friulsider ONE IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
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1 Pag. 1/5 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 Product identifier Product name: White (Cod. ONE5000) 1.2 Relevant identified uses of the substance or mixture and uses advised against 1.3 Details of the supplier of the safety data sheet DISTRIBUTOR Friulsider SpA, Via Trieste 1, San Giovanni al Natisone, Udine, ITALIA Tel.: Fax.: address of the competent person responsible for the SDS: 1.4 Emergency telephone number Company emergency telephone: (8.30 am 5.30 pm) 2. HAZARDS IDENTIFICATION 2.1 Classification of the mixture Classification according to Directive 67/548/EEC or Directive 1999/45/EC Not applicable Information concerning particular hazards for human and environment: The product does not have to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. Classification system: The classification is according to the latest editions of the EU-lists, and extended by company and literature data. 2.2 Label elements Labelling according to EU guidelines Observe the general safety regulations when handling chemicals. The product is not subject to identification regulations under EU Directives and the Ordinance on Hazardous Materials (German GefStoffV). Special labelling of certain preparations: Contains N-(3-(trimethoxysilyl)propyl)ethylenediamine, N-[3- (dimethoxymethylsilyl)propyl]ethylenediamine. May produce an allergic reaction. 2.3 Other hazards Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. 3. COMPOSITION/INFORMATION ON INGREDIENTS 3.1 Substances Mixtures 3.2 Mixtures Mixture of substances listed below with nonhazardous additions. Dangerous components: CAS: rimethoxyvinylsilane EINECS: Xn R20 R10 Flam. Liq. 3, H226; Acute Tox. 4, H % 4. FIRST AID MEASURES 4.1 Description of first aid measures General information: After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Generally the product does not irritate the skin. After eye contact: Rinse opened eye for several minutes under running water. After swallowing: If symptoms persist consult doctor.
2 4.2 Most important symptoms and effects, both acute and delayed 4.3 Indication of any immediate medical attention and special treatment needed 5. FIRE-FIGHTING MEASURES 5.1 Extinguishing media 5.2 Special hazards arising from the substance or mixture 5.3 Advice for fire-fighters 6. ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures 6.2 Environmental precautions Do not allow to enter sewers/ surface or ground water. 6.3 Methods and material for containment and cleaning up Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust) 6.4 Reference to other sections Reference to other sections No dangerous substances are released. See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7. HANDLING AND STORAGE 7.1 Precautions for safe handling 7.2 Conditions for safe storage, including any incompatibilities 7.3 Specific end use(s) 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Pag. 2/5 8.1 Control parameters The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. Additional information: The lists valid during the making were used as basis. 8.2 Exposure controls Personal protective equipment: General protective and hygienic measures: The usual precautionary measures are to be adhered to when handlin chemicals. Respiratory protection: Not required. Protection of hands: The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Material of gloves: The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material: The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Not required.
3 9. PHYSICAL AND CHEMICAL Pag. 3/5 9.1 Information on basic physical and chemical properties. General Information. Appearance: Form: Pasty Colour: Various Odour: Characteristic -. ph-value at 20 C: Not applicable. -. Change in condition Melting point/melting range: Not applicable. Boiling point/boiling range: Not applicable.. Flash point: Not applicable.. Ignition temperature. Self-igniting: Product is not selfigniting.. Danger of explosion: Product does not present an explosion hazard.. Explosion limits:: Lower: Not applicable. Upper: Not applicable.. Vapour pressure: Undetermined.. Solubility in / Miscibility with water: Undetermined.. Solvent content: VOC (EC) 2,28 mg/l 9.2 Other information 10. STABILITY AND REACTIVITY 10.1 Reactivity 10.2 Chemical stability No decomposition if used according to specifications Possibility of hazardous reactions No dangerous reactions known 10.4 Conditions to avoid 10.5 Incompatible materials 10.6 Hazardous decomposition products No dangerous decomposition products known. 11. TOXICOLOGICAL INFORMATION 11.1 Information on toxicological effects Primary irritant effect:. on the skin: No irritant effect.. on the eye: No irritating effect. Sensitization: No sensitizing effects known. Additional toxicological information:
4 Pag. 4/5 When used and handled according to specifications, the product does not have any harmful effects to our experience and the information provided to us 12. ECOLOGICAL INFORMATION 12.1 Toxicity 12.2 Persistence and degradability 12.3 Bioaccumulative potential 12.4 Mobility in soil Water hazard class 1 (Self-assessment): slightly hazardous for water. Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable Other adverse effects 13. DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods Disposal must be made according to official regulations. 14. TRANSPORT INFORMATION Not classified as dangerous under transport regulations 14.1 UN number 14.2 UN proper shipping name 14.3 Transport hazard class(es) 14.4 Packing group 14.5 Environmental hazards 14.6 Special precautions for Not dangerous for transport. Irritating to skin or eyes. Protect from 'moisture. Keep away from foodstuffs, acids and alkalis Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Additional information for Transport in accordance with IMDG, ADR/RID and ICAO/IATA - ADR / RID: non-dangerous goods. - ADN: non-dangerous goods. - IATA: non-dangerous goods. - IMDG: Not dangerous goods. 15. REGULATORY INFORMATION 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Chemical Safety Assessment has not been carried out Chemical Safety Assessment
5 Pag. 5/5 16. OTHER INFORMATION Relevant phrases H226 Flammable liquid and vapour. H332 Harmful if inhaled. R10 Flammable R20 Harmful by inhalation. The information contained in this Safety Data Sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of use of the product are outside the supplier s control, the user is responsible for ensuring that the requirements of relevant legislation are complied with. The information contained in this safety data sheet does not constitute the user s own assessment of workplace risks, as required by other health and safety legislation. This sheet replaces all previous versions. Bibliography ESIS European chemical Substances Information System - Joint Research Centre; Federchimica Book series of the Committee for Substances Safety, No. 2 THE MSDS Part 2 - Examples of Safety Data Sheet of a substance and a mixture prepared according to Regulation (EU) 453/2010, July Acronyms ACGIH: American Conference of Governmental Industrial Hygienists. ADN: european Agreement concerning the international carriage of Dangerous good by inland goods ADR: Agreement concerning the international carriage of Dangerous goods by Road BCF: Bio Concentration Factor CLP: Classification, Labelling and Packaging CMR: Cancérogène (ou cancérigène), Mutagène et Reprotoxique (Carcinogenic, mutagenic and toxic). DNEL: derived no effect level. EC50: Effective Concentration of a substance that causes 50% of the maximum response. ErC50: Effective Concentration of a substance that causes a 50% reduction in the growth rate. EWC: European Waste Catalogue. IATA: international air transport association. IBC, code : International Code for the Construction and Equipment of ships carrying dangerous chemical in Bulk. IMDG: International maritime dangerous goods. LC 50: Lethal Concentration for 50% of individuals. LD 50: Lethal Dose for 50% of individuals. LLNA: Local Lymph Node Assay. LOAEL: Lowest Observed Adverse Effect Level. NOAEL: No Observed Adverse Effect Level. NOEC: No Observed Effect Concentration. OECD: Organisation for Economic Co-operation and Development: Guideline for Testing of Chemicals. MARPOL73/78: Convenzione internazionale per la prevenzione dell'inquinamento causato da navi 1973, come modificata dal protocollo del PBT: Persistent, bioaccumulative and toxic. PNEC: Predicted no effect concentration. RID: Règlement concernent le transport International ferroviaire des marchandises Dangereuses (Regulation concenring the International carriage od Dangerous goods). STEL: short term exposure limit. TLV: threshold limit value. TWA: Time Weighted Average. UE/EU: European union. vpvb: Very persistent very bioaccumulative.
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