Coated film for demanding High Barrier applications. 02/2013 Oxaqua - introduction

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1 Coated film for demanding High Barrier applications 1

2 Metalvuoto is one of few players in the flexible packaging marketplace to apply coating and vacuum coating technology on different base substrates: BOPP, PA, PET,... The barrier performance is one of the key measures for our coated and metallised films. Thanks to Oxaqua patented technology, and thanks to tailored metallization process Metalvuoto is at the edge of Barrier Substrate Technology 2

3 Oxygen Transmission Rate 10,000 BOPP Cast PP 1,000 Acrylic Coated 100 Met BOPP PVdC Coated BOPP PET Nylon 10 Metallised PET Al 2 O 3 PET PVdC Coated PET 1 PE-EVOH-PE ,000 Water Vapor Transmission Rate 3

4 Oxygen Transmission Rate 10,000 BOPP Cast PP 1,000 Acrylic Coated 100 Met BOPP PVdC Coated BOPP PET Nylon 10 Metallised PET Al 2 O 3 PET PVdC Coated PET 1 PE-EVOH-PE PTN09 PLA09 0 OTN09-OTR09 ATN09 CTN09 PTR09-PTX ,000 Water Vapor Transmission Rate 4

5 Oxygen Transmission Rate 10,000 BOPP Cast PP 1,000 Acrylic Coated 100 Met BOPP PVdC Coated BOPP PET Nylon 10 Metallised PET Al 2 O 3 PET PVdC Coated PET 1 PROPYLESTER PMN09 PMP09 PE-EVOH-PE ,000 Water Vapor Transmission Rate 5

6 Special coating providing very high gas barrier performance to any plastic film ~ 1g/m 2 of hybrid coating (modified PVOH) Substrate 6

7 Combining the features of two individual phases can be useful to obtain a hybrid network with improved O 2 barrier properties even at high humidity values + PVOH Modifier 7

8 Ultra high gas barrier Excellent transparency Excellent printability Microwave-able High resistance to GelboTest Thermoformable! Retortable (only OTR09 & CTN09 pasteurization) Higher humidity resistance (novelty!) 8

9 Final complex thickness reduction Eco-friendly (waste reduction) Saving cost 9

10 Coating adhesion to substrate > 3N/15mm (If properly laminated, complex can be: not delaminable!) Sealing bond strength > 20N/15mm Packaging bond strength before & after pasteurization = not delaminable (sample breaking)! (only OTR09 & CTN09) 10

11 PET Oxaqua PET AlOx PET SiOx PET PVDC PE/EVOH/PE < 2% % < 7% In accordance with ASTM D , using an integrative sphere (150 mm Ø) 11

12 Film OTR* OTR* (after Gelbo test 20cycles) PTN ml m -2 24h ml m -2 24h -1 PET-AlOx 1.5 ml m -2 24h ml m -2 24h -1 *(23 C & 50% RH) 12

13 Oxaqua stands deformation stresses!! Bottom Structure CTN09-120my//CPP-250my APET-375my//PE-EVOH3-PE Dimensions OTR* of the bottom tray (23 C & 50% RH) 17cm x 13cm x 3cm (depth) < ml/package < ml/package * Test carried out at CSI (certified Italian LAB) 13

14 Metalvuoto s breakthrough in producing trays! The new mono material eco-friendly tray Top -> OTR09-20my//CPP50my Bottom -> CTN09-120my//CPP250my Pasteurizable & Eco-friendly 14

15 Metalvuoto presents PTR09 & PTX09, an evolution of Oxaqua coating, more resistant to humidity! Film OTR* (ml m -2 24h -1 ) OTR** (ml m -2 24h -1 ) laminated with PE60my PTN PTR < 6 PTX < 3 *(23 C & 0% RH) **(23 C & 75%RH) - Humidity facing both sides of the film 15

16 PET based PTN09 PTP09 PTP09CMC PMN09 Coated PET Coated PET with improved adhesion Coated PET with improved adhesion Chemical treatment on the other side Coated & metallised PET PET based Oxaqua Perfomer PTR09 PTX09 Coated PET with improved RH resistance Coated PET with extraordinary improved RH resistance 16

17 BOPA based ATN09 BOPP & CPP based OTN09 OTR09 OTX09 PROPYLESTER CTN09 PLA based PLA09 Coated BOPA Coated BOPPCEX sealable Coated BOPP not sealable pasteurizable Coated BOPP with improved humidity resistance Coated & metallised BOPP Coated CPP for thermoforming & pasteurization Coated PLA 17

18 MAP Top of trays Fresh pasta Meat Cheese slices (ATN09) Thermoforming (CTN09) Pizza / Bakery 18

19 ETP09 = Peelable LDPE Oxaqua coated (to be used as inner layer of trays) Coated film with improved Water Vapor barrier (such as PTN89!) Coated PET & OPA resistant to thermal processes the next film required by the market! 19

20 Thanks for your kind attention Roberto Rocca Metalvuoto S.p.A. Via L. da Vinci, Roncello (MB) robertorocca@metalvuoto.it 20

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