X SAFETY DATA SHEET (INFORMATION FORM FOR CHEMICALS DATA) Date: 01 October 2012 Former date: 01 April 2011

Transcription

1 X SAFETY DATA SHEET (INFORMATION FORM FOR CHEMICALS DATA) Former date: 01 April 2011 (*) concerns only chemical notification (**) either 3.1 or 3.2 must be filled SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 Product identifier Trade name / Substance name Company product code 999 REACH Registration number 1.2 Relevant identified uses of the substance or mixture and uses advised against The uses of the chemical Defoaming agent. Classification of economic activities (NACE) (*) Use categories (UC62) (*) The chemical can be used by the general public (*) The chemical is used by the general public only (*) 1.3 Details of the supplier of the Safety Data Sheet Supplier (manufacturer, importer, only representative, downstream user, distributor) Responsible for placing a chemical on the market in Finland (*) TeknoForest Ltd. Street address Kynttilätie 3 Postcode and post office Postoffice box Postcode and post office FIN11710 Riihimäki Telephone number Telefax address info@pineline.fi Finnish Business ID (Y code) (*) Emergency telephone number , The central hospital of Helsinki University. SECTION 2: HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture 67/548/EEC 1999/45/EC 2.2 Label elements 67/548/EEC 1999/45/EC 2.3 Other hazards Page 1

2 SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS 3.2 Mixtures (**) Substance name CAS, EC or index number REACH Registration No. Concentration Classification Silicone oilbased emulsion. DSD: CLP: SECTION 4: FIRST AID MEASURES 4.1 Description of first aid measures Inhalation Skin Wash affected areas with soap and fresh water. Remove contaminated clothing and wash before reuse. Splashes in eyes Wash immediately and continuously with clean, copious flow of water for at least 15 min keeping eyelids open. Seek medical advise. Ingestion Do not induce vomiting. If conscious and alert, rinse mouth and drink 12 cupfuls of milk or water. Seek medical advise immediately. 4.2 Most important symptoms and effects, both acute and delayed 4.3 Indication of any immediate medical attention and special treatment needed SECTION 5: FIREFIGHTING MEASURES 5.1 Extinguishing media Nonflammable. 5.2 Special hazards arising from the substance or mixture 5.3 Advice for firefighters SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures Wear adequate personal protective equipment, see section Environmental precautions Prevent liquid of larger quantities entering to public water supplies, natural waterways or sewers. 6.3 Methods and material for containment and cleaning up Contain&collect spillage with noncombustible absorbent material. Then place into a suitable clean, dry closed container for disposal. 6.4 Reference to other sections SECTION 7: HANDLING AND STORAGE 7.1 Precautions for safe handling Avoid contact of liquid or mist with eyes and skin. Do not ingest or inhale. See the personal protective equipments in the section Conditions for safe storage, including any incompatibilities Temperature: C. Always keep packages or containers closed and away from incompatible substances. The product has a self life of 12 months when being stored in original Page 2

3 sealed containers. 7.3 Specific end use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Control parameters National occupational exposure limit values Other limit values DNEL PNEC 8.2 Exposure controls Appropriate engineering controls Eye / face protection Wear appropriate eye/face protection or chemical safety goggles (EN 166). Skin protection Wear appropriate protective clothing. Hand protection Use PVC or rubber gloves (EN 374). Respiratory protection Thermal hazards Environmental exposure controls SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties Appearance Odour Odour threshold ph 7 Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability or explosive limits Vapour pressure Vapour density White, viscous liquid. > 100 C Page 3

4 Relative density 1,0 Solubility(ies) Partition coefficient: noctanol/water Autoignition temperature Decomposition temperature Viscosity Explosive properties Oxidising properties Water solubility: Miscible Fat solubility: 1500 mpas (20 ºC) 9.2 Other information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity 10.2 Chemical stability 10.3 Possibility of hazardous reactions 10.4 Conditions to avoid The product is stable under normal temperature and pressure Incompatible materials Follow the instructions in the label. Other use forbidden Hazardous decomposition products None with proper sorage and handling. SECTION 11: TOXICOLOGICAL INFORMATION 11.1 Information on toxicological effects Acute toxicity LD50(rat, oral) > 30 ml/kg. Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOTsingle exposure STOTrepeated exposure Aspiration hazard Other information Page 4

5 SECTION 12: ECOLOGICAL INFORMATION 12.1 Toxicity Aquatic toxicity LC50(fish, 96h) > 300 mg/l Persistence and degradability 12.3 Bioaccumulative potential Not known Mobility in soil With water Results of PBT and vpvb assessment 12.6 Other adverse effects SECTION 13: DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods Place in special container and send for recycling or disposal. Wastes and empty containers must be disposed as hazardous waste taking into account local and national regulations. SECTION 14: TRANSPORT INFORMATION 14.1 UN number Not classified as hazardous for transport UN proper shipping name 14.3 Transport hazard class(es) 14.4 Packing group 14.5 Environmental hazards 14.6 Special precautions for user 14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: REGULATORY INFORMATION 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture 15.2 Chemical safety assessment SECTION 16: OTHER INFORMATION Indication of changes Updated according to regulation (EY) Nr 453/2010 of the European Parliament and Council. Abbreviations and acronyms CLP According to regulation (EY) N:o 1272/2008 DSD Classified and labelled according to directive 67/548/ETY. Key literature references and sources for data International Chemical Safety Cards (ICSCs). Hazardous Substance Data Bank. MSDS:s of raw material distributors. Legislation. Used method in evaluating classification Page 5

6 Classified and labelled according to directive 67/548/ETY. List of relevant Rand Sphrases or/and safety and precautionary statements Training advice for workers Additional information available from Page 6