Safety data sheet according to 1907/2006/EC, Article 31

Transcription

1 Page 1/9 1 Identification of the substance/mixture and of the company/undertaking Product identifier Relevant identified uses of the substance or mixture and uses advised against Sector of Use SU21 Consumer uses: Private households / general public / consumers Product category PC35 Washing and cleaning products (including solvent based products) Environmental release category ERC8b Wide dispersive indoor use of reactive substances in open systems Application of the substance / the preparation Tube cleaner/ pipe cleaning agent Details of the supplier of the safety data sheet Manufacturer/Supplier: AVT Abfüll- und Verpackungstechnik GmbH Simonshöfchen 55 D Wuppertal Tel: +49-(0) dirk.stockmeier@avt-deutschland.de Further information obtainable from: Product safety department Emergency telephone number: Phone: +49-(0) (8:00-17:00) 2 Hazards identification Classification of the substance or mixture Classification according to Directive 67/548/EEC or Directive 1999/45/EC C; Corrosive R35: Causes severe burns. Information concerning particular hazards for human and environment: The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. Classification system: The classification is according to the latest editions of the EU-lists, and extended by company and literature data. Label elements Labelling according to EU guidelines: The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous Materials. Code letter and hazard designation of product: C Corrosive Hazard-determining components of labelling: sodium hydroxide Risk phrases: 35 Causes severe burns. Safety phrases: 1/2 Keep locked up and out of the reach of children. 24/25 Avoid contact with skin and eyes. 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 27/28 After contact with skin, take off immediately all contaminated clothing, and wash immediately with plenty of water. 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). (Contd. on page 2)

2 Page 2/9 (Contd. of page 1) 64 If swallowed, rinse mouth with water (only if the person is conscious). Special labelling of certain preparations: Warning! Do not use together with other products. May release dangerous gases (chlorine). Other hazards Results of PBT and vpvb assessment PBT: The product does not contain any PBT substance or does not fulfil criteria for PBT according to annex XIII of regulation (EC) 1907/2006. vpvb: The product does not contain any vpvb substance or does not fulfil criteria for vpvb according to annex XIII of regulation (EC) 1907/ Composition/information on ingredients Chemical characterization: Mixtures Description: Cleansing agent Dangerous components: CAS: EINECS: CAS: EINECS: CAS: EC number: Reg.nr.: REACH: sodium hydroxide C R35 Skin Corr. 1A, H314 Sodium hypochlorite C R34; N R50 R31 Skin Corr. 1B, H314; Aquatic Acute 1, H400 Amines, coco alkyldimethyl, N-oxides Xi R38-41; N R50 Eye Dam. 1, H318; Aquatic Acute 1, H400; Skin Irrit. 2, H315 1-<5% 1-<5% 0.1-<1% Regulation (EC) No 648/2004 on detergents / Labelling for contents chlorine-based bleaching agents, non-ionic surfactants, soap < 5% Additional information: For the wording of the listed risk phrases refer to section First aid measures Description of first aid measures General information: Immediately remove any clothing soiled by the product. After inhalation: Fresh air. If pain persists, get medical attention. After skin contact: Clean with water and soap. If possible, also wash with polyethylene glycol 400. Cover wound with a sterile dressing. Immediate medical treatment necessary. Failure to treat burns can prevent wounds from healing. After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. Protect unharmed eye. After swallowing: Rinse out mouth and drink plenty of water. Do not induce vomiting; call for medical help immediately. Information for doctor: Most important symptoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. (Contd. on page 3)

3 Page 3/9 (Contd. of page 2) 5 Firefighting measures Extinguishing media Suitable extinguishing agents: Use fire extinguishing methods suitable to surrounding conditions. For safety reasons unsuitable extinguishing agents: None known. Special hazards arising from the substance or mixture In case of fire, the following can be released: Hydrogen chloride (HCl) Carbon monoxide (CO) Advice for firefighters Protective equipment: Do not inhale explosion gases or combustion gases. Wear self-contained respiratory protective device. Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation Wear protective equipment. Keep unprotected persons away. Particular danger of slipping on leaked/spilled product. Environmental precautions: Dilute with plenty of water. Do not allow to enter sewers/ surface or ground water. Inform respective authorities in case of seepage into water course or sewage system. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. Clean the affected area carefully; suitable cleaners are: Water Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage Handling: Precautions for safe handling Observe use instructions. Open and handle receptacle with care. Avoid contact with eyes and skin. Use only in well ventilated areas. Information about fire - and explosion protection: No special measures required. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: Store in a cool location. Store only in the original receptacle. Information about storage in one common storage facility: Do not store together with acids. Further information about storage conditions: Store in a cool place. Store in dry conditions. Store under lock and key and out of the reach of children. (Contd. on page 4)

4 Page 4/9 Specific end use(s) No further relevant information available. (Contd. of page 3) 8 Exposure controls/personal protection Additional information about design of technical facilities: No further data; see item 7. Control parameters Ingredients with limit values that require monitoring at the workplace: sodium hydroxide WEL Short-term value: 2 mg/m³ DNELs sodium hydroxide Inhalative DNEL (population) 1.0 mg/m³ (long-term - local effects) DNEL (worker) 1.0 mg/m³ (long-term - local effects) Oral DNEL (population) 0.26 mg/kg bw/day (long-term - systemic effects) Inhalative DNEL (population) 1.55 mg/m³ (long-term - local effects) 1.55 mg/m³ (long-term - systemic effects) 3.1 mg/m³ (Acute/short-term exposure-local effects) DNEL (worker) 1.55 mg/m³ (long-term - local effects) 1.55 mg/m³ (long-term - systemic effects) 3.1 mg/m³ (Acute/short-term exposure-local effects) PNECs PNEC STP 0.03 mg/l (STP) PNEC aqua mg/l (freshwater) mg/l (marine water) Additional information: The lists valid during the making were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing Avoid contact with the eyes and skin. Do not inhale gases / fumes / aerosols. Respiratory protection: Use suitable respiratory protective device in case of insufficient ventilation. Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Alkaline resistant gloves Protective gloves according EN 374. Material of gloves Butyl rubber, BR Nitrile rubber, NBR PVC gloves (Contd. on page 5)

5 Page 5/9 (Contd. of page 4) Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Tightly sealed goggles Body protection: Alkaline resistant protective clothing 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Liquid Colour: Light yellow Odour: Chlorine-like Odour threshold: Not determined. ph-value at 20 C: Change in condition Melting point/melting range: Not determined. Boiling point/boiling range: > 100 C Flash point: > 100 C Flammability (solid, gaseous): Not applicable. Ignition temperature: Decomposition temperature: Not determined. Self-igniting: Product is not selfigniting. Danger of explosion: Product does not present an explosion hazard. Explosion limits: Lower: Upper: Not determined. Not determined. Vapour pressure: Not determined. Density at 20 C: ~ 1.08 g/cm³ Relative density Not determined. Vapour density Not determined. Evaporation rate Not determined. Solubility in / Miscibility with water: Soluble. Partition coefficient (n-octanol/water): Not determined. Viscosity: Dynamic at 20 C: Kinematic: Solvent content: mpas Not determined. Solids content: Other information No further relevant information available. (Contd. on page 6)

6 Page 6/9 (Contd. of page 5) 10 Stability and reactivity Reactivity Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. To avoid thermal decomposition do not overheat. Possibility of hazardous reactions Contact with acids releases toxic gases. Reacts with reducing agents. Conditions to avoid No further relevant information available. Incompatible materials: Warning! Do not use together with other products. May release dangerous gases (chlorine). Hazardous decomposition products: Hydrogen chloride (HCl) Chlorine 11 Toxicological information Information on toxicological effects Acute toxicity: LD/LC50 values relevant for classification: sodium hydroxide Oral LD mg/kg (rat) Oral LD mg/kg (rat) Dermal LD50 > mg/kg (rabbit) (OECD 402) Inhalative LC50/4 h 293 mg/l (rat) Chlor Primary irritant effect: on the skin: Caustic effect on skin and mucous membranes. on the eye: Strong caustic effect. Sensitization: No sensitizing effects known. Additional toxicological information: The product shows the following dangers according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version: Corrosive Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus and stomach. Repeated dose toxicity No further relevant information available. CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) No further relevant information available. Germ cell mutagenicity Ames test negative (bacterial reverse mutation assay) 12 Ecological information Toxicity Aquatic toxicity: EC mg/l (algae) (OECD 201) (Contd. on page 7)

7 Page 7/9 (Contd. of page 6) LC mg/l (fish) Persistence and degradability The contained surfactants are easily biodegradable Behaviour in environmental systems: Bioaccumulative potential No further relevant information available. Mobility in soil No further relevant information available. Additional ecological information: General notes: The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be made available to them, at their direct request or at the request of a detergent manufacturer. Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water Do not allow product to reach ground water, water course or sewage system. Rinse off of bigger amounts into drains or the aquatic environment may lead to increased ph-values. A high ph-value harms aquatic organisms. In the dilution of the use-level the ph-value is considerably reduced, so that after the use of the product the aqueous waste, emptied into drains, is only low water-dangerous. Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. Other adverse effects No further relevant information available. 13 Disposal considerations Waste treatment methods Recommendation Dispose of in accordance with all applicable local and national regulations. European waste catalogue * detergents containing dangerous substances * packaging containing residues of or contaminated by dangerous substances Uncleaned packaging: Recommendation: Dispose of in accordance with all applicable local and national regulations. Recommended cleansing agents: Water, if necessary together with cleansing agents. 14 Transport information UN-Number ADR, IMDG, IATA UN3266 UN proper shipping name ADR 3266 CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (SODIUM HYDROXIDE) IMDG, IATA CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (SODIUM HYDROXIDE) Transport hazard class(es) ADR, IMDG, IATA Class 8 Corrosive substances. Label 8 Packing group ADR, IMDG, IATA II (Contd. on page 8)

8 Page 8/9 Environmental hazards: Marine pollutant: No Special precautions for user Warning: Corrosive substances. Danger code (Kemler): 80 EMS Number: F-A,S-B Segregation groups Alkalis Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Transport/Additional information: ADR Limited quantities (LQ) 1L Transport category 2 Tunnel restriction code E Not applicable. (Contd. of page 7) 15 Regulatory information National regulations: Information about limitation of use: Employment restrictions concerning juveniles must be observed. Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Relevant phrases H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H318 Causes serious eye damage. H400 Very toxic to aquatic life. R31 Contact with acids liberates toxic gas. R34 Causes burns. R35 Causes severe burns. R38 Irritating to skin. R41 Risk of serious damage to eyes. R50 Very toxic to aquatic organisms. Department issuing MSDS: Chemisches Labor & Consulting - Dr. Ulrich Bönig Simonshöfchen 55, D Wuppertal Germany Tel.: +49-(0) Contact: Mr. Boenig, PhD. Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association PBT: persitent, bioaccumulative, toxic vpvb: very persistent, very bioaccumulative CAS: Chemical Abstracts Service (division of the American Chemical Society) EINECS: European Inventory of Existing Commercial Chemical Substances REACH: Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals. VCI: Verband der chemischen Industrie, Deutschland (German chemical industry association) DNEL: Derived No-Effect Level (REACH) (Contd. on page 9)

9 Page 9/9 PNEC: Predicted No-Effect Concentration (REACH) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent (Contd. of page 8)