pain, bloody vomit, difficulty speaking, chest pain, irregular heartbeat, fainting, loss of memory, blood disorder, brain damage, coma and heart failure may occur. Extremly high concentration vapors may cause person to unconsciousness or death. Drinking alcohol may worsen the effects. Prolonged overexposure to solvent may cause liver, kidney, brain and nerve system damage and reproductive harm. Section 4 - First Aid Measures INHALATION : Remove from exposure area to fresh air immediately. Perform artificial respiration if necessary. Keep person warm and at rest and get medical attention immediately. EYES : Wash eyes immediately with large amounts of water occasionally lifting upper and lower lids, until no evidence of chemical remains (at least 15 ~ 20 minutes). Get medical attention immediately. SKIN : Remove contaminated clothing and shoes immediately. Launder before re-use. Wash affected area thoroughly with soap and water until no evidence of chemical remains(at least 15 ~ 20 minutes). Get medical attention immediately. SWALLOW : Extreme care must be used to prevent aspiration. Do not induce vomiting. Get medical attention immediately. Section 5 - Fire Fighting Measures Hazards from combustion products: On burning will emit toxic fumes, including those of oxides of carbon and oxides of nitrogen. Precautions for fire fighters and special protective equipment: Fire fighters to wear self-contained breathing apparatus and suitable protective clothing if risk of exposure to vapour or products of combustion. Minimize dusting during use. Keep all equipment clean and properly grounded to avoid static electricity discharge. Suitable Extinguishing Media: Fine water spray, normal foam, dry agent (carbon dioxide, dry chemical powder). Section 6 - Accidental Release Measures Emergency procedures: If contamination of sewers or waterways has occurred advise local emergency services.
Methods and materials for containment and clean up: Wear protective equipment to prevent skin and eye contact and breathing in dust. Work up wind or increase ventilation. Cover with damp absorbent (inert material, sand or soil). Sweep or vacuum up, but avoid generating dust. Collect and seal in properly labelled containers or drums for disposal. Page 1
MSDS - Version: 1.2 Product name : RAL7040 PE-PARLAK Product code : KC80907040 Product date : 26.07.2013 Section 7 - Handling and Storage HANDLING Keep all equipment clean and properly grounded to avoid static electricity discharge. Keep work areas free of dust. Avoid excessive skin contact. Do not ingest or inhale. Keep out of the reach of children. STORAGE Keep containers sealed and avoid static electricity discharges. Section 8 - Exposure controls / Personal Protection Occupational Exposure Limits 1,3,5-Triglycidyl Isocyanurate BARIUM SULFATE TITANIUM DIOXIDE NUISANCE DUST ACGIH TLV ACGIH TLV-C ACGIH STEL OSHA STEL OSHA PEL 0.05 mg/m³ 10.00 mg/m³ 5.00 mg/m³ 10.00 mg/m³ 10.00 mg/m³ 10.00 mg/m³ ENGINEERING CONTROLS Provide sufficient ventilation in volume and pattern to keep air contamination concentration below applicable OSHA permissible exposure levels or ACGIH s TLV TWA limit. RESPIRATORS Use properly fitted NIOSH/MSHA approved gas & vapor respirators, or conventional respirators, or negative pressure respirators or particulate respirators, or FFR (filtering facepiece respirator) to avoid breathing dust. OTHER CLOTHING PROTECTIVE GLOVES: Recommended to avoid skin contact. EYE PROTECTION: Goggles or safety glasses w/side shields recommended. OTHER PROTECTIVE EQUIPMENT: Protective overalls recommended. Remove and wash soiled clothing. Section 9 - Physical and Chemical Properties Physical state : Colour : Odour : Solubility: Specific Gravity : Relative Vapour Density(air=1): Vapour Pressure (20 C): Flash Point ( C): Flammability Limits (%) : Autoignition Temperature ( C) : % Volatile by Weight : Solubility in water (g/l) : Melting Point/Range ( C) : Boiling Point/Range ( C) : Powder Coloured Slight Insoluble in water. 1,61 ±0.05 gr/cm³ Not available Not available <1 Insoluble Not available Section 10 - Stability and Reactivity Chemical stability : Conditions to avoid : Stable under normal conditions of use. Avoid contact with foodstuffs. Avoid exposure to heat, sources of ignition, and open flame. Incompatible materials : Incompatible with oxidising agents. Hazardous decomposition products : Oxides of carbon. Oxides of nitrogen. Hazardous reactions : Hazardous polymerisation will not occur. Section 11 - Toxicological Information EFFECTS OF EXPOSURE : See section 3 ACUTE TOXICITY DATA : 1) 1,3,5-Triglycidyl Isocyanurate LD50(Oral-rat) LD50 440. mg/kg Section 12 - Environmental Information Ecotoxicity Do not allow to enter soil, waterways and waste water channel. Section 13 - Disposal Considerations
Disposal methods: Manage or dispose in accordance with local, state and national regulations. Page 2
MSDS - Version: 1.2 Product name : RAL7040PE-PARLAK Product code : KC80907040 Product date : 26.07.2013 Section 14 - Transport Information Road and Rail Transport Not classified as Dangerous Goods by the criteria of the International Freight Transport Association (FTA Code) for transport by Road and Rail; NON-DANGEROUS GOODS. Marine Transport Not classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG Code) for transport by sea; NON-DANGEROUS GOODS. Air Transport Not classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA) Dangerous Goods Regulations for transport by air; NON-DANGEROUS GOODS. U.S. Department of Transportation (DOT) Not in the IATA dangerous condition. Shiping Name: by plane, by ship, by truck Hazard Class: None ID Number: None Packing group: None Labels: Not dangerous material Section 15 - Regulatory Information Classification : Hazard Category : Risk Phrase(s): Safety Phrase(s): This product has been classified in accordance with the hazard criteria of the 91/155/UE. T : Toxic Xi: Irritant R20/22: Harmful by inhalation and if swallowed. R36: Irritating to eyes. R42/43: May cause sensitisation by inhalation and skin contact. R46: May cause heritable genetic damage. S22: Do not breathe dust. S24/25: Avoid contact with skin and eyes. S36/39: Wear suitable protective clothing and eye/face protection. Section 16 - Other Information The data given here is based on our current knowledge and experience. The purpose of this safety data sheet is to describe the products in terms of their safety requirements. The data does not signify any warranty with regard to the products properties. Page 3