Preparation of core-shell Fe3O4@poly(dopamine) magnetic nanoparticles for biosensor construction. Supplementary materials



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Supplementary materials Figure SM1. Thermal analysis (TG and TDA) of Fe 3 O 4 (A) and Fe 3 O 4 @pda (B) nanoparticles. Supplementary Material 1

Figure SM2. Funcionalized magnetic nanoparticles (Fe 3 O 4 @pda/hrp) under magnetic field. Supplementary Material 2

Figure SM3. CVs for GCE/Fe 3 O 4 @pda recorded in PBS solution, ph 7.4 containing 1.5 mm HQ and 0, 0.2, 0.6, 1 mm H 2 O 2 (scan rate: 100 mv/s). Supplementary Material 3

Figure SM4. Dependence of the: amount of Fe 3 O 4 @pda/hrp nanoparticles (A), applied potential (B), ph of PBS solution (C) and hydroquinone concentration (D) on the current response for 0.5 mm H 2 O 2 (in PBS containing 1.5 mm HQ) at GCE/Fe 3 O 4 @pda/hrp. Supplementary Material 4

Figure SM5. (A) Dependence of the temperature on the current response for 0.5 mm H 2 O 2 (in PBS containing 1.5 mm HQ) at GCE/Fe 3 O 4 @pda/hrp and (B) Semi-log Arrhenius-type plot obtained for previous data. Supplementary Material 5

Figure SM6. (A) Chronoamperograms obtained for 0.0-1.0 mm H 2 O 2 (in PBS, ph 7.4, containing 1.5 mm HQ at GCE/Fe 3 O 4 @pda/hrp (E app = -0.15 V) (B) plots of I vs. t -1/2 obtained from the data of (A); (C) plot of the absolute values of the slopes (m i ) obtained from (B) vs. the concentration of H 2 O 2. Supplementary Material 6

Table SM1. Possible interferents tested with the GCE/Fe 3 O 4 @pda/hrp biosensor. Supplementary Material 7