Chemtex Group Global Engineering and Project Solutions

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Chemtex Group Global Engineering and Project Solutions Case study on the first advanced industrial demonstration bioethanol plant in the EU, and how it was financed Stefania Pescarolo R&D Public Funding Projects Assistant Chemtex Italia - Mossi & Ghisolfi Group, Tortona (AL), Italy EBTP 5 th Stakeholder Plenary Meeting - Bruxelles, 06/02/2013

Summary 1. M&G vision on renewables 2. The companies involved 3. PROESA Technology 4. Public funds for demo project

M&G vision on renewables For both Bio-Fuels and Bio-based Chemicals the solution is based on the same key fundamentals: 1.Competitive pricing compared to products from Black Route (at oil prices in the 60-70$/barrel); 2.Environmentally sustainable with respect to Green House Gases: overall GHG sequestration balance (including biomass feedstock farming, transportation, chemicals or biofuels production processes); 3.Agronomically sustainable on the long term (i.e. no competition with food) and profitable for farmers 3

M&G Group: the companies involved $3B per year #2 producer of PET 2,600 Employees Location: Italy, US, Mexico, Brazil Engineering division Technology for biomass to sugars

Chemtex R&D&D investments on renewables Feedstock Capacity Location M&G Investment Status R&D Center on Lignocellulosic biomass conversion on Biofuel and Biochemical and development of PROESA technology (lab/batch/pilot scale) Multiple lignocellulosic energy crops and agro residues 50 kg/h of biomass inlet continuous Pilot plants Rivalta (IT) 160 million On going R&D Centers on Lignin valorization to Biofuel and Biochemical (lab/pilot/demo scale) Lignin Bioreformate, BTX. Production of biofuel and biochemicals Modugno (IT) Sharon C. (US) 50 million On going 2 nd generation Industrial Bioethanol Demo plant Arundo donax and Wheat straw 40,000 ton/y Bioethanol Crescentino (IT) 120 million (CAPEX) Commissioning 12/2012 5

PROESA technology: the pillars Biomass Enzymes CO 2 Water Feed Handling Pre-Treatment and Viscosity Reduction Hydrolysis + Fermentation Recovery Ethanol Steam Water Boiler + Generator Steam Power The Pillars of PROESA are: 1. Agronomy: Field experimentation and best energy crops identified and characterized (12 kinds of biomasse tested -> tech biomass agnostic). No biomass drying/grinding required. 2. Biomass Pre-Treatment and Viscosity Reduction: Continuous process developed and piloted to produce costeffective and clean fermentable sugars. Low level of inhibitors. No use of chemicals (only steam is added). Rapid liquefaction of solid content. 3. Hydrolysis and Fermentation: Unique hybrid SSCF process scheme yielding high ethanol concentrations. Reduced enzymes load. High solid concentration (>40%) in the hydrolysis step 4. Valorization of secondary streams and co-products. 6

PROESA Technology: the history 2006-2008 Scouting of Technologies Agronomic testing on energy crops Generation of key inventions Proof of unit operation in lab/batch 2009-2010 PILOT PLANT construction & start up (June 2009) Pilot Plant operation and Data gathering Test of plant flexibility using multiple biomasses 2011-2012 Crescentino 40,000 ton/y INDUSTRIAL DEMONSTRATION ETHANOL PLANT Technology licensing

Financial: Lower capital investment as a result of minimum handling of biomass, simplified flow schemes and no special materials of construction; Cash cost of fermentable sugars at ~10 /lb; Cash cost of ethanol of <$ 1.50/USG ($ 0.40/L); Cost-effective at modest scale; short supply chains Beta Renawables: joint venture Chemtex-TPG Strategic partnership making Novozymes the preferred enzyme supplier for Beta Renewables current and future cellulosic biofuel projects. Flexibility: Key advantages of PROESA technology Feedstock-agnostic: energy crops, agricultural residues, organic waste, woody biomass, bagasse; Deployable worldwide; Pure lignin by-product to be valorized to energy or renewable chemicals. Commitment of Chemtex and its partners to continuous development and improvement Competitive and attractive economics without subsidies

Three points that will change the industry Commercial-scale cellulosic ethanol plant, Q3 2012: 40,000 ton/y, Crescentino - Italy (ready to start) Cellulosic costs less No subsidies required Sept 2011 Febr 2012 May 2012 July 2012 Aug 2012 Sept 2012 Dec. 2012 PREPARED FOR ROQUETTE NOT FOR DISTRIBUTION OUTSIDE ROQUETTE

Crescentino in numbers 120 M of investment 40 000 Mtons Second generation Bioethanol 160,000 ton/y of dry lignocellulosic biomass 13 MW of green power from lignin 300 pieces of equipment 1 500 tons of steel 1 400 tons of pipes and valves 30 000 m 3 of concrete 18 km of underground piping More than 150 persons involved directly Commissioning: December 2012 Sept.2012 Sept. 2011 April 2011

How can research and its scale-up be founded? Basic and applied research (lab/batch) PILOT SCALE DEMONSTRATION PLANT First-in-its-kind PRE-COMMERCIAL PLANT INDUSTRIAL COMMERCIAL PLANT European (FP7, NER300, IEE, Life+, ) and National funds RTD RTD pilot DEM PRE- COM COM

PROESA technology scale-up European (FP7, NER300, IEE, Life+, ) and National funds RTD RTD pilot DEM PRE- COM COM

Public funds for demonstration project the Bioethanol case RTD RTD pilot DEM PRE-COM COM 13

Chemtex next demonstration projects LOW COST SUGAR C5-C6 PLATFOMR New Tech New Tech BIOFUEL Biochemicals DEMO/ PRE-COMMERCIAL DEMO/ PRE-COMMERCIAL PROESA Technology BIOFUEL Ethanol Bio-Jet fuel Marine Diesel Green Diesel Butanol LIGNIN-CHEMICALS Benzen Phenols Xylene Terephthalic Acid Aromatic aldehydes BIOCHEMICAL Acrylic Acid Fatty Alcohols Succinic Acid 1,4 Butanediol Acrylic Acid Farnasene Bio-PE Bio-EO/EG LIGNIN PLATFORM New Tech New Tech BIOFUEL Biochemicals DEMO/ PRE-COMMERCIAL DEMO/ PRE-COMMERCIAL 14

THANK YOU 15