Technical & gluten-free solutions for baked goods Experts formulate with Specialty Rice Ingredients

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Technical & gluten-free solutions for baked goods Experts formulate with Specialty Rice Ingredients Consumers busy lifestyles often result in a lack of time to prepare healthy meals themselves. At the same time, people are becoming more conscious about their nutrition. They do not only expect food to be readily available, but also want it to be healthy and taste great all at the same time. Shoppers have a critical look at food content and the detailed ingredient list. More than ever, consumers want clean labelled and naturally derived products. In this context, the quality and origin of ingredients is becoming more important to them. Besides this, consumer research showed that the group of people who buy gluten-free products is steadily growing. While a part of them is actually diagnosed with food allergies, an increasing number deliberately chooses a gluten-free diet simply because they consider it to be better for them. Combining the desire for tasteful, healthy food with the growing group of gluten-free eaters instantly brings the challenge back to the food industry. Formulating tasty, gluten-free baked goods can be made easier when experts share their findings. BENEO Inc. 201 Littleton Road, 1st Floor Morris Plains, NJ 07950 (USA) Phone +1 973-867-2140 Fax +1 973-867-2141 contact@beneo.com www.beneo.com

Technical challenges when developing gluten-free baked goods While gluten has a certain elasticity, responsible for the light, airy structure and the tender crumb of baked products such as bread, producing gluten-free baked products with similar physical and sensorial properties can be challenging. When formulating for high quality baked goods, some common objectives instantly cross our minds: improved volume delivery nice rise! softness & mouthfeel not rigid or dry! crumb structure and openness not compact or dense! Just a few requirements that become even harder to deliver when working without gluten. Our BENEO application experts have extensively tested formula s where wheat flour was replaced by rice flour and starches. They are pleased to share their results. Expert case studies Gluten-free baked goods In gluten-free baked goods, rice flours and rice starches are the main ingredients, allowing to formulate products close to their wheat-based counterparts. Breads, cookies and cakes have been developed with an excellent taste and texture. Our ingredients portfolio also contains whole grain rice flours meeting the increased market needs for whole grain bakery products. In a test formulation gluten-free bread, a variation of the following ingredients were used: native regular starches Remy DR and Remy B, as well as native waxy rice starch Remyline AX-DR. Remarkable results were delivered on the optimization of appearance, technical aspects and eating quality. The table in Fig. 1 clearly shows the search for the optimal rice starch. Where initial results with Remy AX-DR showed good signs, further improvement was achieved with Remy B. The use of Remy B in the recipe offers good overall crumb structure and eating quality (tested dosage 15.3%). Fig. 1: Pilot test gluten-free bread. Remyline AX-DR Remy DR Remy B Volume (cm 3 /100 g) 360 344 352 Crumb texture Softest Firmer Soft Crumb structure More open More open Finer

This test was worked out with the following gluten-free bread recipe (Fig. 2): Fig. 2: Test recipe: gluten-free bread. Typical values per 100g Energy Protein Carbohydrates Of which sugars Fat Of which saturated fat Fibre Sodium Recipe 283 kcal 4.5 g 40.8 g 4.9 g 1.3 g 4.9 g 7.5 g 399 mg Ingredient list Rice starch, rice flour, tapioca starch, shortening, sugar, inulin, sugar cane fibre, egg white, yeast, hydroxypropyl methylcellulose and carboxymethyl cellulose, locust bean gum, salt. BENEO ingredients to use: Rice flour & whole grain rice flour Native rice starches (cook-up and pre-cooked) Inulin as fibre source Wheat-based baked goods In wheat-based recipes, rice starch achieves the required texture or improves final product characteristics, such as increased crunchiness in crackers thanks to the use of our pregelatinised waxy rice starch. This rice starch can also be used to reduce breakage in cookies and cracks in pastries. In fig. 3, a distinct hardness in the cracker is shown by the use of rice starch Remyline AX-FG-P, the BENEO solution for breakage control and crunchiness in hard baked goods. Fig. 4 provides a recipe used in a similar test, resulting in improved crunch for crackers. Fig. 3: Texture improvement in biscuits. Ingredients Reference (%) Test (%) Wheat flour 44.9 38.9-41.9 25 Measured hardness (g) Remyline AX-FG-P 0.0 3.0-6.0 Brown sugar 28.0 28.0 Butter 16.8 16.8 Eggs 9.0 9.0 Spices 0.8 0.8 Baking powder 0.3 0.3 Salt 0.2 0.2 Total 100.0 100.0 20 15 10 5 0 14,630 Reference 19,471 4% Remyline AX FG P

Texture improvement in crackers: This test recipe is recommended for an improved crunch and products with clean label requirements. Fig. 4: Texture improvement in crackers. Ingredients Reference (%) Test (%) Wheat flour (9.3% protein) 30.8 27.8 Wheat flour (11.5% protein) 29.7 26.7 Water 25.1 25.1 Shortening 10.0 10.0 Remyline AX-FG-P 0.0 6.0 Baking powder 1.5 1.5 Salt 0.9 0.9 Remylose 58-80 1.2 1.2 Sugar 0.6 0.6 Veron P 0.2 0.2 Total 100.0 100.0 The hardness and brittleness of thin bakery products can be fine-tuned by adding small amounts of rice ingredients. Incorporating 2 4% of rice ingredients gives noticeable improvements in texture. The mechanism behind this lies in the characteristic water absorption during dough handling and baking. The neutral taste of rice ingredients and the low amounts needed, mean that the small changes in the recipe will not affect the overall taste and appearance of the cookie or the cracker. It is only the texture that will be improved.

Soft baked goods In soft baked goods like cakes, rice flour with a fine particle size or a modified waxy rice starch can extend shelf life as it promotes water retention during baking. Additionally significantly softer crumb, with crumb remaining more soft in time, can be achieved with a modified waxy rice starch. The table in Fig. 5 provides the recipe comparison, where the Remy ingredients were tested alternately in the recipe compared to the reference. With the replacement of wheat flower by one of our rice starches or flour, an improved juiciness and longer shelf life was ascertained. Fig. 5: Texture improvement in sponge cakes. Ingredients Reference (%) Test (%) Eggs 35.0 35.0 Wheat flour 30.0 24.0 27.0 Remygel 663 0.0 3.0 Remy DR 0.0 3.0 Remyflo R7-90T LP 0.0 6.0 Sugar 30.0 30.0 Water 4.0 4.0 Baking powder 1.0 1.0 Total 100.0 100.0 The test showed significantly lower water loss directly after baking and after 2 weeks storage compared to the reference recipe (Fig.6). The sponge cake showed a softer crumb, from the moment of production until far into ca. 4 months shelf life (Fig.7). Fig. 6: Water retention in baked goods. Fig. 7: Softer crumb in sponge cake. Significant difference in water loss compared to the reference 700 600 12 500 10 8 6 4 2 0 8,5 6,6 6,4 Reference Remy DR Remygel 663 hardness (g) 400 300 200 100 0 0 2 4 6 8 10 12 14 16 time (weeks) After 2 weeks shelf life After baking Reference Remyflo R7 90 T Remygel 663

Bakery fillings In water-based bakery fillings, our modified waxy rice starch can control moisture migration. Furthermore, trials have shown that BENEO regular rice starch can reduce fat or sugar in fat-based fillings, to improve the nutritional composition of bakery products. Rice starch in filling Type and dosage 1-2% Remygel 663 or Remygel 652 (NAFTA) / Remyline XS (EU) 1-2% rice starch Conditions & functionality To avoid water migration from filling to baked good Provides good process stability of the filling Provides creamy texture More than a texturiser the goodness of rice Rice-based ingredients offer food producers high-quality, stable products that encompass a wide range of nutritional benefits: they are naturally derived, hypoallergenic, wholegrain, gluten-free and rich in antioxidants and phytosterols. Rice is well-balanced and nutritional, with a low level of fat and high levels of carbohydrates. Between 98 % and 100 % of the rice we consume is digested by the body. Low in fat and characterised by a carbohydrate content of ± 78 %, rice is very easy to digest. Besides carbohydrates, rice contains a good amount of non-gluten proteins (~ 7 %) with a very interesting amino acid profile. The amino acid profile of rice proteins and ease of digestion are the main reasons why rice flour is widely used in baby food cereals. Compared to that of cow milk and soy milk, the overall amino acid profile of rice proteins is more closely related to breast s milk A.A. profile. The high nutritional value of rice can also be found in rice derived products such as rice flours, rice starches and proteins.

BENEO specialty rice ingredients BENEO specialty rice ingredients meet today s expectations in several ways. They act as naturally sourced functional ingredients in today s convenient food and snacks. Their functional strengths in formulations deliver the right solutions for the food industry. Improving crunchiness & crispiness, creating creaminess and a fatty mouthfeel. Furthermore, they can increase shelf life or prevent moisture migration in baked goods. All this, with the focus on clean labeling. As healthy alternatives to dairy or other grain ingredients, our specialty rice ingredients perform well in gluten-free products. Besides wholegrain options, our wide range of rice ingredients also includes high quality solutions for infant nutrition. Along with the overall healthy image of rice, this makes BENEO specialty rice ingredients perfectly suitable for today s food trends. BENEO offers a wide range of specialty rice ingredients that combine nutritional and technical benefits. Rice flours are available from different varieties, particle sizes and qualities. BENEO rice flours include baby food quality, organic, whole grain and instant options. BENEO rice flours of multiple technical benefits ranging from enhancing crispiness & crunchiness, extending shelf life of baked goods to offering creaminess and fat-like mouthfeel. Additionally BENEO offers a range of specialty rice starches. They comprise both native and modified starches from different rice varieties (waxy, regular, organic), available in cook-up or instant forms. With our rice starches we promote also promote clean label, non-gmo (labeling), gluten-free and hypoallergenic solutions. Technical benefits of rice starches can be linked to the unique rice starch properties (small granule size, white colour, delicate texture) adding multiple benefits to food applications. Our BENEO specialty rice ingredients for baked goods. Rice ingredient Description Technical properties Remyflo R7 90T (LP) Regular rice fine particle size Increased freshness in baked goods, main ingredient in gluten-free Remyflo C(O) 200 Whole grain regular rice flour Main ingredient in gluten-free (bread), whole grain Remyline AX FG P Pregelatinised waxy rice starch Breakage control & crunchiness in hard baked goods Remygel 663 Modified waxy rice starch Moisture control in fillings & cakes Remy DR Regular rice starch Fat/sugar reduction in bakery fillings RemyLiVe Rice bran & germ Nutritional enrichment, whole grain Our BENEO experts can provide optimal solutions in the following applications: Baby food Baked goods Cereals Confectionery Dairy & dairy alternative products Meat & vegetables Soups & sauces

BENEO at your trade fair! BENEO plays an active partner at many local and international events, where its full range of ingredients for a variety of physiological benefits is presented. To name a few: blood sugar management, weight management, digestive health, energy management, healthy ageing all with technical benefits such as improved shelf life, enhanced mouth feeling, brighter colors, sugar reduction, natural sweetness, non-gmo, fiber enrichment and last but certainly not least: improved taste & texture. Come visit us at one of the following events and find out more about how using our carbohydrates, fibers and specialty rice ingredients can help to position your product innovation to appeal to today s consumers. Health Ingredients Japan, Tokio 8-10 October 2014 Booth 2-278 (DKSH) Supply Side West, Las Vegas 6-10 October Booth N 29109 Food Ingredients Asia, Jakarta 15-17 October 2014 Booth N E18 (DPO) Health Ingredients Europe, Amsterdam 2-4 December 2014 Hall 1 - Booth N G4 Always at your side: Profit from our interdisciplinary expertise. Our experts offer valuable insights. No matter if your question concerns physiology or process technology, if it is marketing-related or if it is about legislation and regulations. With nutritionists, marketers, regulatory professionals, technical food engineers and a competent sales force team throughout the world, there is always a BENEO expert that can help you. It s the combination of advanced ingredients and specialist knowledge together with access to a global network of experts which makes BENEO a unique business partner. The BENEO range of food ingredients includes specialty rice ingredients, functional carbohydrates, prebiotic fibres and vital wheat gluten. Learn more about the our BENEO nutrients online: www.beneo.com The information in this document is presented in good faith and believed to be correct, nevertheless no responsibilities/warranties as to the completeness of this information can be taken. This information is supplied upon the condition that the persons receiving the same will make their own determination as to its suitability for their purposes prior to use. It is strongly recommended to consult and apply all national food legislation (e.g. legislation on claims, communication towards the consumer etc.) prior to any communication to consumers. This information does not contain any warranty that the supply or the use of the products in any territory is not an infringement of the rights of third parties in industrial or intellectual property. It can also not be regarded as an encouragement to use our products in violation of existing patents or legal provisions in the matter of food stuffs.