BYK-Chemie GmbH Postfach 02 45, 46462 Wesel, Germany To whom it may Substances of Very High Concern (SVHC) Dear Customer, According to the recipe, the products in table 1 do not contain any of the substances listed in the latest version of the candidate list. The substances in the candidate lists, that was taken into consideration are given in the tables at the end of this document. For the substances we state that they are absent according to the recipe: All values are given according to the recipe, i.e. not intentionally added or intentionally added but removed. All values are not a sales specification, given as typical value. We do not check the content of these substances as part of our quality control and therefore we cannot formally guarantee the absence of these substances. The products that are in red/crossed out contain a SVHC-substance. See table 2 below for further details. In Tables 3 and 4 the SVHC substances taken into consideration are given. Table 1 ANTI-TERRA-202 AQUACER 40 AQUACER 517 ANTI-TERRA-203 AQUACER 41 AQUACER 519 ANTI-TERRA-204 AQUACER 63 AQUACER 526 ANTI-TERRA-205 AQUACER 1547 AQUACER 527 ANTI-TERRA-206 AQUACER 1800 AQUACER 528 ANTI-TERRA-207 AQUACER 2500 AQUACER 531 ANTI-TERRA-250 AQUACER 2650 AQUACER 533 ANTI-TERRA-P AQUACER 3500 AQUACER 535 ANTI-TERRA-U AQUACER 494 AQUACER 537 ANTI-TERRA-U 0 AQUACER 498 AQUACER 539 ANTI-TERRA-U 80 AQUACER 501 AQUACER 541 AQUACER 505 AQUACER 552 AQUACER AQUACER 506 AQUACER 561 AQUACER 21 AQUACER 507 AQUACER 565 AQUACER 30 AQUACER 513 AQUACER 580 AQUACER 31 AQUACER 516 AQUACER 581 1/23 Your contact Rob Zwanenburg Tel (direct) +49 281 670-236 Fax (direct) +49 281 670-23533 E-mail BRIEF.BYK@altana.com BYK-Chemie GmbH Abelstrasse 45 46483 Wesel Germany Tel +49 281 670-0 Fax +49 281 65735 www.byk.com Chairman of the Supervisory Board Dr. Matthias L. Wolfgruber Management Dr. Christoph Schlünken (Chairman) Dr. Uwe Zakrzewski Albert von Hebel Bank Commerzbank AG, Wesel IBAN: DE70 3564 0064 0133 0000 00 BIC: COBADEFF356 VAT-No. DE 811113391 Registered Registered Office: Wesel Registry Court: Duisburg HRB-No. 656
AQUACER 593 BYK-066 N BYK-301 BYK-359 AQUACER 595 BYK-067 A BYK-302 BYK-360 P AQUACER 597 BYK-070 BYK-303 BYK-361 N AQUACER 840 BYK-071 BYK-306 BYK-364 P AQUACER D 208 BYK-072 BYK-307 BYK-366 P AQUACER D 272 BYK-077 BYK-3 BYK-368 P AQUAFLOUR 400 BYK-085 BYK-35 BYK-370 AQUAMAT 1400 BYK-088 BYK-313 BYK-371 AQUAMAT 208 BYK-093 BYK-315 BYK-373 AQUAMAT 263 BYK-094 BYK-3155 BYK-375 AQUAMAT 270 BYK-1161 BYK-3160 BYK-377 AQUAMAT 270 BYK-1162 BYK-320 BYK-378 AQUAMAT 272 BYK-1165 BYK-321 BYK-380 N AQUATIX 8421 BYK-141 BYK-322 BYK-381 BYK-151 BYK-323 BYK-388 BYK-011 BYK-152 BYK-325 BYK-390 BYK-012 BYK-153 BYK-330 BYK-3900 P BYK-014 BYK-154 BYK-331 BYK-3902 P BYK-015 BYK-155 BYK-332 BYK-392 BYK-016 BYK-155 BYK-333 BYK-3931 P BYK-017 BYK-155/35 BYK-335 BYK-3932 P BYK-018 BYK-155/50 BYK-336 BYK-3933 P BYK-019 BYK-156 BYK-337 BYK-394 BYK-020 BYK-16 BYK-340 BYK-3950 P BYK-020 BYK-1615 BYK-3400 BYK-3951 P BYK-021 BYK-1650 BYK-341 BYK-3955 P BYK-022 BYK-1660 BYK-34 BYK-399 BYK-023 BYK-1679 BYK-342 BYK-405 BYK-024 BYK-17 BYK-344 BYK-4 BYK-025 BYK-1711 BYK-3440 BYK-411 BYK-028 BYK-1719 BYK-3441 BYK-415 BYK-031 BYK-1724 BYK-345 BYK-420 BYK-033 BYK-1730 BYK-3455 BYK-425 BYK-034 BYK-1740 BYK-346 BYK-428 BYK-035 BYK-1752 BYK-347 BYK-430 BYK-037 BYK-1770 BYK-348 BYK-431 BYK-038 BYK-1780 BYK-349 BYK-4500 BYK-044 BYK-1785 BYK-3499 BYK-4509 BYK-045 BYK-1790 BYK-350 BYK-45 BYK-051 BYK-1791 BYK-352 BYK-4511 BYK-052 BYK-1794 BYK-3520 BYK-4512 BYK-053 BYK-1798 BYK-3521 BYK-8020 BYK-054 BYK-220 S BYK-354 BYK-8070 BYK-055 BYK-2615 BYK-355 BYK-8800 BYK-057 BYK-2616 BYK-3550 BYK-8801 BYK-060 N BYK-2662 BYK-356 BYK-8820 BYK-065 BYK-300 BYK-358 N BYK-8821 2/23 2
BYK-8822 BYK-LP W 6236 BYK-UV 3575 CERAFLOUR 00 BYK-9076 BYK-LP X 217 BYK-UV 3576 CERAFLOUR 913 BYK-9077 BYKOPLAST-00 BYK-W 90 CERAFLOUR 914 BYK-A 500 BYK-P 4 BYK-W 9011 CERAFLOUR 915 BYK-A 501 BYK-P 4 S BYK-W 903 CERAFLOUR 916 BYK-A 505 BYK-P 5 BYK-W 909 CERAFLOUR 920 BYK-A 506 BYK-P 40 BYK-W 920 CERAFLOUR 921 BYK-A 515 BYK-P 41 BYK-W 935 CERAFLOUR 925 BYK-A 520 BYK-P 42 BYK-W 940 CERAFLOUR 928 BYK-A 525 BYK-P 4200 BYK-W 961 CERAFLOUR 929 BYK-A 530 BYK-P 9050 BYK-W 965 CERAFLOUR 940 BYK-A 535 BYK-P 9051 BYK-W 966 CERAFLOUR 950 BYK-A 550 BYK-P 9060 BYK-W 969 CERAFLOUR 960 BYK-A 555 BYK-P 9065 BYK-W 972 CERAFLOUR 961 BYK-A 560 BYK-P 9080 BYK-W 974 CERAFLOUR 962 BYKANOL-N BYK-P 9085 BYK-W 980 CERAFLOUR 963 BYK-C 8000 BYK-P 9901 BYK-W 985 CERAFLOUR 965 BYK-C 8002 BYK-P 9902 BYK-W 995 CERAFLOUR 967 BYK-C 9200 BYK-P 9904 BYK-W 996 CERAFLOUR 968 BYK-CATALYST 450 BYK-P 9905 BYK-W 997 CERAFLOUR 969 BYK-CATALYST 451 BYK-P 9908 CERAFLOUR 970 BYK-CATALYST 451 BYK-P 9909 CARBOBYK-98 CERAFLOUR 981 BYK-D 4 BYK-P 9915 CERAFLOUR 988 BYK-D 420 BYK-P 9928 CERACOL 39 CERAFLOUR 990 BYK-DYNWET 800 BYK-R 605 CERACOL 600 CERAFLOUR 991 BYK-E 4 BYK-R 606 CERACOL 601 CERAFLOUR 993 BYK-E 411 BYK-S 706 CERACOL 603 CERAFLOUR 994 BYK-E 420 BYK-S 732 CERACOL 604 CERAFLOUR 995 BYK-ES 80 BYK-S 740 CERACOL 607 CERAFLOUR 996 BYK-S 750 CERACOL 609 N CERAFLOUR 997 BYKETOL-AQ BYK-S 760 CERACOL 79 CERAFLOUR 998 BYKETOL-OK BYK-S 780 CERACOL 80 BYKETOL-PC BYK-S 781 CERACOL 83 CERAMAT 241 BYKETOL-SPECIAL BYK-S 782 CERACOL 86 CERAMAT 248 BYKETOL-WS BYK-SILCLEAN 3700 CERAMAT 250 BYK-SILCLEAN 37 CERAFAK 0 CERAMAT 258 BYKJET-9130 BYK-SILCLEAN 3720 CERAFAK 3 BYKJET-9131 BYK-SYNERGIST 20 CERAFAK 6 CERATIX 8461 BYKJET-9132 BYK-SYNERGIST 22 CERAFAK 1 CERATIX 8463 BYKJET-9133 BYK-SYNERGIST 25 CERAFAK 111 CERATIX 8466 BYKJET-9150 BYKUMEN CERAFAK 116 BYKJET-9151 BYK-UV 3500 CERAFAK 127 N DISPERBYK BYKJET-9170 BYK-UV 3505 CERAFAK 131 DISPERBYK-1 BYK-UV 35 CERAFAK 140 N DISPERBYK-2 BYK-K 9600 BYK-UV 3530 CERAFAK 151 DISPERBYK-3 BYK-LP R 20320 BYK-UV 3535 CERAFAK 184 DISPERBYK-6 BYK-LP S 6665 BYK-UV 3570 CERAFAK 186 N DISPERBYK-7 3/23 3
DISPERBYK-8 DISPERBYK-2020 N NANOBYK-38 DISPERBYK-9 DISPERBYK-2022 NANOBYK-3812 DISPERBYK-1 DISPERBYK-2025 NANOBYK-3820 DISPERBYK-111 DISPERBYK-2050 NANOBYK-3821 DISPERBYK-112 DISPERBYK-2059 NANOBYK-3840 DISPERBYK-115 DISPERBYK-2070 NANOBYK-3841 DISPERBYK-116 DISPERBYK-2090 NANOBYK-3842 DISPERBYK-118 DISPERBYK-2091 NANOBYK-3845 DISPERBYK-130 DISPERBYK-2095 NANOBYK-3860 DISPERBYK-140 DISPERBYK-2096 DISPERBYK-142 DISPERBYK-2117 SCONA TPEV 11 PB DISPERBYK-145 DISPERBYK-2118 SCONA TPEV 1112 PB DISPERBYK-160 DISPERBYK-2150 SCONA TPKD 23 PCS DISPERBYK-161 DISPERBYK-2151 SCONA TPKD 53 PCS DISPERBYK-162 DISPERBYK-2152 SCONA TPPE 2400 GAHD DISPERBYK-163 DISPERBYK-2155 SCONA TPPE 5002 GALL DISPERBYK-164 DISPERBYK-2163 SCONA TPPP 2003 GB DISPERBYK-166 DISPERBYK-2164 SCONA TPPP 2112 FA DISPERBYK-167 SCONA TPPP 2112 GA DISPERBYK-168 DISPERPLAST-18 SCONA TPPP 8012 FA DISPERBYK-169 DISPERPLAST-1142 SCONA TPPP 8012 GA DISPERBYK-170 DISPERPLAST-1148 SCONA TPPP 8112 FA DISPERBYK-171 DISPERPLAST-1150 SCONA TPPP 8112 GA DISPERBYK-174 DISPERPLAST-I SCONA TPPP 9012 FA DISPERBYK-180 DISPERPLAST-P SCONA TPPP 9012 GA DISPERBYK-181 SCONA TPPP 9112 FA DISPERBYK-182 HORDAMER PE 02 SCONA TPPP 9112 GA DISPERBYK-183 HORDAMER PE 03 SCONA TPSPS 9012 PA DISPERBYK-184 HORDAMER PE 34 SCONA TSEB 2113 GB DISPERBYK-185 HORDAMER PE 35 SCONA TSKD 93 DISPERBYK-187 SCONA TSPE 1112 GALL DISPERBYK-190 LACTIMON SCONA TSPE 22 GAHD DISPERBYK-191 LACTIMON-WS SCONA TSPOE 02 CMB 1-2 DISPERBYK-192 SCONA TSPOE 02 GBLL DISPERBYK-193 MINERPOL 220 DISPERBYK-194 MINERPOL 221 VISCOBYK-40 DISPERBYK-194 N VISCOBYK-4015 DISPERBYK-198 NANOBYK-3600 VISCOBYK-4040 DISPERBYK-199 NANOBYK-3601 VISCOBYK-4041 DISPERBYK-2000 NANOBYK-3602 VISCOBYK-5025 DISPERBYK-2001 NANOBYK-3605 VISCOBYK-5050 DISPERBYK-2008 NANOBYK-36 VISCOBYK-50 DISPERBYK-2009 NANOBYK-3620 VISCOBYK-5120 DISPERBYK-20 NANOBYK-3630 VISCOBYK-5125 DISPERBYK-2012 NANOBYK-3650 VISCOBYK-5130 DISPERBYK-2015 NANOBYK-3651 VISCOBYK-5316 DISPERBYK-2020 NANOBYK-3652 4/23 4
Table 2 Products that DO contain SVHC-substances Product name SVHC-substance CAS RN %* BYK-4 1-Methyl-2-pyrrolidone 872-50-4 30-50 BYK-411 1-Methyl-2-pyrrolidone 872-50-4 50-0 BYK-420 1-Methyl-2-pyrrolidone 872-50-4 30-50 BYK-LP R 20320 1-Methyl-2-pyrrolidone 872-50-4 50-0 BYK-W 909 Boric acid 233-139-2 Not yet known CERATIX 8461 1-Methyl-2-pyrrolidone 872-50-4 <1 CERATIX 8463 1-Methyl-2-pyrrolidone 872-50-4 <1 CERATIX 8466 1-Methyl-2-pyrrolidone 872-50-4 <1 BYK-033 Nonylphenol ethoxylate 5% BYK-034 Nonylphenol ethoxylate 5% BYK-3160 Nonylphenol ethoxylate 50% BYKETOL-WS Nonylphenol ethoxylate 4% BYK-S 750 Nonylphenol ethoxylate % VISCOBYK-40 Nonylphenol ethoxylate 3% VISCOBYK-4040 Nonylphenol ethoxylate 13% VISCOBYK-5050 Nonylphenol ethoxylate % *theoretical % in additive (NOT a specification) Please note that the 0.1% threshold applies to articles only, and therefore not to formulations like coatings, printing inks or master batches. As NMP is a volatile solvent, in most cases it will have evaporated during the manufacture of the article and therefore only traces of NMP are expected to be residual in the article. Table 3: SVHC-substances taken into consideration as per ECHA-website at date 20 June 2013 Substance Name Cadmium Ammonium pentadecafluorooctanoate (APFO) EC Number CAS Number of inclusion Reason for inclusion 231-152-8 7440-43-9 20.06.2013 Carcinogenic ; Equivalent to human health (Article 57 f) 223-320-4 3825-26-1 20.06.2013 Toxic for ; PBT (Article 57 d) Decision number ED/69/2013 ED/69/2013 5/23 5
Pentadecafluorooctanoic acid (PFOA) Dipentyl phthalate (DPP) 4-Nonylphenol, branched and linear, ethoxylated [substances with a linear and/or branched alkyl chain with a carbon number of 9 covalently bound in position 4 to phenol, ethoxylated covering UVCB- and welldefined substances, polymers and homologues, which include any of the individual isomers and/or combinations thereof] Cadmium oxide Pyrochlore, antimony lead yellow 6-methoxy-m-toluidine (pcresidine) 206-397-9 335-67-1 20.06.2013 Toxic for ; PBT (Article 57 d) 205-017-9 131-18-0 20.06.2013 Toxic for ; 20.06.2013 Equivalent to the environment (Article 57 f) 215-146-2 1306-19-0 20.06.2013 Carcinogenic ; Equivalent to human health (Article 57 f) 232-382-1 8012-00-8 19.12.2012 Toxic for 204-419-1 120-71-8 19.12.2012 Carcinogenic ED/69/2013 ED/69/2013 ED/69/2013 ED/69/2013 Henicosafluoroundecanoic acid 218-165-4 2058-94-8 19.12.2012 vpvb (Article 57 e) 6/23 6
Hexahydromethylphthalic anhydride [1], Hexahydro-4- methylphthalic anhydride [2], Hexahydro-1-methylphthalic anhydride [3], Hexahydro-3- methylphthalic anhydride [4] [The individual isomers [2], [3] and [4](including their cis- and trans- stereo isomeric forms) and all possible combinations of the isomers [1] are covered by this entry] Hexahydromethylphthalic anhydride [1], Hexahydro-4- methylphthalic anhydride [2], Hexahydro-1-methylphthalic anhydride [3], Hexahydro-3- methylphthalic anhydride [4] [The individual isomers [2], [3] and [4](including their cis- and trans- stereo isomeric forms) and all possible combinations of the isomers [1] are covered by this entry] Hexahydromethylphthalic anhydride [1], Hexahydro-4- methylphthalic anhydride [2], Hexahydro-1-methylphthalic anhydride [3], Hexahydro-3- methylphthalic anhydride [4] [The individual isomers [2], [3] and [4](including their cis- and trans- stereo isomeric forms) and all possible combinations of the isomers [1] are covered by this entry] 247-094-1, 243-072-0, 256-356-4, 260-566-1 247-094-1, 243-072-0, 256-356-4, 260-566-1 247-094-1, 243-072-0, 256-356-4, 260-566-1 25550-51-0 19.12.2012 Equivalent to human health (Article 57 f) 19438-60-9 19.12.2012 Equivalent to human health (Article 57 f) 48122-14-1 19.12.2012 Equivalent to human health (Article 57 f) 7/23 7
Hexahydromethylphthalic anhydride [1], Hexahydro-4- methylphthalic anhydride [2], Hexahydro-1-methylphthalic anhydride [3], Hexahydro-3- methylphthalic anhydride [4] [The individual isomers [2], [3] and [4](including their cis- and trans- stereo isomeric forms) and all possible combinations of the isomers [1] are covered by this entry] Cyclohexane-1,2- dicarboxylic anhydride [1], cis-cyclohexane-1,2- dicarboxylic anhydride [2], trans-cyclohexane-1,2- dicarboxylic anhydride [3][The individual cis- [2] and trans- [3] isomer substances and all possible combinations of the cis- and trans-isomers [1] are covered by this entry] Cyclohexane-1,2- dicarboxylic anhydride [1], cis-cyclohexane-1,2- dicarboxylic anhydride [2], trans-cyclohexane-1,2- dicarboxylic anhydride [3] [The individual cis- [2] and trans- [3] isomer substances and all possible combinations of the cis- and trans-isomers [1] are covered by this entry] Cyclohexane-1,2- dicarboxylic anhydride [1], cis-cyclohexane-1,2- dicarboxylic anhydride [2], trans-cyclohexane-1,2- dicarboxylic anhydride [3][The individual cis- [2] and trans- [3] isomer substances and all possible combinations of the cis- and trans-isomers [1] are covered by this entry] 247-094-1, 243-072-0, 256-356-4, 260-566-1 201-604-9, 236-086-3, 238-009-9 201-604-9, 236-086-3, 238-009-9 201-604-9, 236-086-3, 238-009-9 571-29-9 19.12.2012 Equivalent to human health (Article 57 f) 85-42-7 19.12.2012 Equivalent to human health (Article 57 f) 13149-00-3 19.12.2012 Equivalent to human health (Article 57 f) 14166-21-3 19.12.2012 Equivalent to human health (Article 57 f) 8/23 8
Dibutyltin dichloride (DBTC) 211-670-0 683-18-1 19.12.2012 Toxic for Lead bis(tetrafluoroborate) 237-486-0 13814-96-5 19.12.2012 Toxic for Lead dinitrate 233-245-9 099-74-8 19.12.2012 Toxic for Silicic acid, lead salt 234-363-3 11120-22-2 19.12.2012 Toxic for 4-Aminoazobenzene 200-453-6 60-09-3 19.12.2012 Carcinogenic Lead titanium zirconium oxide 235-727-4 12626-81-2 19.12.2012 Toxic for Lead monoxide (lead oxide) 215-267-0 1317-36-8 19.12.2012 Toxic for o-toluidine 202-429-0 95-53-4 19.12.2012 Carcinogenic 3-ethyl-2-methyl-2-(3- methylbutyl)-1,3-oxazolidine Silicic acid (H 2 Si 2 O 5 ), barium salt (1:1), lead-doped [with lead (Pb) content above the applicable generic concentration limit for 'toxicity for ' Repr. 1A (CLP) or category 1 (DSD); the substance is a member of the group entry of lead compounds, with index number 082-001-00-6 in Regulation (EC) No 1272/2008] Trilead bis(carbonate) dihydroxide Furan 421-150-7 143860-04- 2 19.12.2012 Toxic for 272-271-5 68784-75-8 19.12.2012 Toxic for 215-290-6 1319-46-6 19.12.2012 Toxic for 203-727-3 1-00-9 19.12.2012 Carcinogenic 9/23 9
N,N-dimethylformamide 200-679-5 68-12-2 19.12.2012 Toxic for 4-(1,1,3,3-tetramethylbutyl)- phenol, ethoxylated[covering well-defined substances and UVCB substances, polymers and homologues] 4-Nonylphenol, branched and linear [substances with a linear and/or branched alkyl chain with a carbon number of 9 covalently bound in position 4 to phenol, covering also UVCB- and well-defined substances which include any of the individual isomers or a combination thereof] - - 19.12.2012 Equivalent to the environment (Article 57 f) - - 19.12.2012 Equivalent to the environment (Article 57 f) 4,4'-methylenedi-o-toluidine 212-658-8 838-88-0 19.12.2012 Carcinogenic Diethyl sulphate 200-589-6 64-67-5 19.12.2012 Carcinogenic ; Mutagenic (Article 57b) Dimethyl sulphate 201-058-1 77-78-1 19.12.2012 Carcinogenic Lead oxide sulfate 234-853-7 12036-76-9 19.12.2012 Toxic for Lead titanium trioxide 235-038-9 12060-00-3 19.12.2012 Toxic for Acetic acid, lead salt, basic 257-175-3 51404-69-4 19.12.2012 Toxic for [Phthalato(2-)]dioxotrilead 273-688-5 69011-06-9 19.12.2012 Toxic for /23
Bis(pentabromophenyl) ether (decabromodiphenyl ether; DecaBDE) 214-604-9 1163-19-5 19.12.2012 PBT (Article 57 d); vpvb (Article 57 e) N-methylacetamide 201-182-6 79-16-3 19.12.2012 Toxic for Dinoseb (6-sec-butyl-2,4- dinitrophenol) 1,2-Diethoxyethane 201-861-7 88-85-7 19.12.2012 Toxic for 211-076-1 629-14-1 19.12.2012 Toxic for Tetralead trioxide sulphate 235-380-9 12202-17-4 19.12.2012 Toxic for N-pentyl-isopentylphthalate - 776297-69- 9 Dioxobis(stearato)trilead 19.12.2012 Toxic for 235-702-8 12578-12-0 19.12.2012 Toxic for Tetraethyllead 201-075-4 78-00-2 19.12.2012 Toxic for Pentalead tetraoxide sulphate Pentacosafluorotridecanoic acid Tricosafluorododecanoic acid Heptacosafluorotetradecanoi c acid 1-bromopropane (n-propyl bromide) Methoxyacetic acid 4-methyl-mphenylenediamine (toluene- 2,4-diamine) 235-067-7 12065-90-6 19.12.2012 Toxic for 276-745-2 72629-94-8 19.12.2012 vpvb (Article 57 e) 206-203-2 307-55-1 19.12.2012 vpvb (Article 57 e) 206-803-4 376-06-7 19.12.2012 vpvb (Article 57 e) 203-445-0 6-94-5 19.12.2012 Toxic for 2-894-6 625-45-6 19.12.2012 Toxic for 202-453-1 95-80-7 19.12.2012 Carcinogenic 11/23 11
Methyloxirane (Propylene oxide) 200-879-2 75-56-9 19.12.2012 Carcinogenic ; Mutagenic (Article 57b) Trilead dioxide phosphonate 235-252-2 12141-20-7 19.12.2012 Toxic for o-aminoazotoluene 202-591-2 97-56-3 19.12.2012 Carcinogenic 1,2-Benzenedicarboxylic acid, dipentylester, branched and linear 284-032-2 84777-06-0 19.12.2012 Toxic for 4,4'-oxydianiline and its salts 202-977-0 1-80-4 19.12.2012 Carcinogenic ; Mutagenic (Article 57b) Orange lead (lead tetroxide) 215-235-6 1314-41-6 19.12.2012 Toxic for Biphenyl-4-ylamine 202-177-1 92-67-1 19.12.2012 Carcinogenic Diisopentylphthalate Fatty acids, C16-18, lead salts Diazene-1,2-dicarboxamide (C,C'-azodi(formamide)) Sulfurous acid, lead salt, dibasic Lead cyanamidate 2-088-4 605-50-5 19.12.2012 Toxic for 292-966-7 931-62-8 19.12.2012 Toxic for 204-650-8 123-77-3 19.12.2012 Equivalent to human health (Article 57 f) 263-467-1 62229-08-7 19.12.2012 Toxic for 244-073-9 20837-86-9 19.12.2012 Toxic for 12/23 12
α,α-bis[4-(dimethylamino) phenyl]-4-(phenylamino)- naphthalene-1-methanol (C.I. Solvent Blue 4) [with 0.1% of Michler's ketone (EC No. 202-027-5) or Michler's base (EC No. 202-959-2)] 229-851-8 6786-83-0 18.06.2012 Carcinogenic N,N,N',N'-tetramethyl-4,4'- methylenedianiline (Michler s base) 1,3,5-tris[(2S and 2R)-2,3- epoxypropyl]-1,3,5-triazine- 2,4,6-(1H,3H,5H)-trione (TGIC) Diboron trioxide 1,2-bis(2- methoxyethoxy)ethane (TEGDME; triglyme) 4,4'-bis(dimethylamino)-4''- (methylamino)trityl alcohol [with 0.1% of Michler's ketone (EC No. 202-027-5) or Michler's base (EC No. 202-959-2)] Lead(II) bis(methanesulfonate) 202-959-2 1-61-1 18.06.2012 Carcinogenic 423-400-0 59653-74-6 18.06.2012 Mutagenic (Article 57b) 215-125-8 1303-86-2 18.06.2012 Toxic for 203-977-3 112-49-2 18.06.2012 Toxic for 209-218-2 561-41-1 18.06.2012 Carcinogenic 401-750-5 17570-76-2 18.06.2012 Toxic for Formamide 200-842-0 75-12-7 18.06.2012 Toxic for [4-[4,4'-bis(dimethylamino) benzhydrylidene]cyclohexa- 2,5-dien-1- ylidene]dimethylammonium chloride (C.I. Basic Violet 3) [with 0.1% of Michler's ketone (EC No. 202-027-5) or Michler's base (EC No. 202-959-2)] 208-953-6 548-62-9 18.06.2012 Carcinogenic 13/23 13
1,2-dimethoxyethane; ethylene glycol dimethyl ether (EGDME) [4-[[4-anilino-1-naphthyl][4- (dimethylamino)phenyl]meth ylene]cyclohexa-2,5-dien-1- ylidene] dimethylammonium chloride (C.I. Basic Blue 26) [with 0.1% of Michler's ketone (EC No. 202-027-5) or Michler's base (EC No. 202-959-2)] 203-794-9 1-71-4 18.06.2012 Toxic for 219-943-6 2580-56-5 18.06.2012 Carcinogenic 1,3,5-Tris(oxiran-2-ylmethyl)- 1,3,5-triazinane-2,4,6-trione (TGIC) 4,4'-bis(dimethylamino)- benzophenone (Michler s ketone) 4-(1,1,3,3-tetramethylbutyl)- phenol N,N-dimethylacetamide 219-514-3 2451-62-9 18.06.2012 Mutagenic (Article 57b) 202-027-5 90-94-8 18.06.2012 Carcinogenic 205-426-2 140-66-9 19.12.2011 Equivalent to the environment (article 57 f) 204-826-4 127-19-5 19.12.2011 Toxic for (article 57 c) Phenolphthalein 201-004-7 77-09-8 19.12.2011 Carcinogenic Lead diazide, Lead azide Lead dipicrate 1,2-dichloroethane Calcium arsenate 236-542-1 13424-46-9 19.12.2011 Toxic for (article 57 c), 229-335-2 6477-64-1 19.12.2011 Toxic for (article 57 c) 203-458-1 7-06-2 19.12.2011 Carcinogenic 231-904-5 7778-44-1 19.12.2011 Carcinogenic 14/23 14
Dichromium tris(chromate) 246-356-2 24613-89-6 19.12.2011 Carcinogenic 2-Methoxyaniline; o-anisidine 201-963-1 90-04-0 19.12.2011 Carcinogenic Pentazinc chromate 256-418-0 49663-84-5 19.12.2011 Carcinogenic octahydroxide Arsenic acid Potassium hydroxyoctaoxodizincatedichromate Formaldehyde, oligomeric reaction products with aniline Lead styphnate Trilead diarsenate Zirconia Aluminosilicate Refractory Ceramic Fibres are fibres covered by index number 650-017-00-8 in Annex VI, part 3, table 3.1 of Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, and fulfil the three following conditions: a) oxides of aluminium, silicon and zirconium are the main components present (in the fibres) within variable concentration ranges b) fibres have a length weighted geometric mean diameter less two standard geometric errors of 6 or less micrometres (µm). c) alkaline oxide and alkali earth oxide (Na2O+K2O+CaO+MgO+BaO ) content less or equal to 18% by weight 231-901-9 7778-39-4 19.12.2011 Carcinogenic 234-329-8 113-86-9 19.12.2011 Carcinogenic 500-036-1 25214-70-4 19.12.2011 Carcinogenic 239-290-0 15245-44-0 19.12.2011 Toxic for (article 57 c) 222-979-5 3687-31-8 19.12.2011 Carcinogenic and toxic for (articles 57 a and 57 c) 19.12.2011 Carcinogenic 15/23 / ED/95/2012 15
Bis(2-methoxyethyl) phthalate Aluminosilicate Refractory Ceramic Fibres are fibres covered by index number 650-017-00-8 in Annex VI, part 3, table 3.1 of Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, and fulfil the three following conditions: a) oxides of aluminium and silicon are the main components present (in the fibres) within variable concentration ranges b) fibres have a length weighted geometric mean diameter less two standard geometric errors of 6 or less micrometres (µm) c) alkaline oxide and alkali earth oxide (Na 2 O+K 2 O+CaO+MgO+Ba O) content less or equal to 18% by weight Bis(2-methoxyethyl) ether 2,2'-dichloro-4,4'- methylenedianiline 204-212-6 117-82-8 19.12.2011 Toxic for (article 57 c) 19.12.2011 Carcinogenic 203-924-4 111-96-6 19.12.2011 Toxic for (article 57 c) 202-918-9 1-14-4 19.12.2011 Carcinogenic Cobalt dichloride 231-589-4 7646-79-9 2011/06/20-2008//28 1,2-Benzenedicarboxylic acid, di-c6-8-branched alkyl esters, C7-rich Carcinogenic and toxic for (articles 57 a and 57 c) 276-158-1 71888-89-6 20.06.2011 Toxic for (article 57c) / ED/95/2012 ED/31/2011 / ED/31/2011 16/23 16
1,2-Benzenedicarboxylic acid, di-c7-11-branched and linear alkyl esters 271-084-6 68515-42-4 Strontium chromate 232-142-6 7789-06- 2 1-Methyl-2-pyrrolidone 1,2,3-Trichloropropane 2-Ethoxyethyl acetate Hydrazine Hydrazine 206-114-9 7803-57- 8 Cobalt(II) diacetate Cobalt(II) sulphate 233-334-2 124-43-3 2-Ethoxyethanol Acids generated from chromium trioxide and their oligomers. Names of the acids and their oligomers: Chromic acid, Dichromic acid, Oligomers of chromic acid and dichromic acid. 20.06.2011 Toxic for (article 57c) 20.06.2011 Carcinogenic (article 57a) 212-828-1 872-50-4 20.06.2011 Toxic for (article 57c) 202-486-1 96-18-4 20.06.2011 Carcinogenic and toxic for (articles 57 a and 57 c) 203-839-2 111-15-9 20.06.2011 Toxic for (article 57c) 206-114-9 302-01-2 20.06.2011 Carcinogenic (article 57a) 20.06.2011 Carcinogenic (article 57a) 200-755-8 71-48-7 15.12.20 Carcinogenic and toxic for (articles 57 a and 57 c) 15.12.20 Carcinogenic and toxic for (articles 57 a and 57 c) 203-804-1 1-80-5 15.12.20 Toxic for (article 57c) 231-801-5, 236-881-5 13530-68-2 15.12.20 Carcinogenic (article 57a) ED/31/20 11 ED/31/20 11 ED/31/20 11 ED/31/20 11 ED/31/20 11 ED/31/20 11 ED/31/20 11 ED/95/20 ED/95/20 ED/95/20 ED/95/20 17/23 17
Acids generated from chromium trioxide and their oligomers. Names of the acids and their oligomers: Chromic acid, Dichromic acid, Oligomers of chromic acid and dichromic acid. 2-Methoxyethanol 231-801-5, 236-881-5 7738-94- 5 Chromium trioxide 215-607-8 1333-82- 0 Cobalt(II) carbonate Cobalt(II) dinitrate 233-402-1 141-05-6 Trichloroethylene Potassium dichromate 231-906-6 7778-50- 9 Tetraboron disodium heptaoxide, hydrate 15.12.20 Carcinogenic (article 57a) 203-713-7 9-86-4 15.12.20 Toxic for (article 57c) 15.12.20 Carcinogenic and mutagenic (articles 57 a and 57 b) 208-169-4 513-79-1 15.12.20 Carcinogenic and toxic for (articles 57 a and 57 c) 15.12.20 Carcinogenic and toxic for (articles 57 a and 57 c) 201-167-4 79-01-6 18.06.20 Carcinogenic 18.06.20 Carcinogenic, mutagenic and toxic for (articles 57 a, 57 b and 57 c) 235-541-3 12267-73-1 Ammonium dichromate 232-143-1 7789-09- 5 Boric acid 233-139-2, 234-343-4 043-35-3 18.06.20 Toxic for (article 57 c) 18.06.20 Carcinogenic, mutagenic and toxic for (articles 57 a, 57 b and 57 c) 18.06.20 Toxic for (article 57 c) ED/95/20 ED/95/20 ED/95/20 ED/95/20 ED/95/20 ED/30/20 ED/30/20 ED/30/20 ED/30/20 ED/30/20 18/23 18
Boric acid 233-139-2, 234-343-4 Sodium chromate Disodium tetraborate, anhydrous 11113-50-1 18.06.20 Toxic for (article 57 c) 231-889-5 7775-11-3 18.06.20 Carcinogenic, mutagenic and toxic for (articles 57 a, 57 b and 57 c) 215-540-4 1303-96-4 18.06.20 Toxic for (article 57 c) ED/30/20 ED/30/20 ED/30/20 Disodium tetraborate, anhydrous 215-540-4 1330-43-4 18.06.20 Toxic for (article 57 c) ED/30/20 Disodium tetraborate, 215-540-4 12179-04-3 18.06.20 Toxic for anhydrous (article 57 c) Potassium chromate 232-140-5 7789-00-6 18.06.20 Carcinogenic and mutagenic (articles 57 a and 57 b). Acrylamide 201-173-7 79-06-1 30.03.20 Carcinogenic and mutagenic (articles 57 a and 57 b) Lead sulfochromate 215-693-7 1344-37-2 13.01.20 Carcinogenic and yellow (C.I. Pigment toxic for Yellow 34) (articles 57 a and 57 Lead chromate molybdate sulphate red (C.I. Pigment Red 4) Anthracene oil 2,4-Dinitrotoluene Anthracene oil, anthracene paste, anthracene fraction Anthracene oil, anthracene-low Tris(2-chloroethyl) phosphate c)) 235-759-9 12656-85-8 13.01.20 Carcinogenic and toxic for (articles 57 a and 57 c) 292-602-7 90640-80-5 13.01.20 Carcinogenic, PBT and vpvb (articles 57a, 57d and 57e) 204-450-0 121-14-2 13.01.20 Carcinogenic (article 57a) 295-275-9 91995-15-2 13.01.20 Carcinogenic,mutage nic.pbt and vpvb (articles 57a, 57b, 57d and 57e) 292-604-8 90640-82-7 13.01.20 Carcinogenic, mutagenic, PBT and vpvb (articles 57a, 57b, 57d and 57e) 204-118-5 115-96-8 13.01.20 Toxic for (article 57c) ED/30/20 ED/30/20 ED/68/2009 ED/68/2009 ED/68/2009 ED/68/2009 ED/68/2009 ED/68/2009 ED/68/2009 ED/68/2009 19/23 19
Diisobutyl phthalate 201-553-2 84-69-5 13.01.20 Toxic for ED/68/2009 (article 57c) Lead chromate 231-846-0 7758-97-6 13.01.20 Carcinogenic and toxic ED/68/2009 for (articles 57 a and 57 c) Anthracene oil, anthracene paste Pitch, coal tar, high temp. Anthracene oil, anthracene paste,distn. lights Lead hydrogen arsenate Benzyl butyl phthalate (BBP) Bis (2- ethylhexyl)phthalate (DEHP) 5-tert-butyl-2,4,6- trinitro-m-xylene (musk xylene) Diarsenic trioxide Bis(tributyltin)oxide (TBTO) 292-603-2 90640-81-6 13.01.20 CarcinogenicPBT and vpvb (articles 57a, 57b, 57d and 57e) 266-028-2 65996-93-2 13.01.20 Carcinogenic, PBT and vpvb (articles 57a, 57d and 57e) 295-278-5 91995-17-4 13.01.20 Carcinogenic, PBT and vpvb (articles 57a, 57b, 57d and 57e) 232-064-2 7784-40-9 28..2008 Carcinogenic and toxic for (articles 57 a and 57 c) 201-622-7 85-68-7 28..2008 Toxic for (article 57c) 204-211-0 117-81-7 28..2008 Toxic for (article 57c) 20/23 ED/68/2009 ED/68/2009 ED/68/2009 201-329-4 81-15-2 28..2008 vpvb (article 57e) 215-481-4 1327-53-3 28..2008 Carcinogenic (article 57a) 200-268-0 56-35-9 28..2008 PBT (article 57d) Triethyl arsenate 427-700-2 15606-95-8 28..2008 Carcinogenic (article 57a) Diarsenic pentaoxide 215-116-9 1303-28-2 28..2008 Carcinogenic (article 57a) Sodium dichromate 234-190-3 588-01-9 28..2008 Carcinogenic, mutagenic and toxic for (articles 57a, 57b and 57c) Sodium dichromate 234-190-3 7789-12-0 28..2008 Carcinogenic, mutagenic and toxic for (articles 57a, 57b and 57c) 20
Dibutyl phthalate (DBP) 201-557-4 84-74-2 28..2008 Toxic for (article 57c) 4,4'- 202-974-4 1-77-9 28..2008 Carcinogenic (article Diaminodiphenylmeth 57a) ane (MDA) Alkanes, C-13, 287-476-5 85535-84-8 28..2008 PBT and vpvb chloro (Short Chain articles 57 d and 57 e) Chlorinated Paraffins) Anthracene Hexabromocyclodode cane (HBCDD) and all major diastereoisomers identified: Alpha-hexabromocyclo-dodecane Beta-hexabromocyclododecane Gamma-hexabromocyclododecane Hexabromocyclodode cane (HBCDD) and all major diastereoisomers identified: Alpha-hexabromocyclododecane Beta-hexabromocyclo-dodecane Gamma-hexabromo- 204-371-1 120-12-7 28..2008 PBT (article 57d) 247-148-4 25637-99-4 28..2008 PBT and (article 57d) 221-695-9 247-148-4 and 221-695-9 247-148-4 and 221-695-9 3194-55-6 28..2008 PBT (article 57d) cyclododecane Hexabromocyclodode cane (HBCDD) and all major diastereoisomers identified: Alpha-hexabromocyclododecane Betahexabromocyclodode cane Gamma-hexabromocyclododecane 134237-50- 6 28..2008 PBT (article 57d) 21/23 21
Hexabromocyclodode cane (HBCDD) and all major diastereoisomers identified: Alphahexabromocyclododecane Betahexabromocyclodode cane Gammahexabromocyclododecane Hexabromocyclodode cane (HBCDD) and all major diastereoisomers identified: Alphahexabromocyclododecane Betahexabromocyclodode cane Gammahexabromocyclododecane 247-148-4 and 221-695-9 247-148-4 and 221-695-9 134237-51- 7 134237-52- 8 28..2008 PBT (article 57d) 28..2008 PBT (article 57d) Table 4: Authorisation List 21 November 2012 Substance Name EC Number CAS Number Sunset date Latest application date Hexabromocyclododecane (HBCDD), alphahexabromocyclododecane, beta-hexabromocyclododecane, gammahexabromocyclododecane 221-695-9, 247-148-4 3194-55-6, 25637-99-4, 134237-50-6, 134237-51-7, 134237-52-8 21.08.2015 21.02.2014 2,4-Dinitrotoluene (2,4-DNT) 204-450-0 121-14-2 21.08.2015 21.02.2014 Tris(2-chloroethyl)phosphate (TCEP) 204-118-5 115-96-8 21.08.2015 21.02.2014 Diarsenic pentaoxide 215-116-9 1303-28-2 21.05.2015 21.11.2013 Diarsenic trioxide 215-481-4 1327-53-3 21.05.2015 21.11.2013 Lead sulfochromate yellow (C.I. Pigment Yellow 34) 215-693-7 1344-37-2 21.05.2015 21.11.2013 Lead chromate 231-846-0 7758-97-6 21.05.2015 21.11.2013 Lead chromate molybdate sulphate red (C.I. Pigment Red 4) 235-759-9 12656-85-8 21.05.2015 21.11.2013 22/23 Exempted (categories of) uses 22
Benzyl butyl phthalate (BBP) 201-622-7 85-68-7 Bis(2-ethylhexyl) phthalate (DEHP) 21.02.2015 21.08.2013 Uses in the immediate packaging of medicinal products covered under Regulation (EC) No 726/2004, Directive 2001/82 /EC, and/or Directive 2001/83/EC. 204-211-0 117-81-7 21.02.2015 21.08.2013 Uses in the immediate packaging of medicinal products covered under Regulation (EC) No 726/2004, Directive 2001/82/EC, and/or Directive 2001/83/EC. Dibutyl phthalate (DBP) 201-557-4 84-74-2 21.02.2015 21.08.2013 Uses in the immediate packaging of medicinal products covered under Regulation (EC) No 726/2004, Directive 2001/82 /EC, and/or Directive 2001/83/EC. Diisobutyl phthalate (DIBP) 201-553-2 84-69-5 21.02.2015 21.08.2013 5-tert-butyl-2,4,6-trinitro-mxylene (Musk xylene) 4,4'-Diaminodiphenylmethane (MDA) 201-329-4 81-15-2 21.08.2014 21.02.2013 202-974-4 1-77-9 21.08.2014 21.02.2013 23/23 23