SAFETY DATA SHEET Kölner Classic Caselo

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1 SAFETY DATA SHEET Köln Classc Casl accn t Rlatn (EC) N. 1907/2006 (REACH) Rsn at: Pnt at: Vsn: 1.0 Pa 1/11 SECTION 1: Intfcatn f th sbstanc/mxt an f th cmpany/ntan 1.1. Pt ntf Ta nam/snatn: Köln Classc Casl Atcl N.: 1510 l p 1.2. Rlant ntf ss f th sbstanc mxt an ss as aanst Us f th sbstanc/mxt: Pants an anshs, Pfssnal s, Atsts spply. F pfssnal s nly. n ln n 1.3. Dtals f th sppl f th safty ata sht Manfact/Sppl: KVP Köln Vlp GmbH Dhna Staß Dsn GERMANY Tlphn: +49 (0) Tlfax: +49 (0) Wbst: E-Mal (cmptnt psn): nf@ln-lp Emncy tlphn nmb +49 (0) (Only aalabl n ffc hs.) SECTION 2: Hazas ntfcatn 2.1. Classfcatn f th sbstanc mxt Classfcatn accn t Rlatn (EC) N. 1272/2008 [CLP]: Haza classs an haza Haza statmnts cats Rspaty sn snstsatn H317: May cas an allc sn actn. (Sn Sns. 1) Classfcatn pc 2.2. Labl lmnts Lablln accn t Rlatn (EC) N. 1272/2008 [CLP] Haza pctams: GHS07 Exclamatn ma Snal w: Wann Haza cmpnnts f lablln: actn mass f: 5-chl-2-mthyl-4-sthazln-3-n [EC n ]; an 2-mthyl-2H - sthazl-3-n [EC n ] (3:1); actn mass f: 5-chl-2-mthyl-4-sthazln-3-n [EC n ]; an 2-mthyl-4-sthazln-3-n [EC n ] (3:1) p n ln n l lp tn s à p t KVP Köln Vlp GmbH Phn: Fax: nf@ln-lp.

2 l SAFETY DATA SHEET Köln Classc Casl accn t Rlatn (EC) N. 1907/2006 (REACH) Rsn at: Pnt at: Vsn: 1.0 Pa 2/11 Haza statmnts f halth hazas Pcatnay statmnts Pntn Pcatnay statmnts Rspns p H317 May cas an allc sn actn. P280.3 Wa ptct ls an ptct clthn. P302 + P352 IF ON SKIN: Wash wth plnty f sap an wat. P333 + P313 If sn tatn ash ccs: Gt mcal ac/attntn Oth hazas n ln n As hman halth ffcts an symptms: May cas sn tatn. May cas y tatn. SECTION 3: Cmpstn / nfmatn n nnts 3.1. Mxts Dscptn: Lm-Dspsn n aqs sltn, Dystff, Ats Hazas nnts / Hazas mpts / Stablss: Pt ntfs Sbstanc nam Cncntatn Classfcatn accn t Rlatn (EC) N.1272/2008 [CLP] CAS N.: EC N.: Mabl Wt % CAS N.: actn mass f: 5-chl-2-mthyl-4-sthazln-3-n [EC n ]; an 2-mthyl-2H -sthazl-3-n [EC n ] (3:1); actn mass f: 5-chl-2- mthyl-4-st hazln-3-n [EC n ]; an 2-mthyl-4-sthazln-3-n [EC n ] (3:1) Sn C. 1B, Act Tx. 3, Sn Sns. 1, Aqatc Act 1, Aqa. Chnc Wt % Dan H301-H311-H314-H317-H331-H410 Fll txt f H- an EUH-phass: s sctn 16. p n ln n l lp tn s à p t KVP Köln Vlp GmbH Phn: Fax: nf@ln-lp.

3 l SAFETY DATA SHEET Köln Classc Casl accn t Rlatn (EC) N. 1907/2006 (REACH) Rsn at: Pnt at: Vsn: 1.0 Pa 3/11 p n SECTION 4: Fst a mass 4.1. Dscptn f fst a mass Gnal nfmatn: Rm ctm t f th an aa. Rm cntamnat, satat clthn. If ncnscs plac n cy pstn an s mcal ac. D nt la affct psn nattn. Gt mcal ac/attntn f y fl nwll. Fllwn nhalatn: P fsh a. In cas f sn cntact: Wash wth plnty f sap an wat. If sn tatn ash ccs: Gt mcal ac/attntn. Aft y cntact: In cas f cntact wth ys, ns thhly wth wat. In cas f y tatn cnslt an phthalmlst. Aft nstn: Rns mth mmatly an n plnty f wat. Gt mcal ac/attntn. ln n 4.2. Mst mptant symptms an ffcts, bth act an lay May cas an allc sn actn. May cas sn tatn. May cas y tatn Incatn f any mmat mcal attntn an spcal tatmnt n Tat symptmatcally. SECTION 5: Ffhtn mass 5.1. Extnshn ma Stabl xtnshn ma: C-nat f-fhtn mass t th f snns Spcal hazas asn fm th sbstanc mxt Th pt tslf s nt bn. N spcal f ptctn mass a ncssay Hazas cmbstn pts: In cas f f may b lbat: Gass/aps, txc 5.3. Ac f ffhts Wa a slf-cntan bathn appaats an chmcal ptct clthn Atnal nfmatn Cllct cntamnat f xtnshn wat spaatly. D nt allw ntn ans sfac wat. p n ln n l lp tn s à p t KVP Köln Vlp GmbH Phn: Fax: nf@ln-lp.

4 l SAFETY DATA SHEET Köln Classc Casl accn t Rlatn (EC) N. 1907/2006 (REACH) Rsn at: Pnt at: Vsn: 1.0 Pa 4/11 SECTION 6: Accntal las mass 6.1. Psnal pcatns, ptct qpmnt an mncy pcs F nn-mncy psnnl Psnal pcatns: A cntact wth ys an sn. Rm cntamnat, satat clthn. Cla splls mmatly Ptct qpmnt: Wa ptct ls/ptct clthn/y ptctn/fac ptctn. p F mncy spns n n Psnal ptctn qpmnt: Psnal ptctn qpmnt: s sctn 8 ln 6.2. Ennmntal pcatns D nt allw t nt nt sfac wat ans. D nt allw t nt nt sl/sbsl Mths an matal f cntanmnt an clann p F cntanmnt: Wp p wth absbnt matal (. clth, flc). Hanln la qantts: Absb wth lqbnn matal (.. san, atmacs ath, ac- nsal bnn ants). F clann p: Wat wth tns at 6.4. Rfnc t th sctns Saf hanln: s sctn 7 Psnal ptctn qpmnt: s sctn 8 Dspsal: s sctn Atnal nfmatn Us apppat cntan t a nnmntal cntamnatn. SECTION 7: Hanln an sta 7.1. Pcatns f saf hanln Ptct mass Acs n saf hanln: A cntact wth sn, ys an clths. Rm cntamnat, satat clthn. Wash cntamnat clthn p t -s. Wa psnal ptctn qpmnt (f t sctn 8). F pnt mass: N spcal mass a ncssay. Ennmntal pcatns: Dscha nt th nnmnt mst b a. Acs n nal ccpatnal hyn Whn sn nt at, n sm. Wash hans an fac bf bas an aft w an ta a shw f ncssay. Apply sn ca pts aft w. p n ln n l lp tn s à p t KVP Köln Vlp GmbH Phn: Fax: nf@ln-lp.

5 l SAFETY DATA SHEET Köln Classc Casl accn t Rlatn (EC) N. 1907/2006 (REACH) Rsn at: Pnt at: Vsn: 1.0 Pa 5/11 p 7.2. Cntns f saf sta, ncln any ncmpatblts Tchncal mass an sta cntns: Kp cntan thtly cls n a cl, wll-ntlat plac. Cntns t a: Fst, Hat, UV-aatn/snlht. Rqmnts f sta ms an ssls: Fls shl b mps, sstant t lqs an asy t clan. Kp/St nly n nal cntan. Hnts n sta assmbly: Kp away fm f, n an anmal fnstffs. Sta class: 12 nn-cmbstbl lqs that cannt b assn t any f th ab sta classs 7.3. Spcfc n s(s) n n Rcmmnatn: Pants an anshs, Pfssnal s, Atsts spply. Obs nsttns f s. ln SECTION 8: Exps cntls/psnal ptctn 8.1. Cntl Paamts Occpatnal xps lmt als Lmt al typ (cnty) Sbstanc nam 1 Ln-tm ccpatnal xps lmt al 2 Sht-tm ccpatnal xps lmt al 3 Instantans al 4 Mntn an bsatn pcsss 5 Rma WEL (GB) Mabl CAS N.: m/m³ 5 (nhalabl factn) WEL (GB) Mabl CAS N.: m/m³ 5 (spabl factn) Blcal lmt als N ata aalabl DNEL-/PNEC-als N ata aalabl Exps cntls Apppat nnn cntls Tchncal mass an th applcatn f stabl w pcsss ha pty psnal ptctn qpmnt. Vntlat affct aa. p n ln n l lp tn s à p t KVP Köln Vlp GmbH Phn: Fax: nf@ln-lp.

6 l SAFETY DATA SHEET Köln Classc Casl accn t Rlatn (EC) N. 1907/2006 (REACH) Rsn at: Pnt at: Vsn: 1.0 Pa 6/ Psnal ptctn qpmnt Ey/fac ptctn: Flln an tansf: Ey lasss wth s ptctn (DIN EN 166). Sn ptctn: Tst ptct ls mst b wn (DIN EN 374). Th qalty f th ptct ls sstant t chmcals mst b chsn as a fnctn f th spcfc wn plac cncntatn an qantty f hazas sbstancs. F spcal ppss, t s cmmn t chc th sstanc t chmcals f th ptct ls mntn ab tth wth th sppl f ths ls. In th cas f wantn t s th ls aan, clan thm bf tan ff an a thm wll. Rspaty ptctn: Usally n psnal spat ptctn ncssay. P aqat ntlatn. Wa bathn appaats f xps t aps/sts/asls. Us apppat spaty ptctn. Patcl flt c (DIN EN 143), Flt typ: P2 Oth ptctn mass: Wa stabl ptct clthn. p n ln n Ennmntal xps cntls N ata aalabl Atnal nfmatn N ata aalabl. SECTION 9: Physcal an chmcal ppts 9.1. Infmatn n basc physcal an chmcal ppts Appaanc Physcal stat: lq Cl: ffnt, pnn n clatn O: nt tmn Safty lant bass ata Paamt at C Mth Rma ph nt tmn Mltn pnt/fzn pnt Fzn pnt Intal bln pnt an bln an Dcmpstn tmpat Flash pnt nt tmn nt tmn 100 C nt tmn nt applcabl p n ln n l lp tn s à p t KVP Köln Vlp GmbH Phn: Fax: nf@ln-lp.

7 l SAFETY DATA SHEET Köln Classc Casl accn t Rlatn (EC) N. 1907/2006 (REACH) Rsn at: Pnt at: Vsn: 1.0 Pa 7/11 Eapatn at Intn tmpat p n Upp/lw flammablty xpls lmts Vap pss Vap nsty ln n nt tmn nt applcabl nt applcabl nt tmn nt applcabl Dnsty /ml 20 Bl nsty Wat slblty Pattn cffcnt: n-ctanl/wat Dynamc scsty Knmatc scsty nt applcabl spsbl nt tmn nt tmn nt tmn 9.2. Oth nfmatn N ata aalabl. SECTION 10: Stablty an actty Ractty Th pt tslf s nt bn Chmcal stablty Th pt s stabl n sta at nmal ambnt tmpats Pssblty f hazas actns N hazas actn whn hanl an st accn t psns Cntns t a Fst, Hat, UV-aatn/snlht Incmpatbl matals Oxzn ant, stn Hazas cmpstn pts In cas f f may b lbat: Gass/aps, txc p n ln n l lp tn s à p t KVP Köln Vlp GmbH Phn: Fax: nf@ln-lp.

8 l SAFETY DATA SHEET Köln Classc Casl accn t Rlatn (EC) N. 1907/2006 (REACH) Rsn at: Pnt at: Vsn: 1.0 Pa 8/11 p n SECTION 11: Txclcal nfmatn Infmatn n txclcal ffcts Act al txcty: Bas n aalabl ata, th classfcatn cta a nt mt. Act mal txcty: Bas n aalabl ata, th classfcatn cta a nt mt. Act nhalatn txcty: Bas n aalabl ata, th classfcatn cta a nt mt. Sn csn/tatn: Bas n aalabl ata, th classfcatn cta a nt mt. May cas sn tatn. Ey ama/tatn: Bas n aalabl ata, th classfcatn cta a nt mt. May cas y tatn. Rspaty sn snstsatn: May cas an allc sn actn. Gm cll mtancty: Bas n aalabl ata, th classfcatn cta a nt mt. Cacnncty: Bas n aalabl ata, th classfcatn cta a nt mt. Rpt txcty: Bas n aalabl ata, th classfcatn cta a nt mt. STOT-snl xps: Bas n aalabl ata, th classfcatn cta a nt mt. STOT-pat xps: Bas n aalabl ata, th classfcatn cta a nt mt. Aspatn haza: Bas n aalabl ata, th classfcatn cta a nt mt. Atnal nfmatn: N ata aalabl. ln n SECTION 12: Eclcal nfmatn Txcty Aqatc txcty: Bas n aalabl ata, th classfcatn cta a nt mt. Effcts n swa plants: Th nslbl pat can b pcptat mchancally n stabl swa tatmnt plants. Atnal ctxclcal nfmatn: Dscha nt th nnmnt mst b a. D nt mpty nt ans. D nt allw t nt nt sl/sbsl Psstnc an aablty Baatn: Th mths f tmnn th blcal aablty a nt applcabl t nanc sbstancs. Sm f th cmpnnts a ply baabl Baccmlat ptntal Amlatn / Ealatn: N ncatn f baccmlatn ptntal Mblty n sl N ata aalabl Rslts f PBT an PB assssmnt Th sbstancs n th mxt nt mt th PBT/PB cta accn t REACH, annx III. p n ln n l lp tn s à p t KVP Köln Vlp GmbH Phn: Fax: nf@ln-lp.

9 l SAFETY DATA SHEET Köln Classc Casl accn t Rlatn (EC) N. 1907/2006 (REACH) Rsn at: Pnt at: Vsn: 1.0 Pa 9/ Oth as ffcts N ata aalabl. p n SECTION 13: Dspsal cnsatns Wast tatmnt mths Pt/Pacan spsal Wast cs/wast snatns accn t EWC/AVV Wast c pt: wast pant an ansh th than ths mntn n Wast c pacan: Mx cnsttn an mltn wasts th than ths mntn n , an Plastc pacan plastc Wast tatmnt ptns: Apppat spsal / Pt: Dsps f wast accn t applcabl lslatn. Cnslt th apppat lcal wast spsal xpt abt wast spsal. F cycln, cntact manfact. Apppat spsal / Paca: Cmpltly mpt pacas can b cycl. Oth spsal cmmnatns: Th allcatn f wast ntty nmbs/wast scptns mst b ca t accn t th EEC, spcfc t th nsty an pcss. Cllct n cls an stabl cntans f spsal. ln n Atnal nfmatn Wast f spsal s t b classf an labll. SECTION 14: Tanspt nfmatn N ans n sns f ths tanspt latns UN-N. nt lant UN pp shppn nam nt lant Tanspt haza class(s) nt lant p n ln n l lp tn s à p t KVP Köln Vlp GmbH Phn: Fax: nf@ln-lp.

10 l SAFETY DATA SHEET Köln Classc Casl accn t Rlatn (EC) N. 1907/2006 (REACH) Rsn at: Pnt at: Vsn: 1.0 Pa 10/ Pacn p nt lant Ennmntal hazas nt lant p Spcal pcatns f s nt lant n ln n Tanspt n bl accn t Annx II f MARPOL 73/78 an th IBC C nt lant SECTION 15: Rlaty nfmatn Safty, halth an nnmntal latns/lslatn spcfc f th sbstanc mxt EU lslatn Oth latns (EU): Ths pt mts th qmnts f Rlatn (EC) N.1935/2004 n th lmtatn f VOC cntnt Natnal latns N ata aalabl Chmcal Safty Assssmnt N ata aalabl Atnal nfmatn N ata aalabl. SECTION 16: Oth nfmatn Incatn f chans N ata aalabl Abbatns an acnyms F abbatns an acnyms, s: ECHA Ganc n nfmatn qmnts an chmcal safty assssmnt, chapt R.20 (Tabl f tms an abbatns) Ky ltat fncs an ss f ata N ata aalabl. p n ln n l lp tn s à p t KVP Köln Vlp GmbH Phn: Fax: nf@ln-lp.

11 l SAFETY DATA SHEET Köln Classc Casl accn t Rlatn (EC) N. 1907/2006 (REACH) Rsn at: Pnt at: Vsn: 1.0 Pa 11/11 p Classfcatn f mxts an s alatn mth accn t latn (EC) N. 1272/2008 [CLP] Classfcatn accn t Rlatn (EC) N. 1272/2008 [CLP]: Haza classs an haza Haza statmnts cats Rspaty sn snstsatn H317: May cas an allc sn actn. (Sn Sns. 1) Classfcatn pc n ln n Rlant R-, H- an EUH-phass (Nmb an fll txt) Haza statmnts H301 H311 H314 H317 H331 H400 H410 Txc f swallw. Txc n cntact wth sn. Cass s sn bns an y ama. May cas an allc sn actn. Txc f nhal. Vy txc t aqatc lf. Vy txc t aqatc lf wth ln lastn ffcts Tann ac N ata aalabl Atnal nfmatn Th nfmatn n ths ata sht has bn stablsh t bst nwl an was p-t-at at tm f sn. Th nfmatn s ntn t y ac abt th saf hanln f th pt nam n ths safty ata sht, f sta, pcssn, tanspt an spsal. It s nt psnt a aant f th ppts f th pt scb n tms f th lal waanty latns. p n ln n l lp tn s à p t KVP Köln Vlp GmbH Phn: Fax: nf@ln-lp.

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