Safety data sheet according to 1907/2006/EC, Article 31

Transcription

1 Page 1/7 * 1 Identification of the substance/mixture and of the company/undertaking Product identifier Article number: CAS Number: EINECS Number: Index number: Relevant identified uses of the substance or mixture and uses advised against not determined. Application of the substance / the preparation Raw material Details of the supplier of the safety data sheet Manufacturer/Supplier: Hansa Group AG Wanheimer Str. 408 D Duisburg Tel.: +49 (0) juergen.mueller@hansagroup.de Further information obtainable from: Product safety Tel.: +49 (0) juergen.mueller@hansagroup.de Emergency telephone number: GIZ-Nord, Göttingen, Germany Member of EPECS Network 2 Hazards identification Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 GHS05 corrosion Skin Corr. 1B H314 Causes severe skin burns and eye damage. GHS07 Acute Tox. 4 Acute Tox. 4 Skin Sens. 1 H302 Harmful if swallowed. H312 Harmful in contact with skin. H317 May cause an allergic skin reaction. Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects. Classification according to Directive 67/548/EEC or Directive 1999/45/EC C; Corrosive R34: Causes burns. Xn; Harmful R21/22: Harmful in contact with skin and if swallowed. Xi; Sensitising (Contd. on page 2)

2 Page 2/7 R43: May cause sensitisation by skin contact. (Contd. of page 1) R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Label elements Labelling according to Regulation (EC) No 1272/2008 The substance is classified and labelled according to the CLP regulation. Hazard pictograms GHS05 GHS07 Signal word Danger Hazard statements H302 Harmful if swallowed. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H412 Harmful to aquatic life with long lasting effects. Precautionary statements P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/physician. Other hazards Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. * 3 Composition/information on ingredients Chemical characterization: Substances CAS No. Description N-(2-Aminoethyl)-piperazine 2-Piperazinoethylamine Identification number(s) EINECS Number: Index number: Dangerous components: CAS: EINECS: N-(2-Aminoethyl)-piperazine 2-Piperazinoethylamine C R34; Xn R21/22; Xi R43 R52/53 Skin Corr. 1B, H314; Acute Tox. 4, H302; Acute Tox. 4, H312; Skin Sens. 1, H317; Aquatic Chronic 3, H412 4 First aid measures Description of first aid measures General information: Remove contaminated, soaked clothing immediately and dispose of safely. Seek medical treatment. After inhalation: Supply fresh air. (Contd. on page 3)

3 Page 3/7 (Contd. of page 2) Seek medical treatment. After skin contact: Immediately rinse with water. Immediately remove any clothing soiled by the product. If skin irritation continues, consult a doctor. After eye contact: Rinse opened eye for several minutes under running water. Call a doctor immediately. After swallowing: Rinse out mouth and then drink plenty of water. Do not induce vomiting - aspiration hazard. Call in a physician immediately and show him the Safety Data Sheet. 5 Firefighting measures Extinguishing media Suitable extinguishing agents: Water Carbon dioxide Foam Fire-extinguishing powder Special hazards arising from the substance or mixture In case of combustion evolution of dangerous gases possible. In case of fire, the following can be released: Nitrogen oxides (NOx) Advice for firefighters Protective equipment: Wear self-contained respiratory protective device. Wear fully protective suit. Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Avoid contact with skin, eyes and clothing. Use respiratory protective device against the effects of fumes/dust/aerosol. Ensure adequate ventilation Environmental precautions: Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders). Reference to other sections See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage Handling: Precautions for safe handling Keep receptacles tightly sealed. Avoid contact with skin, eyes and clothing. Carry out filling operations only at sites with extractors available. Information about fire - and explosion protection: No special measures required. (Contd. on page 4)

4 Page 4/7 Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Not required. Further information about storage conditions: Keep container tightly sealed. Store receptacle in a well ventilated area. (Contd. of page 3) 8 Exposure controls/personal protection Additional information about design of technical facilities: No further data; see item 7. Control parameters Ingredients with limit values that require monitoring at the workplace: Not required. Additional information: The lists valid during the making were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Carry out filling operations only at sites with extractors available. Immediately remove all soiled and contaminated clothing Avoid contact with the eyes and skin. Respiratory protection: Use suitable respiratory protective device only when aerosol or mist is formed. Protection of hands: Protective gloves Material of gloves Fluorocarbon rubber (Viton) Recommended thickness of the material: 0.7 mm Penetration time of glove material Time for permeation appr.60 min Eye protection: Tightly sealed goggles Body protection: Protective work clothing Protective clothing should be selected specifically for the working place, depending on concentration and quantity of the hazardous substances handled. The resistance of the protective clothing to chemicals should be ascertained with the respective supplier. 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: fluid Colour: colourless Odour: Amine-like ph-value (100 g/l) at 20 C: 12 (in H2O) Change in condition Melting point/melting range: -19 C (1013 hpa) (Contd. on page 5)

5 Page 5/7 Boiling point/boiling range: 220 C (1013 hpa) Flash point: 92 C Ignition temperature: 315 C Danger of explosion: Product does not present an explosion hazard. Explosion limits: Lower: 2.1 Vol % Upper: 10.5 Vol % Vapour pressure at 20 C: 0.07 hpa Density at 20 C: g/cm³ Solubility in / Miscibility with water: Fully miscible. (Contd. of page 4) 10 Stability and reactivity Reactivity Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Possibility of hazardous reactions Reacts with strong oxidizing agents. Incompatible materials: Oxidizing agents Hazardous decomposition products: No dangerous decomposition products known. Additional information: hygroscopic 11 Toxicological information Information on toxicological effects Acute toxicity: LD/LC50 values relevant for classification: Oral LD mg/kg (rat) Dermal LD mg/kg (rabbit) Primary irritant effect: on the skin: Strong caustic effect on skin and mucous membranes. on the eye: Strong caustic effect. Danger of severe eye injury. Sensitization: Sensitization possible through skin contact. Additional toxicological information: After inhalation: may lead to irritation or burns of the respiratory system. Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus and stomach. Sensitisation May cause sensitisation by skin contact. * 12 Ecological information Toxicity Acquatic toxicity: LC50/48 h mg/l (fish) Persistence and degradability No further relevant information available. Additional ecological information: General notes: Water hazard class 2(VwVwS): hazardous for water. (Contd. on page 6)

6 Page 6/7 Do not allow product to reach ground water, water course or sewage system. Harmful to aquatic organisms Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. (Contd. of page 5) 13 Disposal considerations Waste treatment methods Recommendation Must not be disposed together with household garbage. Do not allow product to reach sewage system. Must be specially treated adhering to official regulations. Uncleaned packaging: Recommendation: Disposal must be made according to official regulations. * 14 Transport information ADR/RID class: 8 Corrosive substances. Danger code (Kemler): 80 UN-Number: 2815 Packaging group: III Hazard label: 8 UN proper shipping name: N-AMINOETHYLPIPERAZINE Tunnel restriction code E Inland shipping ADN/ADNR: 2815 ADN/R Class: 8 Maritime transport IMDG: IMDG Class: 8 UN Number: 2815 Label 8 Packaging group: III EMS Number: F-A,S-B Proper shipping name: N-AMINOETHYLPIPERAZINE Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: 8 UN/ID Number: 2815 Label 8 Packaging group: III Proper shipping name: N-AMINOETHYLPIPERAZINE UN "Model Regulation": UN2815, N-AMINOETHYLPIPERAZINE, 8, III Special precautions for user Warning: Corrosive substances. (Contd. on page 7)

7 Page 7/7 (Contd. of page 6) 15 Regulatory information Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Relevant phrases H302 Harmful if swallowed. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H412 Harmful to aquatic life with long lasting effects. R21/22 Harmful in contact with skin and if swallowed. R34 Causes burns. R43 May cause sensitisation by skin contact. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Department issuing MSDS: Product safety Contact: Dr. Müller Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA) ICAO: International Civil Aviation Organization ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO) GHS: Globally Harmonized System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent Sources Literature value * Data compared to the previous version altered.